TY  - JOUR
AU  - Savić, Slavica M.
AU  - Stojanović, G.
AU  - Vasiljević, D.
AU  - Vojisavljević, K.
AU  - Dapčević, Aleksandra
AU  - Radojković, Aleksandar
AU  - Prsić, S.
AU  - Branković, Goran
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3286
AB  - The chemical synthesis of nickel manganite powder was performed by a complex polymerization method (CPM). The obtained fine nanoscaled powders were uniaxially pressed and sintered at different temperatures: 1000-1200 degrees C for 2 h, and different atmospheres: air and oxygen. The highest density was obtained for the sample sintered at 1200 degrees C in oxygen atmosphere. The energy for direct band gap transition (Eg) calculated from the Tauc plot decreases from 1.51 to 1.40 eV with the increase of the sintering temperature. Indentation experiments were carried out using a three-sided pyramidal (Berkovich) diamond tip, and Young's modulus of elasticity and hardness of NTC (negative temperature coefficient) ceramics at various indentation depths were calculated. The highest hardness (0.754 GPa) and elastic modulus (16.888 GPa) are exhibited by the ceramics sintered at highest temperature in oxygen atmosphere.
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Nanoindentation study of nickel manganite ceramics obtained by a complex polymerization method
EP  - 12282
IS  - 10
SP  - 12276
VL  - 42
DO  - 10.1016/j.ceramint.2016.04.174
ER  - 

@article{
author = "Savić, Slavica M. and Stojanović, G. and Vasiljević, D. and Vojisavljević, K. and Dapčević, Aleksandra and Radojković, Aleksandar and Prsić, S. and Branković, Goran",
year = "2016",
abstract = "The chemical synthesis of nickel manganite powder was performed by a complex polymerization method (CPM). The obtained fine nanoscaled powders were uniaxially pressed and sintered at different temperatures: 1000-1200 degrees C for 2 h, and different atmospheres: air and oxygen. The highest density was obtained for the sample sintered at 1200 degrees C in oxygen atmosphere. The energy for direct band gap transition (Eg) calculated from the Tauc plot decreases from 1.51 to 1.40 eV with the increase of the sintering temperature. Indentation experiments were carried out using a three-sided pyramidal (Berkovich) diamond tip, and Young's modulus of elasticity and hardness of NTC (negative temperature coefficient) ceramics at various indentation depths were calculated. The highest hardness (0.754 GPa) and elastic modulus (16.888 GPa) are exhibited by the ceramics sintered at highest temperature in oxygen atmosphere.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Nanoindentation study of nickel manganite ceramics obtained by a complex polymerization method",
pages = "12282-12276",
number = "10",
volume = "42",
doi = "10.1016/j.ceramint.2016.04.174"
}

Savić, S. M., Stojanović, G., Vasiljević, D., Vojisavljević, K., Dapčević, A., Radojković, A., Prsić, S.,& Branković, G.. (2016). Nanoindentation study of nickel manganite ceramics obtained by a complex polymerization method. in Ceramics International
Elsevier Sci Ltd, Oxford., 42(10), 12276-12282.
https://doi.org/10.1016/j.ceramint.2016.04.174

Savić SM, Stojanović G, Vasiljević D, Vojisavljević K, Dapčević A, Radojković A, Prsić S, Branković G. Nanoindentation study of nickel manganite ceramics obtained by a complex polymerization method. in Ceramics International. 2016;42(10):12276-12282.
doi:10.1016/j.ceramint.2016.04.174 .

Savić, Slavica M., Stojanović, G., Vasiljević, D., Vojisavljević, K., Dapčević, Aleksandra, Radojković, Aleksandar, Prsić, S., Branković, Goran, "Nanoindentation study of nickel manganite ceramics obtained by a complex polymerization method" in Ceramics International, 42, no. 10 (2016):12276-12282,
https://doi.org/10.1016/j.ceramint.2016.04.174 . .

