Razvoj metoda za separaciju, predkoncentrisanje, određivanje i uklanjanje zagađivača okoline

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Razvoj metoda za separaciju, predkoncentrisanje, određivanje i uklanjanje zagađivača okoline (en)
Развој метода за сепарацију, предконцентрисање, одређивање и уклањање загађивача околине (sr)
Razvoj metoda za separaciju, predkoncentrisanje, određivanje i uklanjanje zagađivača okoline (sr_RS)
Authors

Publications

Monomer elution from nanohybrid and ormocer-based composites cured with different light sources

Manojlović, Dragica; Radisić, Marina; Vasiljević, Tatjana; Živković, Slavoljub; Laušević, Mila; Miletić, Vesna

(Elsevier Sci Ltd, Oxford, 2011)

TY  - JOUR
AU  - Manojlović, Dragica
AU  - Radisić, Marina
AU  - Vasiljević, Tatjana
AU  - Živković, Slavoljub
AU  - Laušević, Mila
AU  - Miletić, Vesna
PY  - 2011
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5640
AB  - Objectives. To study monomer elution from four resin-based composites (RBCs) cured with different light sources. Methods. Twenty-eight premolars were randomly allocated to four groups. Standardized cavities were prepared and restored with a nanohybrid (Filtek Supreme XT or Tetric EvoCeram), an ormocer (Admira) or a microhybrid RBC (Filtek Z250) which served as control. Buccal restorations were cured with a halogen and oral restorations with an LED light-curing unit. Elution of diurethane dimethacrylate (UDMA), Bisphenol A diglycidylether methacrylate (BisGMA), triethylene glycol dimethacrylate (TEGDMA) and 2-hydroxyethyl methacrylate (HEMA) was analyzed using high-performance liquid chromatography (HPLC) 1h to 28 days post-immersion in 75% ethanol. Data were analyzed using multivariate and repeated measures analysis of variance (alpha = 0.05). Results. The greatest elution of UDMA and BisGMA occurred from Tetric EvoCeram and the least from Filtek Z250 (p  lt  0.05). LED and halogen light-curing units gave similar results for all RBCs (p > 0.05) except Tetric EvoCeram which showed greater elution for the LED unit (p  lt  0.05). TEGDMA was below the limit of quantification. HEMA eluted in similar concentrations from Filtek Supreme and Tetric EvoCeram (p > 0.05). Significance. : The two nanohybrid RBCs eluted more cross-linking monomers than the ormocer and the control microhybrid RBC. Continuous elution over 28 days indicates that RBCs act as a chronic source of monomers in clinical conditions. Light source may affect monomer elution since differences were found for one out of four RBCs. Mathematical models for elution kinetics of UDMA and BisGMA indicated two elution mechanisms.
PB  - Elsevier Sci Ltd, Oxford
T2  - Dental Materials
T1  - Monomer elution from nanohybrid and ormocer-based composites cured with different light sources
EP  - 378
IS  - 4
SP  - 371
VL  - 27
DO  - 10.1016/j.dental.2010.11.017
ER  - 
@article{
author = "Manojlović, Dragica and Radisić, Marina and Vasiljević, Tatjana and Živković, Slavoljub and Laušević, Mila and Miletić, Vesna",
year = "2011",
abstract = "Objectives. To study monomer elution from four resin-based composites (RBCs) cured with different light sources. Methods. Twenty-eight premolars were randomly allocated to four groups. Standardized cavities were prepared and restored with a nanohybrid (Filtek Supreme XT or Tetric EvoCeram), an ormocer (Admira) or a microhybrid RBC (Filtek Z250) which served as control. Buccal restorations were cured with a halogen and oral restorations with an LED light-curing unit. Elution of diurethane dimethacrylate (UDMA), Bisphenol A diglycidylether methacrylate (BisGMA), triethylene glycol dimethacrylate (TEGDMA) and 2-hydroxyethyl methacrylate (HEMA) was analyzed using high-performance liquid chromatography (HPLC) 1h to 28 days post-immersion in 75% ethanol. Data were analyzed using multivariate and repeated measures analysis of variance (alpha = 0.05). Results. The greatest elution of UDMA and BisGMA occurred from Tetric EvoCeram and the least from Filtek Z250 (p  lt  0.05). LED and halogen light-curing units gave similar results for all RBCs (p > 0.05) except Tetric EvoCeram which showed greater elution for the LED unit (p  lt  0.05). TEGDMA was below the limit of quantification. HEMA eluted in similar concentrations from Filtek Supreme and Tetric EvoCeram (p > 0.05). Significance. : The two nanohybrid RBCs eluted more cross-linking monomers than the ormocer and the control microhybrid RBC. Continuous elution over 28 days indicates that RBCs act as a chronic source of monomers in clinical conditions. Light source may affect monomer elution since differences were found for one out of four RBCs. Mathematical models for elution kinetics of UDMA and BisGMA indicated two elution mechanisms.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Dental Materials",
title = "Monomer elution from nanohybrid and ormocer-based composites cured with different light sources",
pages = "378-371",
number = "4",
volume = "27",
doi = "10.1016/j.dental.2010.11.017"
}
Manojlović, D., Radisić, M., Vasiljević, T., Živković, S., Laušević, M.,& Miletić, V.. (2011). Monomer elution from nanohybrid and ormocer-based composites cured with different light sources. in Dental Materials
Elsevier Sci Ltd, Oxford., 27(4), 371-378.
https://doi.org/10.1016/j.dental.2010.11.017
Manojlović D, Radisić M, Vasiljević T, Živković S, Laušević M, Miletić V. Monomer elution from nanohybrid and ormocer-based composites cured with different light sources. in Dental Materials. 2011;27(4):371-378.
doi:10.1016/j.dental.2010.11.017 .
Manojlović, Dragica, Radisić, Marina, Vasiljević, Tatjana, Živković, Slavoljub, Laušević, Mila, Miletić, Vesna, "Monomer elution from nanohybrid and ormocer-based composites cured with different light sources" in Dental Materials, 27, no. 4 (2011):371-378,
https://doi.org/10.1016/j.dental.2010.11.017 . .
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Analysis of selected elements in water in the drinking water preparation plants in Belgrade, Serbia

Antanasijević, Davor; Lukić, Nataša A.; Pocajt, Viktor; Perić-Grujić, Aleksandra; Ristić, Mirjana

(Association of Chemical Engineers of Serbia, 2011)

TY  - JOUR
AU  - Antanasijević, Davor
AU  - Lukić, Nataša A.
AU  - Pocajt, Viktor
AU  - Perić-Grujić, Aleksandra
AU  - Ristić, Mirjana
PY  - 2011
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1779
AB  - Belgrade's water supply relies mainly on the River Sava and groundwater supply wells, which are located in the vicinity of the river and Ada Ciganlija. In this paper, the contents of aluminum, boron, chromium, manganese, cobalt, nickel, copper, zinc, arsenic, cadmium, barium and lead were analyzed in raw water as well as drinking water distributed by the Water Supply and Sewage of Belgrade. A total of 14 samples were examined from all water treatment plants that are part of the distribution system. The measurements were conducted using the inductively coupled plasma-mass spectrometry (ICP-MS) technique. The aim of this research was to examine the effectiveness of the drinking water preparation process in the plants belonging to the Water Supply and Sewage of Belgrade. The content of certain elements varies considerably in raw water (river and groundwater): the concentration of boron in river water is two to three times lower than the concentration in groundwater; the concentration of arsenic in river water is ten to twenty five times lower than the concentration in groundwater; the concentration of aluminum in all groundwater samples was below the detection limit of the instrument (0.50 μg/dm3), whilst in the river water the content of aluminum was about 50 μg/dm3 and the concentration of manganese in the river water was up to 10 times lower than the concentrations in groundwater. In all drinking water samples the concentration of the elements were bellow the maximum allowed levels according to the Serbian regulations. Correlation coefficients determined for boron, manganese, cobalt, nickel, copper, zinc, arsenic, barium and lead, which were analyzed in raw waters, show that four groups of elements can be distinguished. Boron, manganese, arsenic and barium are related to each other and probably have a common natural origin; copper and lead probably have a common anthropogenic origin; correlation of nickel and cobalt was observed, while zinc was not in correlation with any other element.
AB  - U ovom radu ispitivan je sadržaj aluminijuma, bora, hroma, mangana, kobalta, nikla, bakra, cinka, arsena, kadmijuma, barijuma i olova u sirovoj vodi i vodi za piće koju koristi, odnosno isporučuje potrošačima Javno komunalno preduzeće Beogradski vodovod i kanalizacija. Ispitano je ukupno 14 uzoraka sa svih pogona za pripremu vode koja su u sastavu Beogradskog vodovoda i kanalizacije. Analiza uzoraka je rađena primenom indukovano spregnute plazme sa masenom spektrometrijom. Cilj istraživanja je bio da se ispita efikasnost procesa za pripremu vode za piće koji se primenjuju u pogonima Beogradskog vodovoda i kanalizacije. Iako su koncentracije pojedinih elemenata u sirovoj vodi bile u širokom opsegu vrednosti i znatno se razlikovale u podzemnim i rečnim vodama, u uzorcima vode za piće koncentracije svih ispitivanih elemenata bile su niže od maksimalno dozvoljenih koncentracija propisanih zakonskom regulativom Republike Srbije.
PB  - Association of Chemical Engineers of Serbia
T2  - Hemijska industrija
T1  - Analysis of selected elements in water in the drinking water preparation plants in Belgrade, Serbia
T1  - Analiza odabranih elemenata u vodi u pogonima za pripremu vode za piće u Beogradu
EP  - 196
IS  - 2
SP  - 187
VL  - 65
DO  - 10.2298/HEMIND101027001A
ER  - 
@article{
author = "Antanasijević, Davor and Lukić, Nataša A. and Pocajt, Viktor and Perić-Grujić, Aleksandra and Ristić, Mirjana",
year = "2011",
abstract = "Belgrade's water supply relies mainly on the River Sava and groundwater supply wells, which are located in the vicinity of the river and Ada Ciganlija. In this paper, the contents of aluminum, boron, chromium, manganese, cobalt, nickel, copper, zinc, arsenic, cadmium, barium and lead were analyzed in raw water as well as drinking water distributed by the Water Supply and Sewage of Belgrade. A total of 14 samples were examined from all water treatment plants that are part of the distribution system. The measurements were conducted using the inductively coupled plasma-mass spectrometry (ICP-MS) technique. The aim of this research was to examine the effectiveness of the drinking water preparation process in the plants belonging to the Water Supply and Sewage of Belgrade. The content of certain elements varies considerably in raw water (river and groundwater): the concentration of boron in river water is two to three times lower than the concentration in groundwater; the concentration of arsenic in river water is ten to twenty five times lower than the concentration in groundwater; the concentration of aluminum in all groundwater samples was below the detection limit of the instrument (0.50 μg/dm3), whilst in the river water the content of aluminum was about 50 μg/dm3 and the concentration of manganese in the river water was up to 10 times lower than the concentrations in groundwater. In all drinking water samples the concentration of the elements were bellow the maximum allowed levels according to the Serbian regulations. Correlation coefficients determined for boron, manganese, cobalt, nickel, copper, zinc, arsenic, barium and lead, which were analyzed in raw waters, show that four groups of elements can be distinguished. Boron, manganese, arsenic and barium are related to each other and probably have a common natural origin; copper and lead probably have a common anthropogenic origin; correlation of nickel and cobalt was observed, while zinc was not in correlation with any other element., U ovom radu ispitivan je sadržaj aluminijuma, bora, hroma, mangana, kobalta, nikla, bakra, cinka, arsena, kadmijuma, barijuma i olova u sirovoj vodi i vodi za piće koju koristi, odnosno isporučuje potrošačima Javno komunalno preduzeće Beogradski vodovod i kanalizacija. Ispitano je ukupno 14 uzoraka sa svih pogona za pripremu vode koja su u sastavu Beogradskog vodovoda i kanalizacije. Analiza uzoraka je rađena primenom indukovano spregnute plazme sa masenom spektrometrijom. Cilj istraživanja je bio da se ispita efikasnost procesa za pripremu vode za piće koji se primenjuju u pogonima Beogradskog vodovoda i kanalizacije. Iako su koncentracije pojedinih elemenata u sirovoj vodi bile u širokom opsegu vrednosti i znatno se razlikovale u podzemnim i rečnim vodama, u uzorcima vode za piće koncentracije svih ispitivanih elemenata bile su niže od maksimalno dozvoljenih koncentracija propisanih zakonskom regulativom Republike Srbije.",
publisher = "Association of Chemical Engineers of Serbia",
journal = "Hemijska industrija",
title = "Analysis of selected elements in water in the drinking water preparation plants in Belgrade, Serbia, Analiza odabranih elemenata u vodi u pogonima za pripremu vode za piće u Beogradu",
pages = "196-187",
number = "2",
volume = "65",
doi = "10.2298/HEMIND101027001A"
}
Antanasijević, D., Lukić, N. A., Pocajt, V., Perić-Grujić, A.,& Ristić, M.. (2011). Analysis of selected elements in water in the drinking water preparation plants in Belgrade, Serbia. in Hemijska industrija
Association of Chemical Engineers of Serbia., 65(2), 187-196.
https://doi.org/10.2298/HEMIND101027001A
Antanasijević D, Lukić NA, Pocajt V, Perić-Grujić A, Ristić M. Analysis of selected elements in water in the drinking water preparation plants in Belgrade, Serbia. in Hemijska industrija. 2011;65(2):187-196.
doi:10.2298/HEMIND101027001A .
Antanasijević, Davor, Lukić, Nataša A., Pocajt, Viktor, Perić-Grujić, Aleksandra, Ristić, Mirjana, "Analysis of selected elements in water in the drinking water preparation plants in Belgrade, Serbia" in Hemijska industrija, 65, no. 2 (2011):187-196,
https://doi.org/10.2298/HEMIND101027001A . .
1
2
2

