Cleaner production: power plant wastewater treatment process development

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Cleaner production: power plant wastewater treatment process development (en)
Развој технолошких процеса за третман отпадних вода енергетских постројења применом чистије производње (sr)
Razvoj tehnoloških procesa za tretman otpadnih voda energetskih postrojenja primenom čistije proizvodnje (sr_RS)
Authors

Publications

Solvent extraction and entrainment problem

Spasić, Aleksandar; Manojlović, Vaso; Jovanović, Mica

(Association of Metallurgical Engineers of Serbia, 2020)

TY  - JOUR
AU  - Spasić, Aleksandar
AU  - Manojlović, Vaso
AU  - Jovanović, Mica
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4422
AB  - Applications of solvent extraction operations and processes play one of the most important roles in Hydrometallurgy. Therefore, in this brief review, some general concepts for selected representative applications are discussed. Also, one particular entrainment problem solution is discussed in some more details. At first, the selected general concepts for metal production of copper and uranium from their ores are presented. Then after, the leaching-solvent extraction-electro winning process for copper is shown. Finally, the extraction of uranium from wet phosphoric acid is discussed.
PB  - Association of Metallurgical Engineers of Serbia
T2  - Metallurgical & Materials Engineering
T1  - Solvent extraction and entrainment problem
EP  - 175
IS  - 2
SP  - 163
VL  - 26
DO  - 10.30544/480
ER  - 
@article{
author = "Spasić, Aleksandar and Manojlović, Vaso and Jovanović, Mica",
year = "2020",
abstract = "Applications of solvent extraction operations and processes play one of the most important roles in Hydrometallurgy. Therefore, in this brief review, some general concepts for selected representative applications are discussed. Also, one particular entrainment problem solution is discussed in some more details. At first, the selected general concepts for metal production of copper and uranium from their ores are presented. Then after, the leaching-solvent extraction-electro winning process for copper is shown. Finally, the extraction of uranium from wet phosphoric acid is discussed.",
publisher = "Association of Metallurgical Engineers of Serbia",
journal = "Metallurgical & Materials Engineering",
title = "Solvent extraction and entrainment problem",
pages = "175-163",
number = "2",
volume = "26",
doi = "10.30544/480"
}
Spasić, A., Manojlović, V.,& Jovanović, M.. (2020). Solvent extraction and entrainment problem. in Metallurgical & Materials Engineering
Association of Metallurgical Engineers of Serbia., 26(2), 163-175.
https://doi.org/10.30544/480
Spasić A, Manojlović V, Jovanović M. Solvent extraction and entrainment problem. in Metallurgical & Materials Engineering. 2020;26(2):163-175.
doi:10.30544/480 .
Spasić, Aleksandar, Manojlović, Vaso, Jovanović, Mica, "Solvent extraction and entrainment problem" in Metallurgical & Materials Engineering, 26, no. 2 (2020):163-175,
https://doi.org/10.30544/480 . .
3
1
3

Razvoj procesa završnog tretmana čvrstih i tečnih zagađujućih materija primenom principa čistije proizvodnje

Dajić, Ana

(Univerzitet u Beogradu, Tehnološko-metalurški fakultet, 2019)