TY  - JOUR
AU  - Prsić, S.
AU  - Savić, Slavica M.
AU  - Branković, Zorica
AU  - Vrtnik, S.
AU  - Dapčević, Aleksandra
AU  - Branković, Goran
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2992
AB  - In the last decade, the sodium cobaltite ceramic became a promising candidate for potential thermoelectric applications, because of its large thermopower and low resistivity. In this work, polycrystalline samples of NaCo(2-x)CuxO(4) (x = 0, 0.01, 0.03, 0.05) were prepared using mechanochemically assisted solid-state reaction method (MASSR) and the citric acid complex method (CAC). Bulk samples were prepared by pressing into disc-shaped pellets and subsequently subjected to a thermal treatment at 880 degrees C in inert argon atmosphere. Changes in structural and microstructural characteristics of the samples, caused by the substitution of Cu for Co, were characterized using X-ray diffraction (XRD) analysis, and scanning electron microscopy (SEM), respectively. The results of inductively coupled plasma (ICP) analysis showed that the compositions of the final products correspond to gamma-NaCo2O4 and confirmed that desired compound was obtained in both syntheses procedures. The advantages and disadvantages of these two syntheses procedures have been observed and discussed: the CAC method enabled obtaining samples with higher density and fine microstructure compared to the MASSR method, thus better thermoelectric properties. The Cu2+ substitution led to the increase in Seebeck coefficient in both synthesis routes. The highest figure of merit of 0.022 at 300 K was observed for the sample doped with 1 mol% Cu, obtained by the CAC method, and it was almost twice higher than in the undoped sample confirming the significant influence of Cu-doping with even small concentrations.
PB  - Elsevier Science Sa, Lausanne
T2  - Journal of Alloys and Compounds
T1  - Mechanochemically assisted solid-state and citric acid complex syntheses of Cu-doped sodium cobaltite ceramicsh
EP  - 487
SP  - 480
VL  - 640
DO  - 10.1016/j.jallcom.2015.04.003
ER  - 

@article{
author = "Prsić, S. and Savić, Slavica M. and Branković, Zorica and Vrtnik, S. and Dapčević, Aleksandra and Branković, Goran",
year = "2015",
abstract = "In the last decade, the sodium cobaltite ceramic became a promising candidate for potential thermoelectric applications, because of its large thermopower and low resistivity. In this work, polycrystalline samples of NaCo(2-x)CuxO(4) (x = 0, 0.01, 0.03, 0.05) were prepared using mechanochemically assisted solid-state reaction method (MASSR) and the citric acid complex method (CAC). Bulk samples were prepared by pressing into disc-shaped pellets and subsequently subjected to a thermal treatment at 880 degrees C in inert argon atmosphere. Changes in structural and microstructural characteristics of the samples, caused by the substitution of Cu for Co, were characterized using X-ray diffraction (XRD) analysis, and scanning electron microscopy (SEM), respectively. The results of inductively coupled plasma (ICP) analysis showed that the compositions of the final products correspond to gamma-NaCo2O4 and confirmed that desired compound was obtained in both syntheses procedures. The advantages and disadvantages of these two syntheses procedures have been observed and discussed: the CAC method enabled obtaining samples with higher density and fine microstructure compared to the MASSR method, thus better thermoelectric properties. The Cu2+ substitution led to the increase in Seebeck coefficient in both synthesis routes. The highest figure of merit of 0.022 at 300 K was observed for the sample doped with 1 mol% Cu, obtained by the CAC method, and it was almost twice higher than in the undoped sample confirming the significant influence of Cu-doping with even small concentrations.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Journal of Alloys and Compounds",
title = "Mechanochemically assisted solid-state and citric acid complex syntheses of Cu-doped sodium cobaltite ceramicsh",
pages = "487-480",
volume = "640",
doi = "10.1016/j.jallcom.2015.04.003"
}

Prsić, S., Savić, S. M., Branković, Z., Vrtnik, S., Dapčević, A.,& Branković, G.. (2015). Mechanochemically assisted solid-state and citric acid complex syntheses of Cu-doped sodium cobaltite ceramicsh. in Journal of Alloys and Compounds
Elsevier Science Sa, Lausanne., 640, 480-487.
https://doi.org/10.1016/j.jallcom.2015.04.003

Prsić S, Savić SM, Branković Z, Vrtnik S, Dapčević A, Branković G. Mechanochemically assisted solid-state and citric acid complex syntheses of Cu-doped sodium cobaltite ceramicsh. in Journal of Alloys and Compounds. 2015;640:480-487.
doi:10.1016/j.jallcom.2015.04.003 .

Prsić, S., Savić, Slavica M., Branković, Zorica, Vrtnik, S., Dapčević, Aleksandra, Branković, Goran, "Mechanochemically assisted solid-state and citric acid complex syntheses of Cu-doped sodium cobaltite ceramicsh" in Journal of Alloys and Compounds, 640 (2015):480-487,
https://doi.org/10.1016/j.jallcom.2015.04.003 . .