Carbon Monolith Surface Chemistry Influence on the Silver Deposit Amount and Crystallite Size

Vukčević, Marija; Kalijadis, Ana; Jovanović, Zoran M.; Laušević, Zoran; Laušević, Mila

(Polish Acad Sciences Inst Physics, Warsaw, 2011)

TY  - JOUR
AU  - Vukčević, Marija
AU  - Kalijadis, Ana
AU  - Jovanović, Zoran M.
AU  - Laušević, Zoran
AU  - Laušević, Mila
PY  - 2011
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1763
AB  - The surface of carbon monolith (CM) was chemically treated in order to obtain antibacterial filters with silver deposit for water treatment. The chemical treatment involved submerging the as-received CM in HNO(3), KOH and H(2)O(2) solution. The specific surface area was examined by N(2) adsorption. Silver deposition at the surface of CM samples was performed using cheap and simple procedure of immersing CM samples in aqueous solution of AgNO(3). Temperature programmed desorption method has been used in order to investigate the nature and thermal stability of surface oxygen groups before and after silver deposition. The composition and crystalinity of silver deposits have been examined by X-ray diffraction. Chemical treatment does not cause any drastic changes of CM specific surface area, but increases a total amount of surface oxides. Amount of deposited silver is several times higher for all chemically treated samples. The results show that increasing the amount of CO yielding groups on CM surface leads to increased amount of Ag deposit and decreases its crystallite sizes
PB  - Polish Acad Sciences Inst Physics, Warsaw
T2  - Acta Physica Polonica A
T1  - Carbon Monolith Surface Chemistry Influence on the Silver Deposit Amount and Crystallite Size
EP  - 288
IS  - 2
SP  - 284
VL  - 120
DO  - 10.12693/APhysPolA.120.284
ER  - 
@article{
author = "Vukčević, Marija and Kalijadis, Ana and Jovanović, Zoran M. and Laušević, Zoran and Laušević, Mila",
year = "2011",
abstract = "The surface of carbon monolith (CM) was chemically treated in order to obtain antibacterial filters with silver deposit for water treatment. The chemical treatment involved submerging the as-received CM in HNO(3), KOH and H(2)O(2) solution. The specific surface area was examined by N(2) adsorption. Silver deposition at the surface of CM samples was performed using cheap and simple procedure of immersing CM samples in aqueous solution of AgNO(3). Temperature programmed desorption method has been used in order to investigate the nature and thermal stability of surface oxygen groups before and after silver deposition. The composition and crystalinity of silver deposits have been examined by X-ray diffraction. Chemical treatment does not cause any drastic changes of CM specific surface area, but increases a total amount of surface oxides. Amount of deposited silver is several times higher for all chemically treated samples. The results show that increasing the amount of CO yielding groups on CM surface leads to increased amount of Ag deposit and decreases its crystallite sizes",
publisher = "Polish Acad Sciences Inst Physics, Warsaw",
journal = "Acta Physica Polonica A",
title = "Carbon Monolith Surface Chemistry Influence on the Silver Deposit Amount and Crystallite Size",
pages = "288-284",
number = "2",
volume = "120",
doi = "10.12693/APhysPolA.120.284"
}
Vukčević, M., Kalijadis, A., Jovanović, Z. M., Laušević, Z.,& Laušević, M.. (2011). Carbon Monolith Surface Chemistry Influence on the Silver Deposit Amount and Crystallite Size. in Acta Physica Polonica A
Polish Acad Sciences Inst Physics, Warsaw., 120(2), 284-288.
https://doi.org/10.12693/APhysPolA.120.284
Vukčević M, Kalijadis A, Jovanović ZM, Laušević Z, Laušević M. Carbon Monolith Surface Chemistry Influence on the Silver Deposit Amount and Crystallite Size. in Acta Physica Polonica A. 2011;120(2):284-288.
doi:10.12693/APhysPolA.120.284 .
Vukčević, Marija, Kalijadis, Ana, Jovanović, Zoran M., Laušević, Zoran, Laušević, Mila, "Carbon Monolith Surface Chemistry Influence on the Silver Deposit Amount and Crystallite Size" in Acta Physica Polonica A, 120, no. 2 (2011):284-288,
https://doi.org/10.12693/APhysPolA.120.284 . .
1
2
2

Optimization of preparation conditions of poly(ε-caprolactone) microspheres for controlled release of carbamazepine

Pepić, Dragana; Anđelković, Darinka R.; Nikolić, Marija; Grujić, Svetlana; Đonlagić, Jasna

(Association of Chemical Engineers of Serbia, 2010)

TY  - JOUR
AU  - Pepić, Dragana
AU  - Anđelković, Darinka R.
AU  - Nikolić, Marija
AU  - Grujić, Svetlana
AU  - Đonlagić, Jasna
PY  - 2010
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1656
AB  - Poly (ε-caprolactone), PCL, is an aliphatic polyester suitable for controlled drug release due to its biodegradability, biocompatibility, non-toxicity and high permeability to many therapeutic drugs. This study investigates the effect of the preparation parameters on the size and the morphology of the PCL microspheres and on the release profile of carbamazepine from these microspheres. The PCL microspheres were prepared using oil-in-water (o/w) emulsion solvent evaporation method with the poly(vinyl alcohol), PVA, as the emulsion stabilizer. The influence of the stirring rate applied during the emulsion formation, the homogenization time and the emulsifier concentration on diameter and size distribution of the microspheres was analyzed by scanning electron microscope (SEM). The initial emulsion was formed applying high stirring rates of 10000, 18000 and 23000 rpm, for homogenization times: 5, 10 and 15 min. The diameter was strongly influenced by the stirring rate, and the average particle size decreased from 9.2 to 2.8 ìm with the increase of the stirring rate. Increasing the amount of PVA in the water phase from 0.2 to 1 mass% improved stabilization of the oil droplets and led to a slight decrease of the average particle diameter. Drug-loaded microspheres were prepared by the same technique using different amounts of carbamazepine (10 and 15 mass%), under given conditions (1.0 mass% PVA, stirring rate of 18000 rpm for a period of 5 min of emulsion formation). Additionally, microspheres were prepared by applying low stirring rate of 1000 rpm with 10 and 15 mass% of the drug. The SEM analysis showed that microspheres created with 18000 rpm stirring rate, had average diameters of 3-4 ìm, and the microspheres prepared with 1000 rpm stirring rate were larger than 100 ìm. It was also observed that, in the case of the large microspheres, carbamazepine was deposited on their surfaces, while the small microspheres had smooth surfaces without observable drug crystals. The encapsulation efficiency and the release behaviour of the carbamazepine were examined using high performance liquid chromatography-ultraviolet spectroscopy (HPLC-UV). The drug encapsulation efficiencies were in the range from 69 to 81%, and were increasing with the increase of the amount of carbamazepine in both series. In vitro release experiments were carried out in the phosphate buffer solution (pH 7) at 37°C. The release rate was influenced by the microspheres size and morphology. The larger microspheres released more carbamazepine (85-95%) compared to the small ones (50-65%) for the same period. This behavior was attributed to the different drug distribution in the PCL matrix. Different mathematical models were used to describe drug release kinetics. It was concluded that the mechanism of the carbamazepine release from the microspheres was diffusion-controlled, independent on the type of microspheres. The kinetic parameters showed that the release of carbamazepine was slower from the smaller microspheres, probably as a result of more even distribution of the drug in the polymer matrix.
AB  - Cilj ovog rada je ispitivanje uticaja uslova dobijanja mikrosfera biodegradabilnog poli(ε-kaprolaktona) tehnikom otparavanja rastvarača iz emulzije, na veličinu i raspodelu veličina mikrosfera. Polazne emulzije rastvora polimera u vodi formirane su pri velikim brzinama mešanja tokom formiranja emulzije u opsegu od 10000 do 23000 o min-1, radi dobijanja mikrosfera malih prečnika. Varirana je brzina mešanja prilikom formiranja emulzije, dužina trajanja emulgovanja velikim brzinama mešanja i udeo stabilizatora emulzije, poli(vinil alkohola). Veličina i raspodela veličina polimernih mikrosfera određivana je skenirajućom elektronskom mikroskopijom. U polimerne mikrosfere inkapsuliran je lek karbamazepin iz grupe antiepileptika i određivana je efikasnost inkapsulacije, kao i profil otpuštanja leka u puferskom rastvoru metodom tečne hromatografije sa UV spektroskopijom. Takođe je izučavana kinetika otpuštanja karbamazepina korišćenjem različitih modela s ciljem ispitivanja mehanizma otpuštanja leka iz mikrosfera dobijenih pri različitim uslovima.
PB  - Association of Chemical Engineers of Serbia
T2  - Hemijska industrija
T1  - Optimization of preparation conditions of poly(ε-caprolactone) microspheres for controlled release of carbamazepine
T1  - Optimizacija uslova dobijanja mikrosfera na bazi biodegradabilnog poli(ε-kaprolaktona) za kontrolisano otpuštanje karbamazepina
EP  - 502
IS  - 6
SP  - 491
VL  - 64
DO  - 10.2298/HEMIND101117073P
ER  - 
@article{
author = "Pepić, Dragana and Anđelković, Darinka R. and Nikolić, Marija and Grujić, Svetlana and Đonlagić, Jasna",
year = "2010",
abstract = "Poly (ε-caprolactone), PCL, is an aliphatic polyester suitable for controlled drug release due to its biodegradability, biocompatibility, non-toxicity and high permeability to many therapeutic drugs. This study investigates the effect of the preparation parameters on the size and the morphology of the PCL microspheres and on the release profile of carbamazepine from these microspheres. The PCL microspheres were prepared using oil-in-water (o/w) emulsion solvent evaporation method with the poly(vinyl alcohol), PVA, as the emulsion stabilizer. The influence of the stirring rate applied during the emulsion formation, the homogenization time and the emulsifier concentration on diameter and size distribution of the microspheres was analyzed by scanning electron microscope (SEM). The initial emulsion was formed applying high stirring rates of 10000, 18000 and 23000 rpm, for homogenization times: 5, 10 and 15 min. The diameter was strongly influenced by the stirring rate, and the average particle size decreased from 9.2 to 2.8 ìm with the increase of the stirring rate. Increasing the amount of PVA in the water phase from 0.2 to 1 mass% improved stabilization of the oil droplets and led to a slight decrease of the average particle diameter. Drug-loaded microspheres were prepared by the same technique using different amounts of carbamazepine (10 and 15 mass%), under given conditions (1.0 mass% PVA, stirring rate of 18000 rpm for a period of 5 min of emulsion formation). Additionally, microspheres were prepared by applying low stirring rate of 1000 rpm with 10 and 15 mass% of the drug. The SEM analysis showed that microspheres created with 18000 rpm stirring rate, had average diameters of 3-4 ìm, and the microspheres prepared with 1000 rpm stirring rate were larger than 100 ìm. It was also observed that, in the case of the large microspheres, carbamazepine was deposited on their surfaces, while the small microspheres had smooth surfaces without observable drug crystals. The encapsulation efficiency and the release behaviour of the carbamazepine were examined using high performance liquid chromatography-ultraviolet spectroscopy (HPLC-UV). The drug encapsulation efficiencies were in the range from 69 to 81%, and were increasing with the increase of the amount of carbamazepine in both series. In vitro release experiments were carried out in the phosphate buffer solution (pH 7) at 37°C. The release rate was influenced by the microspheres size and morphology. The larger microspheres released more carbamazepine (85-95%) compared to the small ones (50-65%) for the same period. This behavior was attributed to the different drug distribution in the PCL matrix. Different mathematical models were used to describe drug release kinetics. It was concluded that the mechanism of the carbamazepine release from the microspheres was diffusion-controlled, independent on the type of microspheres. The kinetic parameters showed that the release of carbamazepine was slower from the smaller microspheres, probably as a result of more even distribution of the drug in the polymer matrix., Cilj ovog rada je ispitivanje uticaja uslova dobijanja mikrosfera biodegradabilnog poli(ε-kaprolaktona) tehnikom otparavanja rastvarača iz emulzije, na veličinu i raspodelu veličina mikrosfera. Polazne emulzije rastvora polimera u vodi formirane su pri velikim brzinama mešanja tokom formiranja emulzije u opsegu od 10000 do 23000 o min-1, radi dobijanja mikrosfera malih prečnika. Varirana je brzina mešanja prilikom formiranja emulzije, dužina trajanja emulgovanja velikim brzinama mešanja i udeo stabilizatora emulzije, poli(vinil alkohola). Veličina i raspodela veličina polimernih mikrosfera određivana je skenirajućom elektronskom mikroskopijom. U polimerne mikrosfere inkapsuliran je lek karbamazepin iz grupe antiepileptika i određivana je efikasnost inkapsulacije, kao i profil otpuštanja leka u puferskom rastvoru metodom tečne hromatografije sa UV spektroskopijom. Takođe je izučavana kinetika otpuštanja karbamazepina korišćenjem različitih modela s ciljem ispitivanja mehanizma otpuštanja leka iz mikrosfera dobijenih pri različitim uslovima.",
publisher = "Association of Chemical Engineers of Serbia",
journal = "Hemijska industrija",
title = "Optimization of preparation conditions of poly(ε-caprolactone) microspheres for controlled release of carbamazepine, Optimizacija uslova dobijanja mikrosfera na bazi biodegradabilnog poli(ε-kaprolaktona) za kontrolisano otpuštanje karbamazepina",
pages = "502-491",
number = "6",
volume = "64",
doi = "10.2298/HEMIND101117073P"
}
Pepić, D., Anđelković, D. R., Nikolić, M., Grujić, S.,& Đonlagić, J.. (2010). Optimization of preparation conditions of poly(ε-caprolactone) microspheres for controlled release of carbamazepine. in Hemijska industrija
Association of Chemical Engineers of Serbia., 64(6), 491-502.
https://doi.org/10.2298/HEMIND101117073P
Pepić D, Anđelković DR, Nikolić M, Grujić S, Đonlagić J. Optimization of preparation conditions of poly(ε-caprolactone) microspheres for controlled release of carbamazepine. in Hemijska industrija. 2010;64(6):491-502.
doi:10.2298/HEMIND101117073P .
Pepić, Dragana, Anđelković, Darinka R., Nikolić, Marija, Grujić, Svetlana, Đonlagić, Jasna, "Optimization of preparation conditions of poly(ε-caprolactone) microspheres for controlled release of carbamazepine" in Hemijska industrija, 64, no. 6 (2010):491-502,
https://doi.org/10.2298/HEMIND101117073P . .
1
1
1

Determination of selected pesticides in environmental water by employing liquid-phase microextraction and liquid chromatography-tandem mass spectrometry

Trtić-Petrović, Tatjana M.; Đorđević, Jelena S.; Dujaković, Nikolina; Kumrić, Ksenija; Vasiljević, Tatjana; Laušević, Mila

(2010)

TY  - JOUR
AU  - Trtić-Petrović, Tatjana M.
AU  - Đorđević, Jelena S.
AU  - Dujaković, Nikolina
AU  - Kumrić, Ksenija
AU  - Vasiljević, Tatjana
AU  - Laušević, Mila
PY  - 2010
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5590
AB  - An optimised extraction and cleanup method for the analysis of pesticide in natural water samples is presented. Sixteen pesticides of different polarity and from the different chemical classes (organophosphates, triazines, benzimidazoles, carbamates, carbamides, neonicotinoides, methylureas, phenylureas and benzohydrazides), most frequently used in Serbia, were selected for the analysis. Liquid-phase microextraction in a single hollow fibre (HF-LPME) has been applied for sample preparation. The concentrations of pesticides were determined using HPLC-MS/MS method with electrospray ionisation. The extraction behaviour and selection of the experimental conditions was predicted based on log D and pK (a) values of targeted pesticides, which were calculated applying the computer software ACD/Labs PhysChem Suite v12. The influence of the donor pH and concentration of pesticides, organic phase composition as well as the extraction time on the extraction efficiency was investigated. Optimum extraction conditions were evaluated with respect to the investigated parameters of the extraction. The extraction method was validated for 10 out of 16 studied pesticides. Linear range of the pesticides was 0.1-5 A mu g L(-1) with the correlation coefficient from 0.991 to 0.9998, and the relative standard deviation for three standard measurements was between 0.2 and 11.8%. The limits of detections ranged from 0.026 to 0.237 A mu g L(-1) and the limits of quantifications from 0.094 to 0.793 A mu g L(-1). The optimised two-phase HF-LPME method was successfully applied for determination of moderately polar as well low-polar pesticides in the environmental water samples.
T2  - Analytical and Bioanalytical Chemistry
T1  - Determination of selected pesticides in environmental water by employing liquid-phase microextraction and liquid chromatography-tandem mass spectrometry
EP  - 2243
IS  - 6
SP  - 2233
VL  - 397
DO  - 10.1007/s00216-010-3725-5
ER  - 
@article{
author = "Trtić-Petrović, Tatjana M. and Đorđević, Jelena S. and Dujaković, Nikolina and Kumrić, Ksenija and Vasiljević, Tatjana and Laušević, Mila",
year = "2010",
abstract = "An optimised extraction and cleanup method for the analysis of pesticide in natural water samples is presented. Sixteen pesticides of different polarity and from the different chemical classes (organophosphates, triazines, benzimidazoles, carbamates, carbamides, neonicotinoides, methylureas, phenylureas and benzohydrazides), most frequently used in Serbia, were selected for the analysis. Liquid-phase microextraction in a single hollow fibre (HF-LPME) has been applied for sample preparation. The concentrations of pesticides were determined using HPLC-MS/MS method with electrospray ionisation. The extraction behaviour and selection of the experimental conditions was predicted based on log D and pK (a) values of targeted pesticides, which were calculated applying the computer software ACD/Labs PhysChem Suite v12. The influence of the donor pH and concentration of pesticides, organic phase composition as well as the extraction time on the extraction efficiency was investigated. Optimum extraction conditions were evaluated with respect to the investigated parameters of the extraction. The extraction method was validated for 10 out of 16 studied pesticides. Linear range of the pesticides was 0.1-5 A mu g L(-1) with the correlation coefficient from 0.991 to 0.9998, and the relative standard deviation for three standard measurements was between 0.2 and 11.8%. The limits of detections ranged from 0.026 to 0.237 A mu g L(-1) and the limits of quantifications from 0.094 to 0.793 A mu g L(-1). The optimised two-phase HF-LPME method was successfully applied for determination of moderately polar as well low-polar pesticides in the environmental water samples.",
journal = "Analytical and Bioanalytical Chemistry",
title = "Determination of selected pesticides in environmental water by employing liquid-phase microextraction and liquid chromatography-tandem mass spectrometry",
pages = "2243-2233",
number = "6",
volume = "397",
doi = "10.1007/s00216-010-3725-5"
}
Trtić-Petrović, T. M., Đorđević, J. S., Dujaković, N., Kumrić, K., Vasiljević, T.,& Laušević, M.. (2010). Determination of selected pesticides in environmental water by employing liquid-phase microextraction and liquid chromatography-tandem mass spectrometry. in Analytical and Bioanalytical Chemistry, 397(6), 2233-2243.
https://doi.org/10.1007/s00216-010-3725-5
Trtić-Petrović TM, Đorđević JS, Dujaković N, Kumrić K, Vasiljević T, Laušević M. Determination of selected pesticides in environmental water by employing liquid-phase microextraction and liquid chromatography-tandem mass spectrometry. in Analytical and Bioanalytical Chemistry. 2010;397(6):2233-2243.
doi:10.1007/s00216-010-3725-5 .
Trtić-Petrović, Tatjana M., Đorđević, Jelena S., Dujaković, Nikolina, Kumrić, Ksenija, Vasiljević, Tatjana, Laušević, Mila, "Determination of selected pesticides in environmental water by employing liquid-phase microextraction and liquid chromatography-tandem mass spectrometry" in Analytical and Bioanalytical Chemistry, 397, no. 6 (2010):2233-2243,
https://doi.org/10.1007/s00216-010-3725-5 . .
52
41
49

Removal of cadmium from aqueous solutions by oxidized and ethylenediamine-functionalized multi-walled carbon nanotubes

Vuković, Goran D.; Marinković, Aleksandar; Čolić, Miodrag; Ristić, Mirjana; Aleksić, Radoslav; Perić-Grujić, Aleksandra; Uskoković, Petar

(Elsevier Science Sa, Lausanne, 2010)

TY  - JOUR
AU  - Vuković, Goran D.
AU  - Marinković, Aleksandar
AU  - Čolić, Miodrag
AU  - Ristić, Mirjana
AU  - Aleksić, Radoslav
AU  - Perić-Grujić, Aleksandra
AU  - Uskoković, Petar
PY  - 2010
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1714
AB  - Surface functionalization of multi-walled carbon nanotubes (MWCNTs) by ethylenediamine, via chemical modification of carboxyl groups, using O-(7-azabenzotriazol-1-yl)-N,N,N',N'-tetramethyluronium hexafluorophosphate, was performed. The resulting materials were characterized by different techniques, such as FTIR, TGA and elemental analysis. Biocompatibility studies showed that the functionalized MWCNTs, at concentrations between 1 and 50 mu g mL(-1), were not cytotoxic for the fibroblast L929 cell line. In batch tests, the influences of solution pH, contact time, initial metal ion concentration and temperature on the sorption of Cd2+ ions onto raw-MWCNTs (raw-MWCNT), oxidized MWCNTs (o-MWCNT) and ethylenediamine-functionalized MWCNTs (e-MWCNT) were studied. The adsorption of Cd2+ ions by o-MWCNT and e-MWCNT was strongly pH dependent. The time dependent Cd2+ sorption onto raw-MWCNT, o-MWCNT and e-MWCNT can be described by a pseudo-second-order kinetic model. The Langmuir isotherm model agrees well with the equilibrium experimental data. The maximum capacity was obtained for e-MWCNT, 25.7 mgg(-1), at 45 degrees C. The thermodynamic parameters were also deduced for the adsorption of Cd2+ ions on raw-MWCNT, o-MWCNT and e-MWCNT and the results showed that the adsorption was spontaneous and endothermic.
PB  - Elsevier Science Sa, Lausanne
T2  - Chemical Engineering Journal
T1  - Removal of cadmium from aqueous solutions by oxidized and ethylenediamine-functionalized multi-walled carbon nanotubes
EP  - 248
IS  - 1
SP  - 238
VL  - 157
DO  - 10.1016/j.cej.2009.11.026
ER  - 
@article{
author = "Vuković, Goran D. and Marinković, Aleksandar and Čolić, Miodrag and Ristić, Mirjana and Aleksić, Radoslav and Perić-Grujić, Aleksandra and Uskoković, Petar",
year = "2010",
abstract = "Surface functionalization of multi-walled carbon nanotubes (MWCNTs) by ethylenediamine, via chemical modification of carboxyl groups, using O-(7-azabenzotriazol-1-yl)-N,N,N',N'-tetramethyluronium hexafluorophosphate, was performed. The resulting materials were characterized by different techniques, such as FTIR, TGA and elemental analysis. Biocompatibility studies showed that the functionalized MWCNTs, at concentrations between 1 and 50 mu g mL(-1), were not cytotoxic for the fibroblast L929 cell line. In batch tests, the influences of solution pH, contact time, initial metal ion concentration and temperature on the sorption of Cd2+ ions onto raw-MWCNTs (raw-MWCNT), oxidized MWCNTs (o-MWCNT) and ethylenediamine-functionalized MWCNTs (e-MWCNT) were studied. The adsorption of Cd2+ ions by o-MWCNT and e-MWCNT was strongly pH dependent. The time dependent Cd2+ sorption onto raw-MWCNT, o-MWCNT and e-MWCNT can be described by a pseudo-second-order kinetic model. The Langmuir isotherm model agrees well with the equilibrium experimental data. The maximum capacity was obtained for e-MWCNT, 25.7 mgg(-1), at 45 degrees C. The thermodynamic parameters were also deduced for the adsorption of Cd2+ ions on raw-MWCNT, o-MWCNT and e-MWCNT and the results showed that the adsorption was spontaneous and endothermic.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Chemical Engineering Journal",
title = "Removal of cadmium from aqueous solutions by oxidized and ethylenediamine-functionalized multi-walled carbon nanotubes",
pages = "248-238",
number = "1",
volume = "157",
doi = "10.1016/j.cej.2009.11.026"
}
Vuković, G. D., Marinković, A., Čolić, M., Ristić, M., Aleksić, R., Perić-Grujić, A.,& Uskoković, P.. (2010). Removal of cadmium from aqueous solutions by oxidized and ethylenediamine-functionalized multi-walled carbon nanotubes. in Chemical Engineering Journal
Elsevier Science Sa, Lausanne., 157(1), 238-248.
https://doi.org/10.1016/j.cej.2009.11.026
Vuković GD, Marinković A, Čolić M, Ristić M, Aleksić R, Perić-Grujić A, Uskoković P. Removal of cadmium from aqueous solutions by oxidized and ethylenediamine-functionalized multi-walled carbon nanotubes. in Chemical Engineering Journal. 2010;157(1):238-248.
doi:10.1016/j.cej.2009.11.026 .
Vuković, Goran D., Marinković, Aleksandar, Čolić, Miodrag, Ristić, Mirjana, Aleksić, Radoslav, Perić-Grujić, Aleksandra, Uskoković, Petar, "Removal of cadmium from aqueous solutions by oxidized and ethylenediamine-functionalized multi-walled carbon nanotubes" in Chemical Engineering Journal, 157, no. 1 (2010):238-248,
https://doi.org/10.1016/j.cej.2009.11.026 . .
364
297
373

Determination of pesticides in surface and ground waters by liquid chromatography-electrospray-tandem mass spectrometry

Dujaković, Nikolina; Grujić, Svetlana; Radišić, Marina; Vasiljević, Tatjana; Laušević, Mila

(Elsevier, Amsterdam, 2010)

TY  - JOUR
AU  - Dujaković, Nikolina
AU  - Grujić, Svetlana
AU  - Radišić, Marina
AU  - Vasiljević, Tatjana
AU  - Laušević, Mila
PY  - 2010
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1731
AB  - The sensitive multiresidual analytical method for simultaneous analysis of 14 most commonly used agricultural pesticides in Serbia was developed and optimized. The selected insecticides, fungicides and herbicides belong to seven chemical classes (organophosphates, neonicotinoids, carbamates, diacylhydrazines, benzimidazoles, triazines and phenylureas). The method was based on solid-phase extraction followed by liquid chromatography-tandem mass spectrometry. The following parameters that may affect the SPE procedure efficiency were optimized: the sorbent type in combination with different elution solvents, the sample pH and the sample volume. For each pesticide, MSn analysis was performed and distinctive ions and transitions were selected for identification and quantification, as well as for confirmation purposes. External matrix-matched calibration method was used to eliminate variable matrix effect and ensure precise quantification. Good recoveries (72-129%), and low limits of detection (0.4-5.5 ng L-1) and quantification (1.1-18.2 ng L-1) were achieved for all selected pesticides. The developed and optimized method was successfully applied in the analysis of several river waters, as well as ground waters in Serbia, influenced by agriculture. The most frequently detected pesticide was carbendazim. Dimethoate, carbofuran and propazine were also found in the investigated samples.
PB  - Elsevier, Amsterdam
T2  - Analytica Chimica Acta
T1  - Determination of pesticides in surface and ground waters by liquid chromatography-electrospray-tandem mass spectrometry
EP  - 72
IS  - 1
SP  - 63
VL  - 678
DO  - 10.1016/j.aca.2010.08.016
ER  - 
@article{
author = "Dujaković, Nikolina and Grujić, Svetlana and Radišić, Marina and Vasiljević, Tatjana and Laušević, Mila",
year = "2010",
abstract = "The sensitive multiresidual analytical method for simultaneous analysis of 14 most commonly used agricultural pesticides in Serbia was developed and optimized. The selected insecticides, fungicides and herbicides belong to seven chemical classes (organophosphates, neonicotinoids, carbamates, diacylhydrazines, benzimidazoles, triazines and phenylureas). The method was based on solid-phase extraction followed by liquid chromatography-tandem mass spectrometry. The following parameters that may affect the SPE procedure efficiency were optimized: the sorbent type in combination with different elution solvents, the sample pH and the sample volume. For each pesticide, MSn analysis was performed and distinctive ions and transitions were selected for identification and quantification, as well as for confirmation purposes. External matrix-matched calibration method was used to eliminate variable matrix effect and ensure precise quantification. Good recoveries (72-129%), and low limits of detection (0.4-5.5 ng L-1) and quantification (1.1-18.2 ng L-1) were achieved for all selected pesticides. The developed and optimized method was successfully applied in the analysis of several river waters, as well as ground waters in Serbia, influenced by agriculture. The most frequently detected pesticide was carbendazim. Dimethoate, carbofuran and propazine were also found in the investigated samples.",
publisher = "Elsevier, Amsterdam",
journal = "Analytica Chimica Acta",
title = "Determination of pesticides in surface and ground waters by liquid chromatography-electrospray-tandem mass spectrometry",
pages = "72-63",
number = "1",
volume = "678",
doi = "10.1016/j.aca.2010.08.016"
}
Dujaković, N., Grujić, S., Radišić, M., Vasiljević, T.,& Laušević, M.. (2010). Determination of pesticides in surface and ground waters by liquid chromatography-electrospray-tandem mass spectrometry. in Analytica Chimica Acta
Elsevier, Amsterdam., 678(1), 63-72.
https://doi.org/10.1016/j.aca.2010.08.016
Dujaković N, Grujić S, Radišić M, Vasiljević T, Laušević M. Determination of pesticides in surface and ground waters by liquid chromatography-electrospray-tandem mass spectrometry. in Analytica Chimica Acta. 2010;678(1):63-72.
doi:10.1016/j.aca.2010.08.016 .
Dujaković, Nikolina, Grujić, Svetlana, Radišić, Marina, Vasiljević, Tatjana, Laušević, Mila, "Determination of pesticides in surface and ground waters by liquid chromatography-electrospray-tandem mass spectrometry" in Analytica Chimica Acta, 678, no. 1 (2010):63-72,
https://doi.org/10.1016/j.aca.2010.08.016 . .
115
103
117

Hydrogel based on chitosan, itaconic acid and methacrylic acid as adsorbent of Cd2+ ions from aqueous solution

Milosavljević, Nedeljko; Ristić, Mirjana; Perić-Grujić, Aleksandra; Filipović, Jovanka M.; Štrbac, Svetlana; Rakočević, Zlatko Lj.; Kalagasidis Krušić, Melina

(Elsevier Science Sa, Lausanne, 2010)

TY  - JOUR
AU  - Milosavljević, Nedeljko
AU  - Ristić, Mirjana
AU  - Perić-Grujić, Aleksandra
AU  - Filipović, Jovanka M.
AU  - Štrbac, Svetlana
AU  - Rakočević, Zlatko Lj.
AU  - Kalagasidis Krušić, Melina
PY  - 2010
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1716
AB  - A hydrogel has been synthesized by ionic crosslinking of chitosan (Ch) with itaconic acid (IA), followed by a free radical polymerization and crosslinking of Ch/IA network by adding methacrylic acid and the crosslinker. The resulting material (Ch/IA/MAA hydrogel) was characterized by spectral (Fourier transform infrared (FTIR)), thermal (thermogravimetric analysis (TGA)) and structural (SEM/EDX and atomic force microscopy (AFM)) analyses. The prepared hydrogel was investigated as potential adsorbent for removal of Cd2+ ions from aqueous solution. The effect of various physico-chemical parameters such as pH, adsorbent dosage, adsorbate concentration and contact time was studied in batch experiments. The results of spectral analyses of Cd-loaded hydrogel have shown that active functional groups are -NH2, -OH and -COOH. SEM/EDX analysis and AFM surface topography and phase images indicated that apart from the adsorption on the surface of the hydrogel, sorption takes place in the bulk, as well. The experimental kinetic and equilibrium data were better fitted by pseudo-second order kinetic model and Langmuir adsorption isotherm. The parameters obtained in thermodynamic studies showed that the adsorption of Cd2+ on Ch/IA/MAA hydrogel was spontaneous and exothermic in nature. Desorption studies were carried out using acid leaching (HNO3) and it has been shown that the regenerated hydrogel can be reused three times without any loss of adsorption capacity. The maximum adsorption of 285.7 mg/g has been obtained at pH 5.5 and the results of adsorption/desorption experiments implies that the Ch/IA/MAA hydrogel may be used as efficient sorbent for removal of Cd2+ ions from aqueous solution.
PB  - Elsevier Science Sa, Lausanne
T2  - Chemical Engineering Journal
T1  - Hydrogel based on chitosan, itaconic acid and methacrylic acid as adsorbent of Cd2+ ions from aqueous solution
EP  - 562
IS  - 2
SP  - 554
VL  - 165
DO  - 10.1016/j.cej.2010.09.072
ER  - 
@article{
author = "Milosavljević, Nedeljko and Ristić, Mirjana and Perić-Grujić, Aleksandra and Filipović, Jovanka M. and Štrbac, Svetlana and Rakočević, Zlatko Lj. and Kalagasidis Krušić, Melina",
year = "2010",
abstract = "A hydrogel has been synthesized by ionic crosslinking of chitosan (Ch) with itaconic acid (IA), followed by a free radical polymerization and crosslinking of Ch/IA network by adding methacrylic acid and the crosslinker. The resulting material (Ch/IA/MAA hydrogel) was characterized by spectral (Fourier transform infrared (FTIR)), thermal (thermogravimetric analysis (TGA)) and structural (SEM/EDX and atomic force microscopy (AFM)) analyses. The prepared hydrogel was investigated as potential adsorbent for removal of Cd2+ ions from aqueous solution. The effect of various physico-chemical parameters such as pH, adsorbent dosage, adsorbate concentration and contact time was studied in batch experiments. The results of spectral analyses of Cd-loaded hydrogel have shown that active functional groups are -NH2, -OH and -COOH. SEM/EDX analysis and AFM surface topography and phase images indicated that apart from the adsorption on the surface of the hydrogel, sorption takes place in the bulk, as well. The experimental kinetic and equilibrium data were better fitted by pseudo-second order kinetic model and Langmuir adsorption isotherm. The parameters obtained in thermodynamic studies showed that the adsorption of Cd2+ on Ch/IA/MAA hydrogel was spontaneous and exothermic in nature. Desorption studies were carried out using acid leaching (HNO3) and it has been shown that the regenerated hydrogel can be reused three times without any loss of adsorption capacity. The maximum adsorption of 285.7 mg/g has been obtained at pH 5.5 and the results of adsorption/desorption experiments implies that the Ch/IA/MAA hydrogel may be used as efficient sorbent for removal of Cd2+ ions from aqueous solution.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Chemical Engineering Journal",
title = "Hydrogel based on chitosan, itaconic acid and methacrylic acid as adsorbent of Cd2+ ions from aqueous solution",
pages = "562-554",
number = "2",
volume = "165",
doi = "10.1016/j.cej.2010.09.072"
}
Milosavljević, N., Ristić, M., Perić-Grujić, A., Filipović, J. M., Štrbac, S., Rakočević, Z. Lj.,& Kalagasidis Krušić, M.. (2010). Hydrogel based on chitosan, itaconic acid and methacrylic acid as adsorbent of Cd2+ ions from aqueous solution. in Chemical Engineering Journal
Elsevier Science Sa, Lausanne., 165(2), 554-562.
https://doi.org/10.1016/j.cej.2010.09.072
Milosavljević N, Ristić M, Perić-Grujić A, Filipović JM, Štrbac S, Rakočević ZL, Kalagasidis Krušić M. Hydrogel based on chitosan, itaconic acid and methacrylic acid as adsorbent of Cd2+ ions from aqueous solution. in Chemical Engineering Journal. 2010;165(2):554-562.
doi:10.1016/j.cej.2010.09.072 .
Milosavljević, Nedeljko, Ristić, Mirjana, Perić-Grujić, Aleksandra, Filipović, Jovanka M., Štrbac, Svetlana, Rakočević, Zlatko Lj., Kalagasidis Krušić, Melina, "Hydrogel based on chitosan, itaconic acid and methacrylic acid as adsorbent of Cd2+ ions from aqueous solution" in Chemical Engineering Journal, 165, no. 2 (2010):554-562,
https://doi.org/10.1016/j.cej.2010.09.072 . .
46
44
46

The influence of PET containers on antimony concentration in bottled drinking water

Perić-Grujić, Aleksandra; Radmanovac, Aleksandar R.; Stojanov, Aleksander M.; Pocajt, Viktor; Ristić, Mirjana

(Association of Chemical Engineers of Serbia, 2010)

TY  - JOUR
AU  - Perić-Grujić, Aleksandra
AU  - Radmanovac, Aleksandar R.
AU  - Stojanov, Aleksander M.
AU  - Pocajt, Viktor
AU  - Ristić, Mirjana
PY  - 2010
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1649
AB  - Antimony trioxide (Sb2O3) is the most frequently used catalyst in the polyethylene terephthalate (PET) manufacture. As a result, antimony is incorporated into PET bottles at concentration level of 100-300 mg/kg. PET containers are used for drinking water and beverages, as well as food packaging and in the pharmaceutical industry. Thus, it is important to understand the factors that may influence the release of antimony from the catalysts into water and other products, since antimony is potentially toxic trace element. In this paper, the antimony content in nine brands of bottled mineral and spring water from Serbia, and seven brands of bottled mineral and spring water from EU countries was analyzed. The measurements were conducted using the inductively coupled plasma-mass spectrometry (ICP-MS) technique. In the all examined samples the antimony concentration was bellow the maximum contaminant level of 5 μg/L prescribed by the Serbian and EU regulations. Comparison of the content of antimony in PET bottled waters with the content of antimony in water bottled commercially in glass and the natural content of antimony in pristine groundwaters, provides explicit evidence of antimony leaching from PET containers. Since waters bottled in PET have much greater concentration ratio of Sb to Pb than corresponding pristine groundwaters, it can be assumed that bottled waters cannot be used as the relevant source for the study of the natural antimony content in groundwaters. There is a clear relation between the quality of water in bottles (composition, ion strength) and antimony leaching rate. Moreover, while the rate of antimony leaching is slow at temperatures below 60°C, at the temperature range of 60-80°C antimony release occurs and rapidly reaches maximum contaminant level. As antimony can cause both acute and chronic health problems, factors that promote the increase of antimony concentration should be avoided.
AB  - U ovom radu je ispitivan sadržaj antimona u uzorcima flaširanih mineralnih i izvorskih voda sa domaćeg tržišta, kao i sa tržišta nekih zemalja Evropske Unije, primenom indukovano spregnute plazme sa masenom spektrometrijom. Ispitivanja su vršena sa ciljem da se utvrdi u kojoj meri PET ambalaža utiče na povećanje njegove koncentracije u flaširanim vodama, imajući u vidu da antimon, koji sama ambalaža sadrži, spada u grupu potencijalno toksičnih elemenata. Dobijeni rezultati pokazali su da uzorci voda flaširani u PET ambalaži uvek sadrže antimon u većoj koncentraciji u odnosu na odgovarajuće uzorke koji nisu bili flaširani u PET ambalaži. I pored činjenice da dolazi do otpuštanja antimona iz PET ambalaže, ni u jednom od ispitanih uzoraka voda sadržaj antimona nije prevazilazio maksimalno dozvoljene vrednosti regulisane propisima o kvalitetu vode za piće i kvalitetu flaširanih voda Republike Srbije i Evropske Unije.
PB  - Association of Chemical Engineers of Serbia
T2  - Hemijska industrija
T1  - The influence of PET containers on antimony concentration in bottled drinking water
T1  - Uticaj PET ambalaže na sadržaj antimona u flaširanim vodama za piće
EP  - 310
IS  - 4
SP  - 305
VL  - 64
DO  - 10.2298/HEMIND100419037P
ER  - 
@article{
author = "Perić-Grujić, Aleksandra and Radmanovac, Aleksandar R. and Stojanov, Aleksander M. and Pocajt, Viktor and Ristić, Mirjana",
year = "2010",
abstract = "Antimony trioxide (Sb2O3) is the most frequently used catalyst in the polyethylene terephthalate (PET) manufacture. As a result, antimony is incorporated into PET bottles at concentration level of 100-300 mg/kg. PET containers are used for drinking water and beverages, as well as food packaging and in the pharmaceutical industry. Thus, it is important to understand the factors that may influence the release of antimony from the catalysts into water and other products, since antimony is potentially toxic trace element. In this paper, the antimony content in nine brands of bottled mineral and spring water from Serbia, and seven brands of bottled mineral and spring water from EU countries was analyzed. The measurements were conducted using the inductively coupled plasma-mass spectrometry (ICP-MS) technique. In the all examined samples the antimony concentration was bellow the maximum contaminant level of 5 μg/L prescribed by the Serbian and EU regulations. Comparison of the content of antimony in PET bottled waters with the content of antimony in water bottled commercially in glass and the natural content of antimony in pristine groundwaters, provides explicit evidence of antimony leaching from PET containers. Since waters bottled in PET have much greater concentration ratio of Sb to Pb than corresponding pristine groundwaters, it can be assumed that bottled waters cannot be used as the relevant source for the study of the natural antimony content in groundwaters. There is a clear relation between the quality of water in bottles (composition, ion strength) and antimony leaching rate. Moreover, while the rate of antimony leaching is slow at temperatures below 60°C, at the temperature range of 60-80°C antimony release occurs and rapidly reaches maximum contaminant level. As antimony can cause both acute and chronic health problems, factors that promote the increase of antimony concentration should be avoided., U ovom radu je ispitivan sadržaj antimona u uzorcima flaširanih mineralnih i izvorskih voda sa domaćeg tržišta, kao i sa tržišta nekih zemalja Evropske Unije, primenom indukovano spregnute plazme sa masenom spektrometrijom. Ispitivanja su vršena sa ciljem da se utvrdi u kojoj meri PET ambalaža utiče na povećanje njegove koncentracije u flaširanim vodama, imajući u vidu da antimon, koji sama ambalaža sadrži, spada u grupu potencijalno toksičnih elemenata. Dobijeni rezultati pokazali su da uzorci voda flaširani u PET ambalaži uvek sadrže antimon u većoj koncentraciji u odnosu na odgovarajuće uzorke koji nisu bili flaširani u PET ambalaži. I pored činjenice da dolazi do otpuštanja antimona iz PET ambalaže, ni u jednom od ispitanih uzoraka voda sadržaj antimona nije prevazilazio maksimalno dozvoljene vrednosti regulisane propisima o kvalitetu vode za piće i kvalitetu flaširanih voda Republike Srbije i Evropske Unije.",
publisher = "Association of Chemical Engineers of Serbia",
journal = "Hemijska industrija",
title = "The influence of PET containers on antimony concentration in bottled drinking water, Uticaj PET ambalaže na sadržaj antimona u flaširanim vodama za piće",
pages = "310-305",
number = "4",
volume = "64",
doi = "10.2298/HEMIND100419037P"
}
Perić-Grujić, A., Radmanovac, A. R., Stojanov, A. M., Pocajt, V.,& Ristić, M.. (2010). The influence of PET containers on antimony concentration in bottled drinking water. in Hemijska industrija
Association of Chemical Engineers of Serbia., 64(4), 305-310.
https://doi.org/10.2298/HEMIND100419037P
Perić-Grujić A, Radmanovac AR, Stojanov AM, Pocajt V, Ristić M. The influence of PET containers on antimony concentration in bottled drinking water. in Hemijska industrija. 2010;64(4):305-310.
doi:10.2298/HEMIND100419037P .
Perić-Grujić, Aleksandra, Radmanovac, Aleksandar R., Stojanov, Aleksander M., Pocajt, Viktor, Ristić, Mirjana, "The influence of PET containers on antimony concentration in bottled drinking water" in Hemijska industrija, 64, no. 4 (2010):305-310,
https://doi.org/10.2298/HEMIND100419037P . .
3
2
4

Urban deciduous tree leaves as biomonitors of trace element (As, V and Cd) atmospheric pollution in Belgrade, Serbia

Šućur, Katarina M.; Aničić, Mira P.; Tomašević, Milica N.; Antanasijević, Davor; Perić-Grujić, Aleksandra; Ristić, Mirjana

(Serbian Chemical Society, Belgrade, 2010)

TY  - JOUR
AU  - Šućur, Katarina M.
AU  - Aničić, Mira P.
AU  - Tomašević, Milica N.
AU  - Antanasijević, Davor
AU  - Perić-Grujić, Aleksandra
AU  - Ristić, Mirjana
PY  - 2010
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1596
AB  - Leaves of common deciduous trees: horse chestnut (Aesculus hippocastanum) and linden (Tilia spp.) from three parks within the urban area of Belgrade were studied as biomonitors of trace element (As, V, and Cd) atmospheric pollution. The May-September trace element accumulation in the leaves, and their temporal trends, were assayed in a multi-year period (2002-2006). Significant accumulation in the leaves was evident for As and V, but not so regularly for Cd. Slightly decreasing temporal trends of V and As accumulated in the leaf tissues were observed over the years. During the time span, the concentrations of Cd remained approximately on the same level, except in May 2002 and September 2005, when a rapid increase was observed. The May-September accumulations of As and V were higher in horse chestnut than in linden, although both may be used as biomonitors for these elements, and optionally for Cd in conditions of its high atmospheric loadings.
AB  - Jedna od posledica intenzivnog ekonomskog i industrijskog razvoja je povećana emisija zagađujućih supstancija u atmosferu. Drveće, posebno u urbanim sredinama, veoma je značajno sa aspekta prečišćavanja vazduha; pored toga, uočeno je da postoji korelacija između koncentracije pojedinih zagađujućih materija u vazduhu i u lišću drveća, što je iskorišćeno za biomonitoring kvaliteta vazduha. U ovom radu je ispitivana mogućnost biomonitoringa elemenata u tragovima u vazduhu pomoću dve vrste listopadnog drveća, divljeg kestena (Aesculus hippocastanum) i lipe (Tilia spp.), koje su veoma zastupljene u Beogradu. Uzorci su sakupljani na početku vegetacionog perioda, u maju, kao i na kraju vegetacionog perioda, u septembru, tokom pet godina, od 2002. do 2006. godine. U eksperimentalnom delu izvršena je analiza sadržaja elemenata u tragovima (arsen, vanadijum, kadmijum) u listovima navedenih vrsta drveća sakupljenim sa tri lokacije u Beogradu (Karađorđev park, Studentski park i Botanička bašta), koje su odabrane zbog intenzivnog saobraćaja. Poređenjem dobijenih vrednosti sa koncentracijama ispitivanih elemenata u suspendovanim česticama u vazduhu određen je stepen akumulacije i zaključeno je da se ispitivane vrste mogu koristiti za biomonitoring kvaliteta vazduha, odnosno njegove zagađenosti ispitivanim elementima u tragovima, pri čemu je divlji kesten imao bolje akumulativne sposobnosti.
PB  - Serbian Chemical Society, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Urban deciduous tree leaves as biomonitors of trace element (As, V and Cd) atmospheric pollution in Belgrade, Serbia
T1  - Ispitivanje zagađenosti vazduha u Beogradu elementima u tragovima (As, V, Cd) iz listova listopadnog drveća
EP  - 1461
IS  - 10
SP  - 1453
VL  - 75
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1596
ER  - 
@article{
author = "Šućur, Katarina M. and Aničić, Mira P. and Tomašević, Milica N. and Antanasijević, Davor and Perić-Grujić, Aleksandra and Ristić, Mirjana",
year = "2010",
abstract = "Leaves of common deciduous trees: horse chestnut (Aesculus hippocastanum) and linden (Tilia spp.) from three parks within the urban area of Belgrade were studied as biomonitors of trace element (As, V, and Cd) atmospheric pollution. The May-September trace element accumulation in the leaves, and their temporal trends, were assayed in a multi-year period (2002-2006). Significant accumulation in the leaves was evident for As and V, but not so regularly for Cd. Slightly decreasing temporal trends of V and As accumulated in the leaf tissues were observed over the years. During the time span, the concentrations of Cd remained approximately on the same level, except in May 2002 and September 2005, when a rapid increase was observed. The May-September accumulations of As and V were higher in horse chestnut than in linden, although both may be used as biomonitors for these elements, and optionally for Cd in conditions of its high atmospheric loadings., Jedna od posledica intenzivnog ekonomskog i industrijskog razvoja je povećana emisija zagađujućih supstancija u atmosferu. Drveće, posebno u urbanim sredinama, veoma je značajno sa aspekta prečišćavanja vazduha; pored toga, uočeno je da postoji korelacija između koncentracije pojedinih zagađujućih materija u vazduhu i u lišću drveća, što je iskorišćeno za biomonitoring kvaliteta vazduha. U ovom radu je ispitivana mogućnost biomonitoringa elemenata u tragovima u vazduhu pomoću dve vrste listopadnog drveća, divljeg kestena (Aesculus hippocastanum) i lipe (Tilia spp.), koje su veoma zastupljene u Beogradu. Uzorci su sakupljani na početku vegetacionog perioda, u maju, kao i na kraju vegetacionog perioda, u septembru, tokom pet godina, od 2002. do 2006. godine. U eksperimentalnom delu izvršena je analiza sadržaja elemenata u tragovima (arsen, vanadijum, kadmijum) u listovima navedenih vrsta drveća sakupljenim sa tri lokacije u Beogradu (Karađorđev park, Studentski park i Botanička bašta), koje su odabrane zbog intenzivnog saobraćaja. Poređenjem dobijenih vrednosti sa koncentracijama ispitivanih elemenata u suspendovanim česticama u vazduhu određen je stepen akumulacije i zaključeno je da se ispitivane vrste mogu koristiti za biomonitoring kvaliteta vazduha, odnosno njegove zagađenosti ispitivanim elementima u tragovima, pri čemu je divlji kesten imao bolje akumulativne sposobnosti.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Urban deciduous tree leaves as biomonitors of trace element (As, V and Cd) atmospheric pollution in Belgrade, Serbia, Ispitivanje zagađenosti vazduha u Beogradu elementima u tragovima (As, V, Cd) iz listova listopadnog drveća",
pages = "1461-1453",
number = "10",
volume = "75",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1596"
}
Šućur, K. M., Aničić, M. P., Tomašević, M. N., Antanasijević, D., Perić-Grujić, A.,& Ristić, M.. (2010). Urban deciduous tree leaves as biomonitors of trace element (As, V and Cd) atmospheric pollution in Belgrade, Serbia. in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 75(10), 1453-1461.
https://hdl.handle.net/21.15107/rcub_technorep_1596
Šućur KM, Aničić MP, Tomašević MN, Antanasijević D, Perić-Grujić A, Ristić M. Urban deciduous tree leaves as biomonitors of trace element (As, V and Cd) atmospheric pollution in Belgrade, Serbia. in Journal of the Serbian Chemical Society. 2010;75(10):1453-1461.
https://hdl.handle.net/21.15107/rcub_technorep_1596 .
Šućur, Katarina M., Aničić, Mira P., Tomašević, Milica N., Antanasijević, Davor, Perić-Grujić, Aleksandra, Ristić, Mirjana, "Urban deciduous tree leaves as biomonitors of trace element (As, V and Cd) atmospheric pollution in Belgrade, Serbia" in Journal of the Serbian Chemical Society, 75, no. 10 (2010):1453-1461,
https://hdl.handle.net/21.15107/rcub_technorep_1596 .
14
16

Removal of organochlorine pesticides from water using virgin and regenerated granular activated carbon

Ninković, Mirjana B.; Petrović, Rada; Laušević, Mila

(Serbian Chemical Society, Belgrade, 2010)

TY  - JOUR
AU  - Ninković, Mirjana B.
AU  - Petrović, Rada
AU  - Laušević, Mila
PY  - 2010
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1601
AB  - Public water systems use granular activated carbon in order to eliminate pesticides. After saturation, the used activated carbon is regenerated and reused in order to reduce the costs of water production and minimize waste. In this study, the adsorption of 10 different chlorinated pesticides from water using columns packed with commercial virgin and regenerated granular activated carbon was simulated in order to compare their adsorption capacities for different chlorinated pesticides. The breakthrough curves showed that chlorinated pesticides from the group of hexachlorocyclohexane (HCH) were poorly adsorbed, followed by cyclodiens as averagely adsorbed and the derivatives of halogenated aromatic hydrocarbons (DDT) as strongly adsorbed. However, the adsorption capacity of regenerated granular activated carbon was considerably lower for tested pesticides compared to the virgin granular carbon. In addition, rinsing of the pesticides after the saturation point is a far more efficient process on regenerated carbon.
AB  - Postrojenja za pripremu vode u mnogim zemljama koriste granulisani aktivni ugalj za uklanjanje ostataka pesticida. Uobičajeno je da se aktivni ugalj regeneriše i ponovo koristi da bi se smanjili troškovi proizvodnje vode za piće i da bi se smanjila količina otpada. U ovom radu smo ispitivali adsorpciju organohlornih pesticida iz vodenog rastvora 10 različitih pesticida na kolonama ispunjenim komercijalnim svežim i regenerisanim granulisanim aktivnim ugljem. Utvrđene su adsorpcione sposobnosti granulisanog uglja za različite pesticide. Krive proboja na ovim kolonama pokazuju da se organohlorni pesticidi iz grupe heksahlorocikloheksana najslabije adsorbuju, zatim hlorovani ciklodieni, a najjače pesticidi iz grupe DDT. Utvrđeno je da je adsorpcioni kapacitet regenerisanog aktivnog uglja znatno manji od adsorpcionog kapaciteta svežeg aktivnog uglja, a ispiranje pesticida je mnogo efikasnije posle regeneracije.
PB  - Serbian Chemical Society, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Removal of organochlorine pesticides from water using virgin and regenerated granular activated carbon
T1  - Uklanjanje pesticida iz vode na granulisanom aktivnom uglju
EP  - 573
IS  - 4
SP  - 565
VL  - 75
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1601
ER  - 
@article{
author = "Ninković, Mirjana B. and Petrović, Rada and Laušević, Mila",
year = "2010",
abstract = "Public water systems use granular activated carbon in order to eliminate pesticides. After saturation, the used activated carbon is regenerated and reused in order to reduce the costs of water production and minimize waste. In this study, the adsorption of 10 different chlorinated pesticides from water using columns packed with commercial virgin and regenerated granular activated carbon was simulated in order to compare their adsorption capacities for different chlorinated pesticides. The breakthrough curves showed that chlorinated pesticides from the group of hexachlorocyclohexane (HCH) were poorly adsorbed, followed by cyclodiens as averagely adsorbed and the derivatives of halogenated aromatic hydrocarbons (DDT) as strongly adsorbed. However, the adsorption capacity of regenerated granular activated carbon was considerably lower for tested pesticides compared to the virgin granular carbon. In addition, rinsing of the pesticides after the saturation point is a far more efficient process on regenerated carbon., Postrojenja za pripremu vode u mnogim zemljama koriste granulisani aktivni ugalj za uklanjanje ostataka pesticida. Uobičajeno je da se aktivni ugalj regeneriše i ponovo koristi da bi se smanjili troškovi proizvodnje vode za piće i da bi se smanjila količina otpada. U ovom radu smo ispitivali adsorpciju organohlornih pesticida iz vodenog rastvora 10 različitih pesticida na kolonama ispunjenim komercijalnim svežim i regenerisanim granulisanim aktivnim ugljem. Utvrđene su adsorpcione sposobnosti granulisanog uglja za različite pesticide. Krive proboja na ovim kolonama pokazuju da se organohlorni pesticidi iz grupe heksahlorocikloheksana najslabije adsorbuju, zatim hlorovani ciklodieni, a najjače pesticidi iz grupe DDT. Utvrđeno je da je adsorpcioni kapacitet regenerisanog aktivnog uglja znatno manji od adsorpcionog kapaciteta svežeg aktivnog uglja, a ispiranje pesticida je mnogo efikasnije posle regeneracije.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Removal of organochlorine pesticides from water using virgin and regenerated granular activated carbon, Uklanjanje pesticida iz vode na granulisanom aktivnom uglju",
pages = "573-565",
number = "4",
volume = "75",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1601"
}
Ninković, M. B., Petrović, R.,& Laušević, M.. (2010). Removal of organochlorine pesticides from water using virgin and regenerated granular activated carbon. in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 75(4), 565-573.
https://hdl.handle.net/21.15107/rcub_technorep_1601
Ninković MB, Petrović R, Laušević M. Removal of organochlorine pesticides from water using virgin and regenerated granular activated carbon. in Journal of the Serbian Chemical Society. 2010;75(4):565-573.
https://hdl.handle.net/21.15107/rcub_technorep_1601 .
Ninković, Mirjana B., Petrović, Rada, Laušević, Mila, "Removal of organochlorine pesticides from water using virgin and regenerated granular activated carbon" in Journal of the Serbian Chemical Society, 75, no. 4 (2010):565-573,
https://hdl.handle.net/21.15107/rcub_technorep_1601 .
12
20

Određivanje sadržaja teških metala u čajevima sa tržišta u Beogradu, Srbija

Perić-Grujić, Aleksandra A.; Pocajt, Viktor V.; Ristić, Mirjana Đ.

(Savez hemijskih inženjera Srbije, 2009)

TY  - JOUR
AU  - Perić-Grujić, Aleksandra A.
AU  - Pocajt, Viktor V.
AU  - Ristić, Mirjana Đ.
PY  - 2009
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1403
AB  - U ovom radu su ispitivane koncentracije bakra, cinka, mangana, nikla, kadmijuma i olova u uzorcima čajeva (crni, zeleni, nana, kamilica) uzetih iz lokalnih prodavnica u Beogradu u maju 2008. godine. Priprema uzoraka vršena je mokrom i suvom digestijom. Koncentracije odabranih metala u rastvorima posle digestije određivane su plamenom atomskom apsorpionom spektrofotometrijom. U svim uzorcima posle suve digestije, najviša je bila koncentracija mangana (26,0 do 199,3 mg/kg), dok kadmijum nije detektovan ni u jednom uzorku. Sadržaj bakra je varirao od 7,7 do 14,1 mg/kg, cinka od 6,9 do 26,9 mg/kg, olova od 5,1 do 13,7 mg/kg, a nikla od 1,4 do 4,4 mg/kg. U oba ispitivana uzorka čaja od lista nane koncentracija olova je bila iznad 10 mg/kg, koliko je dozvoljeno zakonskom regulativom Republike Srbije.
AB  - Tea is one of the world's most popular beverages. Economic and social interest in tea is clear from the fact that about 18-20 billion tea cups are being consumed daily in the world. Consequently, chemical components in tea leaves have received great interest because they are related to health and disease. Various reports have discussed the potential health implications of some chemical factors such as heavy metals in tea, particularly since tea bush is known to accumulate trace metals. Metallic constituents of tea leaves depend on the type of tea and geological origin. In the present study four tea samples (two black and two green) and four herbal tea samples (two Mentha piperita and two Matricaria chammomilla) were collected from the local market in Belgrade, Serbia, in May 2008. The sample preparation has been performed using wet and dry digestion procedures. The metal content (Cu, Zn, Mn, Cd, Ni and Pb) in the digested samples has been analyzed by using flame atomic absorption spectrometry. The comparison of wet and dry digestion has shown significant differences in results, indicating that dry digestion is more appropriate method. The levels of the examined metals obtained by dry digestion in this study compared well with those reported for tea samples from some other parts of the world. Among the investigated metals, the most abundant nutritive metal, Mn, has been the highest with 26.0 to 199.3 mg/kg, while fortunately toxic heavy metal, Cd, has been below the detection limit (0.1 mg/kg). The concentrations of lead and nickel have been in the range 5.1-13.7 and 1.4- -4.4, respectively. The content of lead in two samples (Mentha piperita) has been higher than the maximum permissible concentration of 10 mg/kg specified by the national legislation.
PB  - Savez hemijskih inženjera Srbije
T2  - Hemijska industrija
T1  - Određivanje sadržaja teških metala u čajevima sa tržišta u Beogradu, Srbija
T1  - Determination of heavy metal concentrations in tea samples taken from Belgrade market, Serbia
EP  - 436
IS  - 5
SP  - 433
VL  - 63
DO  - 10.2298/HEMIND0905433P
ER  - 
@article{
author = "Perić-Grujić, Aleksandra A. and Pocajt, Viktor V. and Ristić, Mirjana Đ.",
year = "2009",
abstract = "U ovom radu su ispitivane koncentracije bakra, cinka, mangana, nikla, kadmijuma i olova u uzorcima čajeva (crni, zeleni, nana, kamilica) uzetih iz lokalnih prodavnica u Beogradu u maju 2008. godine. Priprema uzoraka vršena je mokrom i suvom digestijom. Koncentracije odabranih metala u rastvorima posle digestije određivane su plamenom atomskom apsorpionom spektrofotometrijom. U svim uzorcima posle suve digestije, najviša je bila koncentracija mangana (26,0 do 199,3 mg/kg), dok kadmijum nije detektovan ni u jednom uzorku. Sadržaj bakra je varirao od 7,7 do 14,1 mg/kg, cinka od 6,9 do 26,9 mg/kg, olova od 5,1 do 13,7 mg/kg, a nikla od 1,4 do 4,4 mg/kg. U oba ispitivana uzorka čaja od lista nane koncentracija olova je bila iznad 10 mg/kg, koliko je dozvoljeno zakonskom regulativom Republike Srbije., Tea is one of the world's most popular beverages. Economic and social interest in tea is clear from the fact that about 18-20 billion tea cups are being consumed daily in the world. Consequently, chemical components in tea leaves have received great interest because they are related to health and disease. Various reports have discussed the potential health implications of some chemical factors such as heavy metals in tea, particularly since tea bush is known to accumulate trace metals. Metallic constituents of tea leaves depend on the type of tea and geological origin. In the present study four tea samples (two black and two green) and four herbal tea samples (two Mentha piperita and two Matricaria chammomilla) were collected from the local market in Belgrade, Serbia, in May 2008. The sample preparation has been performed using wet and dry digestion procedures. The metal content (Cu, Zn, Mn, Cd, Ni and Pb) in the digested samples has been analyzed by using flame atomic absorption spectrometry. The comparison of wet and dry digestion has shown significant differences in results, indicating that dry digestion is more appropriate method. The levels of the examined metals obtained by dry digestion in this study compared well with those reported for tea samples from some other parts of the world. Among the investigated metals, the most abundant nutritive metal, Mn, has been the highest with 26.0 to 199.3 mg/kg, while fortunately toxic heavy metal, Cd, has been below the detection limit (0.1 mg/kg). The concentrations of lead and nickel have been in the range 5.1-13.7 and 1.4- -4.4, respectively. The content of lead in two samples (Mentha piperita) has been higher than the maximum permissible concentration of 10 mg/kg specified by the national legislation.",
publisher = "Savez hemijskih inženjera Srbije",
journal = "Hemijska industrija",
title = "Određivanje sadržaja teških metala u čajevima sa tržišta u Beogradu, Srbija, Determination of heavy metal concentrations in tea samples taken from Belgrade market, Serbia",
pages = "436-433",
number = "5",
volume = "63",
doi = "10.2298/HEMIND0905433P"
}
Perić-Grujić, A. A., Pocajt, V. V.,& Ristić, M. Đ.. (2009). Određivanje sadržaja teških metala u čajevima sa tržišta u Beogradu, Srbija. in Hemijska industrija
Savez hemijskih inženjera Srbije., 63(5), 433-436.
https://doi.org/10.2298/HEMIND0905433P
Perić-Grujić AA, Pocajt VV, Ristić MĐ. Određivanje sadržaja teških metala u čajevima sa tržišta u Beogradu, Srbija. in Hemijska industrija. 2009;63(5):433-436.
doi:10.2298/HEMIND0905433P .
Perić-Grujić, Aleksandra A., Pocajt, Viktor V., Ristić, Mirjana Đ., "Određivanje sadržaja teških metala u čajevima sa tržišta u Beogradu, Srbija" in Hemijska industrija, 63, no. 5 (2009):433-436,
https://doi.org/10.2298/HEMIND0905433P . .
9
8
13

Electrospray mass spectrometric studies of a potential antitumor drug and its analogous platinum(II) and platinum(IV) complexes with the ethylenediamine-N,N '-di-3-propanoato ligand and its dibutyl ester

Kaluđerović, Goran N.; Vasiljević, Tanja M.; Laušević, Mila D.; Gaballa, Akmal S.; Sabo, Tibor

(Springer Wien, Wien, 2009)

TY  - JOUR
AU  - Kaluđerović, Goran N.
AU  - Vasiljević, Tanja M.
AU  - Laušević, Mila D.
AU  - Gaballa, Akmal S.
AU  - Sabo, Tibor
PY  - 2009
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5526
AB  - The electrospray mass spectrometric (ESI-MS) behavior of the complexes trans-dichloro(ethylenediamine-N, N'-di-3-propionato) platinum(IV), trans-dibromo(ethylenediamine-N, N'-di-3-propionato) platinum( IV), dichloro (ethylenediamine-N,N'-di-3-propionic acid) platinum(II), tetrachloro(O,O'-di-n-butyl-ethylenediamine-N,N'-di-3-propanoate) platinum(IV), chlorotribromo(O,O'-di-n-butylethylenediamine-N,N'-di-3-propanoate) platinum(IV), and dichloro(O,O'-di-n-butyl-ethylenediamine-N,N'-di-3-propanoate) platinum( II), with the formulae trans-[PtCl(2) (eddp)] (1), trans-[PtBr(2)(eddp)] (2), [PtCl(2)(H(2)eddp)] (3), [PtCl(4)(Bu(2)eddp)] (4), [PtBr(3)Cl(Bu(2)eddp)] (5), and [PtCl(2)(Bu(2)eddp)]center dot H(2)O (6), is reported. The deprotonated molecular ions or halide adducts are usually observed. ESI-MS data demonstrate the usefulness of the method for efficient characterization of metal complexes in solution.
PB  - Springer Wien, Wien
T2  - Monatshefte Fur Chemie
T1  - Electrospray mass spectrometric studies of a potential antitumor drug and its analogous platinum(II) and platinum(IV) complexes with the ethylenediamine-N,N '-di-3-propanoato ligand and its dibutyl ester
EP  - 557
IS  - 5
SP  - 553
VL  - 140
DO  - 10.1007/s00706-008-0088-0
ER  - 
@article{
author = "Kaluđerović, Goran N. and Vasiljević, Tanja M. and Laušević, Mila D. and Gaballa, Akmal S. and Sabo, Tibor",
year = "2009",
abstract = "The electrospray mass spectrometric (ESI-MS) behavior of the complexes trans-dichloro(ethylenediamine-N, N'-di-3-propionato) platinum(IV), trans-dibromo(ethylenediamine-N, N'-di-3-propionato) platinum( IV), dichloro (ethylenediamine-N,N'-di-3-propionic acid) platinum(II), tetrachloro(O,O'-di-n-butyl-ethylenediamine-N,N'-di-3-propanoate) platinum(IV), chlorotribromo(O,O'-di-n-butylethylenediamine-N,N'-di-3-propanoate) platinum(IV), and dichloro(O,O'-di-n-butyl-ethylenediamine-N,N'-di-3-propanoate) platinum( II), with the formulae trans-[PtCl(2) (eddp)] (1), trans-[PtBr(2)(eddp)] (2), [PtCl(2)(H(2)eddp)] (3), [PtCl(4)(Bu(2)eddp)] (4), [PtBr(3)Cl(Bu(2)eddp)] (5), and [PtCl(2)(Bu(2)eddp)]center dot H(2)O (6), is reported. The deprotonated molecular ions or halide adducts are usually observed. ESI-MS data demonstrate the usefulness of the method for efficient characterization of metal complexes in solution.",
publisher = "Springer Wien, Wien",
journal = "Monatshefte Fur Chemie",
title = "Electrospray mass spectrometric studies of a potential antitumor drug and its analogous platinum(II) and platinum(IV) complexes with the ethylenediamine-N,N '-di-3-propanoato ligand and its dibutyl ester",
pages = "557-553",
number = "5",
volume = "140",
doi = "10.1007/s00706-008-0088-0"
}
Kaluđerović, G. N., Vasiljević, T. M., Laušević, M. D., Gaballa, A. S.,& Sabo, T.. (2009). Electrospray mass spectrometric studies of a potential antitumor drug and its analogous platinum(II) and platinum(IV) complexes with the ethylenediamine-N,N '-di-3-propanoato ligand and its dibutyl ester. in Monatshefte Fur Chemie
Springer Wien, Wien., 140(5), 553-557.
https://doi.org/10.1007/s00706-008-0088-0
Kaluđerović GN, Vasiljević TM, Laušević MD, Gaballa AS, Sabo T. Electrospray mass spectrometric studies of a potential antitumor drug and its analogous platinum(II) and platinum(IV) complexes with the ethylenediamine-N,N '-di-3-propanoato ligand and its dibutyl ester. in Monatshefte Fur Chemie. 2009;140(5):553-557.
doi:10.1007/s00706-008-0088-0 .
Kaluđerović, Goran N., Vasiljević, Tanja M., Laušević, Mila D., Gaballa, Akmal S., Sabo, Tibor, "Electrospray mass spectrometric studies of a potential antitumor drug and its analogous platinum(II) and platinum(IV) complexes with the ethylenediamine-N,N '-di-3-propanoato ligand and its dibutyl ester" in Monatshefte Fur Chemie, 140, no. 5 (2009):553-557,
https://doi.org/10.1007/s00706-008-0088-0 . .
6
6
6

Determination of selected pesticides in fruit juices by matrix solid-phase dispersion and liquid chromatography-tandem mass spectrometry

Radišić, Marina; Grujić, Svetlana; Vasiljević, Tatjana; Laušević, Mila

(Elsevier Sci Ltd, Oxford, 2009)

TY  - JOUR
AU  - Radišić, Marina
AU  - Grujić, Svetlana
AU  - Vasiljević, Tatjana
AU  - Laušević, Mila
PY  - 2009
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1490
AB  - A rapid and sensitive liquid chromatography-tandem mass spectrometry method has been developed for the analysis of acephate, monocrotophos, carbendazim, acetamiprid, dimethoate, simazine, carbofuran, atrazine, diuron, DNOC (4,6-dinitro-o-cresol), malathion and tebufenozide in fruit juices. Extracts were obtained by matrix solid-phase dispersion using diatomaceous earth as dispersant and dichloromethane as eluent. Significant matrix effects observed for most of the pesticides tested were eliminated using matrix-matched standards. The quantification of the analytes was carried out using the most sensitive transition. The confirmation of residues detected in real samples was performed by repeated injection and acquiring additional transitions to that used for quantification. Recoveries were in the range 71-118%. Repeatability of the method, expressed as the relative standard deviation, was in general between 5-15%. Low limits of detection (0.01-0.94 ng ml(-1)) and quantification (0.03-3.12 ng ml(-1)) were readily achieved with this method for all tested pesticides.
PB  - Elsevier Sci Ltd, Oxford
T2  - Food Chemistry
T1  - Determination of selected pesticides in fruit juices by matrix solid-phase dispersion and liquid chromatography-tandem mass spectrometry
EP  - 719
IS  - 2
SP  - 712
VL  - 113
DO  - 10.1016/j.foodchem.2008.07.103
ER  - 
@article{
author = "Radišić, Marina and Grujić, Svetlana and Vasiljević, Tatjana and Laušević, Mila",
year = "2009",
abstract = "A rapid and sensitive liquid chromatography-tandem mass spectrometry method has been developed for the analysis of acephate, monocrotophos, carbendazim, acetamiprid, dimethoate, simazine, carbofuran, atrazine, diuron, DNOC (4,6-dinitro-o-cresol), malathion and tebufenozide in fruit juices. Extracts were obtained by matrix solid-phase dispersion using diatomaceous earth as dispersant and dichloromethane as eluent. Significant matrix effects observed for most of the pesticides tested were eliminated using matrix-matched standards. The quantification of the analytes was carried out using the most sensitive transition. The confirmation of residues detected in real samples was performed by repeated injection and acquiring additional transitions to that used for quantification. Recoveries were in the range 71-118%. Repeatability of the method, expressed as the relative standard deviation, was in general between 5-15%. Low limits of detection (0.01-0.94 ng ml(-1)) and quantification (0.03-3.12 ng ml(-1)) were readily achieved with this method for all tested pesticides.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Food Chemistry",
title = "Determination of selected pesticides in fruit juices by matrix solid-phase dispersion and liquid chromatography-tandem mass spectrometry",
pages = "719-712",
number = "2",
volume = "113",
doi = "10.1016/j.foodchem.2008.07.103"
}
Radišić, M., Grujić, S., Vasiljević, T.,& Laušević, M.. (2009). Determination of selected pesticides in fruit juices by matrix solid-phase dispersion and liquid chromatography-tandem mass spectrometry. in Food Chemistry
Elsevier Sci Ltd, Oxford., 113(2), 712-719.
https://doi.org/10.1016/j.foodchem.2008.07.103
Radišić M, Grujić S, Vasiljević T, Laušević M. Determination of selected pesticides in fruit juices by matrix solid-phase dispersion and liquid chromatography-tandem mass spectrometry. in Food Chemistry. 2009;113(2):712-719.
doi:10.1016/j.foodchem.2008.07.103 .
Radišić, Marina, Grujić, Svetlana, Vasiljević, Tatjana, Laušević, Mila, "Determination of selected pesticides in fruit juices by matrix solid-phase dispersion and liquid chromatography-tandem mass spectrometry" in Food Chemistry, 113, no. 2 (2009):712-719,
https://doi.org/10.1016/j.foodchem.2008.07.103 . .
107
108
121

Determination of multiple pharmaceutical classes in surface and ground waters by liquid chromatography-ion trap-tandem mass spectrometry

Grujić, Svetlana; Vasiljević, Tatjana; Laušević, Mila

(Elsevier Science Bv, Amsterdam, 2009)

TY  - JOUR
AU  - Grujić, Svetlana
AU  - Vasiljević, Tatjana
AU  - Laušević, Mila
PY  - 2009
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1505
AB  - This paper describes development, optimization and application of analytical method for determination and reliable confirmation of nineteen pharmaceuticals from different therapeutic classes (antibiotics-beta-lactams. cephalosporines, sulfonamides, macrolides and tetracyclines: benzodiazepines; antiepileptics and analgoantipyretics) in surface and ground waters at ng l(-1) levels. Water samples were prepared using solid-phase extraction and extracts were analyzed by liquid chromatography-ion trap-tandem mass spectrometry with electrospray ionization in both positive and negative ionization mode. The efficiency of ten different SPE cartridges to extract diverse Compounds from water was tested. The pH-value of the water sample, the volume of elution solvent and the sample volume were optimized. Matrix effect, especially pronounced for cephalexin and metamizole, was eliminated using matrix-matched standards. It was determined that extraction should be performed at pH similar to 7.5, i.e. without pH adjustment, and at pH 3, depending on the analyte. Azithromycin, doxycycline and acetylsalicylic acid must be extracted in acidic environment, whereas extraction of paracetamol, ampicillin, erythromycin and metamizole should be performed without pH adjustment. Repeatability of the method was generally lower than 20%. The estimated limits of detection were in the range from 0.15 to 12.46 ng l(-1). The method was applied to 26 water samples for monitoring of selected drug residues. Results revealed the presence of carbamazepine (80% of water samples), azithromycin (23%), as well as trimethoprim and paracetamol (both 15%). The most striking was the false positive signal of diclofenac in every analyzed water sample. Confirmation of the positive results was performed by repeated injection of the positive sample extracts using confirmatory method with additional transitions.
PB  - Elsevier Science Bv, Amsterdam
T2  - Journal of Chromatography A
T1  - Determination of multiple pharmaceutical classes in surface and ground waters by liquid chromatography-ion trap-tandem mass spectrometry
EP  - 5000
IS  - 25
SP  - 4989
VL  - 1216
DO  - 10.1016/j.chroma.2009.04.059
ER  - 
@article{
author = "Grujić, Svetlana and Vasiljević, Tatjana and Laušević, Mila",
year = "2009",
abstract = "This paper describes development, optimization and application of analytical method for determination and reliable confirmation of nineteen pharmaceuticals from different therapeutic classes (antibiotics-beta-lactams. cephalosporines, sulfonamides, macrolides and tetracyclines: benzodiazepines; antiepileptics and analgoantipyretics) in surface and ground waters at ng l(-1) levels. Water samples were prepared using solid-phase extraction and extracts were analyzed by liquid chromatography-ion trap-tandem mass spectrometry with electrospray ionization in both positive and negative ionization mode. The efficiency of ten different SPE cartridges to extract diverse Compounds from water was tested. The pH-value of the water sample, the volume of elution solvent and the sample volume were optimized. Matrix effect, especially pronounced for cephalexin and metamizole, was eliminated using matrix-matched standards. It was determined that extraction should be performed at pH similar to 7.5, i.e. without pH adjustment, and at pH 3, depending on the analyte. Azithromycin, doxycycline and acetylsalicylic acid must be extracted in acidic environment, whereas extraction of paracetamol, ampicillin, erythromycin and metamizole should be performed without pH adjustment. Repeatability of the method was generally lower than 20%. The estimated limits of detection were in the range from 0.15 to 12.46 ng l(-1). The method was applied to 26 water samples for monitoring of selected drug residues. Results revealed the presence of carbamazepine (80% of water samples), azithromycin (23%), as well as trimethoprim and paracetamol (both 15%). The most striking was the false positive signal of diclofenac in every analyzed water sample. Confirmation of the positive results was performed by repeated injection of the positive sample extracts using confirmatory method with additional transitions.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Journal of Chromatography A",
title = "Determination of multiple pharmaceutical classes in surface and ground waters by liquid chromatography-ion trap-tandem mass spectrometry",
pages = "5000-4989",
number = "25",
volume = "1216",
doi = "10.1016/j.chroma.2009.04.059"
}
Grujić, S., Vasiljević, T.,& Laušević, M.. (2009). Determination of multiple pharmaceutical classes in surface and ground waters by liquid chromatography-ion trap-tandem mass spectrometry. in Journal of Chromatography A
Elsevier Science Bv, Amsterdam., 1216(25), 4989-5000.
https://doi.org/10.1016/j.chroma.2009.04.059
Grujić S, Vasiljević T, Laušević M. Determination of multiple pharmaceutical classes in surface and ground waters by liquid chromatography-ion trap-tandem mass spectrometry. in Journal of Chromatography A. 2009;1216(25):4989-5000.
doi:10.1016/j.chroma.2009.04.059 .
Grujić, Svetlana, Vasiljević, Tatjana, Laušević, Mila, "Determination of multiple pharmaceutical classes in surface and ground waters by liquid chromatography-ion trap-tandem mass spectrometry" in Journal of Chromatography A, 1216, no. 25 (2009):4989-5000,
https://doi.org/10.1016/j.chroma.2009.04.059 . .
3
196
169
202

Heavy metals concentration in soils from parks and green areas in Belgrade

Marjanović, Mirjana D.; Vukčević, Marija; Antonović, Dušan; Dimitrijević, Suzana; Jovanović, Đorđe M.; Matavulj, Milan N.; Ristić, Mirjana

(Serbian Chemical Society, Belgrade, 2009)

TY  - JOUR
AU  - Marjanović, Mirjana D.
AU  - Vukčević, Marija
AU  - Antonović, Dušan
AU  - Dimitrijević, Suzana
AU  - Jovanović, Đorđe M.
AU  - Matavulj, Milan N.
AU  - Ristić, Mirjana
PY  - 2009
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1394
AB  - The current study included the investigation of several metals and their distribution in urban soils from parks and green areas in the city of Belgrade. The soils were sampled in January and February 2008. The concentrations of Cd, Co, Cu, Pb, Mn and Zn were measured, as well as the pH values and organic matter contents. The obtained results showed that there was a significant level of contamination in some samples, especially with lead, and that it was most probably caused by anthropogenic activities, mostly from traffic. The results were compared with the National legislation and Netherlands standards. Also, the recent results were compared with the data from previous work and it was concluded that there has been a certain increase of the Pb concentration in the past three years. The level of pollution in playground soil was very high and each analyzed sample exceeded the Dutch target value for Cd, Co and Pb.
AB  - Cilj ovog rada bio je ispitivanje distribucije teških metala u zemljištu parkova i zelenih površina u Beogradu. U uzorcima zemljišta, prikupljenim tokom januara i februara 2008. godine, određivane su koncentracije kadmijuma, kobalta, bakra, olova, mangana i cinka, kao i pH vrednost i sadržaj organske materije. Dobijeni rezultati pokazuju značajan stepen zagađenja kod pojedinih uzoraka. Izuzetno visok sadržaj olova zabeležen je kod sviispitivanih uzoraka, i najverovatnije je posledica antropogenih aktivnosti, pre svega saobraćaja. Poređenjem rezultata sa ranijim ispitivanjima primećeno je znatno povećanje sadržaja olova u zemljištu u protekle tri godine. Izuzetno zabrinjavajuća je i činjenica da je zemljište uzorkovano u dečijim igralištima zagađeno teškim metalima. Takođe, poređenjem dobijenih rezultata sa holandskim standardom, zaključeno je da su kod svih uzoraka koncentracije ispitivanih metala više od koncentracija definisanih tim standardom.
PB  - Serbian Chemical Society, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Heavy metals concentration in soils from parks and green areas in Belgrade
T1  - Koncentracija teških metala u zemljištu parkova i zelenih površina u Beogradu
EP  - 706
IS  - 6
SP  - 697
VL  - 74
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1394
ER  - 
@article{
author = "Marjanović, Mirjana D. and Vukčević, Marija and Antonović, Dušan and Dimitrijević, Suzana and Jovanović, Đorđe M. and Matavulj, Milan N. and Ristić, Mirjana",
year = "2009",
abstract = "The current study included the investigation of several metals and their distribution in urban soils from parks and green areas in the city of Belgrade. The soils were sampled in January and February 2008. The concentrations of Cd, Co, Cu, Pb, Mn and Zn were measured, as well as the pH values and organic matter contents. The obtained results showed that there was a significant level of contamination in some samples, especially with lead, and that it was most probably caused by anthropogenic activities, mostly from traffic. The results were compared with the National legislation and Netherlands standards. Also, the recent results were compared with the data from previous work and it was concluded that there has been a certain increase of the Pb concentration in the past three years. The level of pollution in playground soil was very high and each analyzed sample exceeded the Dutch target value for Cd, Co and Pb., Cilj ovog rada bio je ispitivanje distribucije teških metala u zemljištu parkova i zelenih površina u Beogradu. U uzorcima zemljišta, prikupljenim tokom januara i februara 2008. godine, određivane su koncentracije kadmijuma, kobalta, bakra, olova, mangana i cinka, kao i pH vrednost i sadržaj organske materije. Dobijeni rezultati pokazuju značajan stepen zagađenja kod pojedinih uzoraka. Izuzetno visok sadržaj olova zabeležen je kod sviispitivanih uzoraka, i najverovatnije je posledica antropogenih aktivnosti, pre svega saobraćaja. Poređenjem rezultata sa ranijim ispitivanjima primećeno je znatno povećanje sadržaja olova u zemljištu u protekle tri godine. Izuzetno zabrinjavajuća je i činjenica da je zemljište uzorkovano u dečijim igralištima zagađeno teškim metalima. Takođe, poređenjem dobijenih rezultata sa holandskim standardom, zaključeno je da su kod svih uzoraka koncentracije ispitivanih metala više od koncentracija definisanih tim standardom.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Heavy metals concentration in soils from parks and green areas in Belgrade, Koncentracija teških metala u zemljištu parkova i zelenih površina u Beogradu",
pages = "706-697",
number = "6",
volume = "74",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1394"
}
Marjanović, M. D., Vukčević, M., Antonović, D., Dimitrijević, S., Jovanović, Đ. M., Matavulj, M. N.,& Ristić, M.. (2009). Heavy metals concentration in soils from parks and green areas in Belgrade. in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 74(6), 697-706.
https://hdl.handle.net/21.15107/rcub_technorep_1394
Marjanović MD, Vukčević M, Antonović D, Dimitrijević S, Jovanović ĐM, Matavulj MN, Ristić M. Heavy metals concentration in soils from parks and green areas in Belgrade. in Journal of the Serbian Chemical Society. 2009;74(6):697-706.
https://hdl.handle.net/21.15107/rcub_technorep_1394 .
Marjanović, Mirjana D., Vukčević, Marija, Antonović, Dušan, Dimitrijević, Suzana, Jovanović, Đorđe M., Matavulj, Milan N., Ristić, Mirjana, "Heavy metals concentration in soils from parks and green areas in Belgrade" in Journal of the Serbian Chemical Society, 74, no. 6 (2009):697-706,
https://hdl.handle.net/21.15107/rcub_technorep_1394 .
38
48

Danube and Sava river sediment monitoring in Belgrade and its surroundings

Crnković, Dragan; Crnković, Nataša S.; Filipović, Anka J.; Rajaković, Ljubinka V.; Perić-Grujić, Aleksandra; Ristić, Mirjana

(Taylor & Francis Inc, Philadelphia, 2008)

TY  - JOUR
AU  - Crnković, Dragan
AU  - Crnković, Nataša S.
AU  - Filipović, Anka J.
AU  - Rajaković, Ljubinka V.
AU  - Perić-Grujić, Aleksandra
AU  - Ristić, Mirjana
PY  - 2008
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1251
AB  - Belgrade is the largest city in Serbia located at the confluence of river Sava to the Danube river. The quality of water and sediments of rivers which run through Belgrade is of a significant importance, since water from these rivers is a source of Belgrade drinking water supply system and probable anthropogenic contamination is related to industrialization and inputs of sewage water. In order to follow the sediment quality of river Sava (km 62-1) and river Danube (km 1193-1124) in Belgrade and its surroundings, the content of As, Cd, Cr, Cu, Zn, Ni, Pb and Hg were measured in the period 2001-2005. The content of 16 polycyclic aromatic hydrocarbons (PAHs) was measured in 2005. The results have shown that, due to the metal content, examined Danube sediment quality varies from class 1 to class 3, predominantly nickel being the class determining parameter. Elevated copper, zinc and mercury concentrations were measured at some profiles, as well. Typically due to the nickel content, Sava sediment quality belongs to class 3 in the period 2001-2004. Elevated concentrations of cadmium, zinc and mercury were observed in 2001, as well. Moreover, in 2005, sediments from three profiles were extremely polluted with nickel, leading the Sava sediment to class 4, when highest urgency measures are needed. Total PAH concentration in the sediments from Danube (213.1-575.4 mu g kg(-1)) was lower than total PAH concentration from Sava sediments (416.2-595.3 mu g kg(-1)). Nevertheless, according to the Dutch regulatory system, it has been concluded that river sediments in Belgrade and its surroundings were not polluted with PAHs in 2005.
PB  - Taylor & Francis Inc, Philadelphia
T2  - Journal of Environmental Science and Health Part A-Toxic/Hazardous Substances & Environmental Engine
T1  - Danube and Sava river sediment monitoring in Belgrade and its surroundings
EP  - 1360
IS  - 12
SP  - 1353
VL  - 43
DO  - 10.1080/10934520802231974
ER  - 
@article{
author = "Crnković, Dragan and Crnković, Nataša S. and Filipović, Anka J. and Rajaković, Ljubinka V. and Perić-Grujić, Aleksandra and Ristić, Mirjana",
year = "2008",
abstract = "Belgrade is the largest city in Serbia located at the confluence of river Sava to the Danube river. The quality of water and sediments of rivers which run through Belgrade is of a significant importance, since water from these rivers is a source of Belgrade drinking water supply system and probable anthropogenic contamination is related to industrialization and inputs of sewage water. In order to follow the sediment quality of river Sava (km 62-1) and river Danube (km 1193-1124) in Belgrade and its surroundings, the content of As, Cd, Cr, Cu, Zn, Ni, Pb and Hg were measured in the period 2001-2005. The content of 16 polycyclic aromatic hydrocarbons (PAHs) was measured in 2005. The results have shown that, due to the metal content, examined Danube sediment quality varies from class 1 to class 3, predominantly nickel being the class determining parameter. Elevated copper, zinc and mercury concentrations were measured at some profiles, as well. Typically due to the nickel content, Sava sediment quality belongs to class 3 in the period 2001-2004. Elevated concentrations of cadmium, zinc and mercury were observed in 2001, as well. Moreover, in 2005, sediments from three profiles were extremely polluted with nickel, leading the Sava sediment to class 4, when highest urgency measures are needed. Total PAH concentration in the sediments from Danube (213.1-575.4 mu g kg(-1)) was lower than total PAH concentration from Sava sediments (416.2-595.3 mu g kg(-1)). Nevertheless, according to the Dutch regulatory system, it has been concluded that river sediments in Belgrade and its surroundings were not polluted with PAHs in 2005.",
publisher = "Taylor & Francis Inc, Philadelphia",
journal = "Journal of Environmental Science and Health Part A-Toxic/Hazardous Substances & Environmental Engine",
title = "Danube and Sava river sediment monitoring in Belgrade and its surroundings",
pages = "1360-1353",
number = "12",
volume = "43",
doi = "10.1080/10934520802231974"
}
Crnković, D., Crnković, N. S., Filipović, A. J., Rajaković, L. V., Perić-Grujić, A.,& Ristić, M.. (2008). Danube and Sava river sediment monitoring in Belgrade and its surroundings. in Journal of Environmental Science and Health Part A-Toxic/Hazardous Substances & Environmental Engine
Taylor & Francis Inc, Philadelphia., 43(12), 1353-1360.
https://doi.org/10.1080/10934520802231974
Crnković D, Crnković NS, Filipović AJ, Rajaković LV, Perić-Grujić A, Ristić M. Danube and Sava river sediment monitoring in Belgrade and its surroundings. in Journal of Environmental Science and Health Part A-Toxic/Hazardous Substances & Environmental Engine. 2008;43(12):1353-1360.
doi:10.1080/10934520802231974 .
Crnković, Dragan, Crnković, Nataša S., Filipović, Anka J., Rajaković, Ljubinka V., Perić-Grujić, Aleksandra, Ristić, Mirjana, "Danube and Sava river sediment monitoring in Belgrade and its surroundings" in Journal of Environmental Science and Health Part A-Toxic/Hazardous Substances & Environmental Engine, 43, no. 12 (2008):1353-1360,
https://doi.org/10.1080/10934520802231974 . .
22
23
26

Adsorption of phenol and 2,4-dinitrophenol on activated carbon cloth: The influence of sorbent surface acidity and pH

Vasiljević, Tatjana; Spasojević, J.; Baćić, M.; Onjia, Antonije; Laušević, Mila

(Taylor & Francis Inc, Philadelphia, 2006)

TY  - JOUR
AU  - Vasiljević, Tatjana
AU  - Spasojević, J.
AU  - Baćić, M.
AU  - Onjia, Antonije
AU  - Laušević, Mila
PY  - 2006
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/927
AB  - In this work the effect of the activated carbon cloth surface acidity and pH of the solution on phenols adsorption has been studied. Two phenols, widely different in the terms of their pKa values (phenol and 2,4-dinitrophenol), have been chosen as the model compounds. It has been shown that phenol adsorption was favored by low pH values of solution and high point of zero charge values of activated carbon cloths. The adsorption of 2,4-dinitrophenol was promoted at very low pH values of solution and it was less influenced by activated carbon cloth surface acidity.
PB  - Taylor & Francis Inc, Philadelphia
T2  - Separation Science and Technology
T1  - Adsorption of phenol and 2,4-dinitrophenol on activated carbon cloth: The influence of sorbent surface acidity and pH
EP  - 1075
IS  - 6
SP  - 1061
VL  - 41
DO  - 10.1080/01496390600588853
ER  - 
@article{
author = "Vasiljević, Tatjana and Spasojević, J. and Baćić, M. and Onjia, Antonije and Laušević, Mila",
year = "2006",
abstract = "In this work the effect of the activated carbon cloth surface acidity and pH of the solution on phenols adsorption has been studied. Two phenols, widely different in the terms of their pKa values (phenol and 2,4-dinitrophenol), have been chosen as the model compounds. It has been shown that phenol adsorption was favored by low pH values of solution and high point of zero charge values of activated carbon cloths. The adsorption of 2,4-dinitrophenol was promoted at very low pH values of solution and it was less influenced by activated carbon cloth surface acidity.",
publisher = "Taylor & Francis Inc, Philadelphia",
journal = "Separation Science and Technology",
title = "Adsorption of phenol and 2,4-dinitrophenol on activated carbon cloth: The influence of sorbent surface acidity and pH",
pages = "1075-1061",
number = "6",
volume = "41",
doi = "10.1080/01496390600588853"
}
Vasiljević, T., Spasojević, J., Baćić, M., Onjia, A.,& Laušević, M.. (2006). Adsorption of phenol and 2,4-dinitrophenol on activated carbon cloth: The influence of sorbent surface acidity and pH. in Separation Science and Technology
Taylor & Francis Inc, Philadelphia., 41(6), 1061-1075.
https://doi.org/10.1080/01496390600588853
Vasiljević T, Spasojević J, Baćić M, Onjia A, Laušević M. Adsorption of phenol and 2,4-dinitrophenol on activated carbon cloth: The influence of sorbent surface acidity and pH. in Separation Science and Technology. 2006;41(6):1061-1075.
doi:10.1080/01496390600588853 .
Vasiljević, Tatjana, Spasojević, J., Baćić, M., Onjia, Antonije, Laušević, Mila, "Adsorption of phenol and 2,4-dinitrophenol on activated carbon cloth: The influence of sorbent surface acidity and pH" in Separation Science and Technology, 41, no. 6 (2006):1061-1075,
https://doi.org/10.1080/01496390600588853 . .
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