TY  - THES
AU  - Dajić, Ana
PY  - 2019
UR  - http://eteze.bg.ac.rs/application/showtheses?thesesId=7269
UR  - https://fedorabg.bg.ac.rs/fedora/get/o:21013/bdef:Content/download
UR  - http://vbs.rs/scripts/cobiss?command=DISPLAY&base=70036&RID=51886607
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4685
AB  - The main goal of the research conducted within this doctoral dissertation was final treatment processes development for solid and liquid pollutants applying cleaner production principles. Aiming to prevent pollution and protect environment applying of cleaner production in processes design have main role. Research in field of technological design development for treatment of solid waste materials was done on example of waste landfiling. In case of liquid waste materials treatment, research was done for simulated wastewater from textile industry...
AB  - Istraživanja u okviru ove doktorske disertacije sprovedena su sa ciljem razvoja procesa završnog tretmana čvrstih i tečnih zagađujućih materija primenom principa čistije proizvodnje. Pri projektovanju tehnoloških rešenja, procesa i postrojenja, u funkciji zaštite životne sredine, moguće je i neophodno koristiti principe i metod čistije proizvodnje. Istraživanja iz oblasti unapređenja tehnologije završnog tretmana čvrstih zagađujućih supstanci izvedena su na primeru odlaganja otpada dok su istraživanja iz oblasti unapređenja tehnologije završnog tretmana tečnih zagađujućih supstanci izvedena na primeru prečišćavanja simulirane otpadne vode iz tekstilne industrije...
PB  - Univerzitet u Beogradu, Tehnološko-metalurški fakultet
T1  - Razvoj procesa završnog tretmana čvrstih i tečnih zagađujućih materija primenom principa čistije proizvodnje
T1  - Development of final treatment processses for solid and liquid pollutants by cleaner production principles application
UR  - https://hdl.handle.net/21.15107/rcub_technorep_4685
ER  - 
@phdthesis{
author = "Dajić, Ana",
year = "2019",
abstract = "The main goal of the research conducted within this doctoral dissertation was final treatment processes development for solid and liquid pollutants applying cleaner production principles. Aiming to prevent pollution and protect environment applying of cleaner production in processes design have main role. Research in field of technological design development for treatment of solid waste materials was done on example of waste landfiling. In case of liquid waste materials treatment, research was done for simulated wastewater from textile industry..., Istraživanja u okviru ove doktorske disertacije sprovedena su sa ciljem razvoja procesa završnog tretmana čvrstih i tečnih zagađujućih materija primenom principa čistije proizvodnje. Pri projektovanju tehnoloških rešenja, procesa i postrojenja, u funkciji zaštite životne sredine, moguće je i neophodno koristiti principe i metod čistije proizvodnje. Istraživanja iz oblasti unapređenja tehnologije završnog tretmana čvrstih zagađujućih supstanci izvedena su na primeru odlaganja otpada dok su istraživanja iz oblasti unapređenja tehnologije završnog tretmana tečnih zagađujućih supstanci izvedena na primeru prečišćavanja simulirane otpadne vode iz tekstilne industrije...",
publisher = "Univerzitet u Beogradu, Tehnološko-metalurški fakultet",
title = "Razvoj procesa završnog tretmana čvrstih i tečnih zagađujućih materija primenom principa čistije proizvodnje, Development of final treatment processses for solid and liquid pollutants by cleaner production principles application",
url = "https://hdl.handle.net/21.15107/rcub_technorep_4685"
}
Dajić, A.. (2019). Razvoj procesa završnog tretmana čvrstih i tečnih zagađujućih materija primenom principa čistije proizvodnje. 
Univerzitet u Beogradu, Tehnološko-metalurški fakultet..
https://hdl.handle.net/21.15107/rcub_technorep_4685
Dajić A. Razvoj procesa završnog tretmana čvrstih i tečnih zagađujućih materija primenom principa čistije proizvodnje. 2019;.
https://hdl.handle.net/21.15107/rcub_technorep_4685 .
Dajić, Ana, "Razvoj procesa završnog tretmana čvrstih i tečnih zagađujućih materija primenom principa čistije proizvodnje" (2019),
https://hdl.handle.net/21.15107/rcub_technorep_4685 .

Development of Green Chemical Process: The Reaction of Condensation in a Continuous Flow Microreactor System

Tadić, Julijana; Svetozarević, Milica; Dajić, Ana; Mihajlović, Marina; Jovanović, Mića; Mijin, Dušan

(Belgrade : Association of Chemists and Chemical Engineers of Serbia UHTS, 2019)

TY  - CONF
AU  - Tadić, Julijana
AU  - Svetozarević, Milica
AU  - Dajić, Ana
AU  - Mihajlović, Marina
AU  - Jovanović, Mića
AU  - Mijin, Dušan
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6909
AB  - Aromatic heterocyclic compounds containing nitrogen in their structure have attracted
considerable interest in medicine, because of their certain pharmacological properties
including anticancer, anti-inflammatory, antihypertensive, antibacterial, antifungal and
antiviral activities. Among them, derivatives with 2-pyridone moiety are particularly
notable due to their wide application in pharmacological and dye industry. A usual
procedure for synthesis of 2-pyridone moiety is classic condensation reaction of 1,3-
dicarbonyl compounds with cyanoacetamide. However, in the case of various
substituted reactants, drawback of this reaction can be a low yield of desirable products
and long reaction time. This factor has led to the development of different methods for
synthesis in order to overcome these defects. The microreactor technology and flow
chemistry could play a significant role in the improving of organic synthesis efficiency.
The microreactor approach could provide enhanced productivity, fast conversion and
altogether less hazardous chemical synthesis. Furthermore, it pushes towards designing
of chemistry with a lower environmental and economic impact. In this study the
synthesis of 2-pyridone moiety in a continuous flow coil-type microreactor system was
examined. In order to optimize reaction conditions, flow rates of starting reagents were
varied. The desirable 2-pyridone was obtained in satisfactory yield of circa 60% in less
than 10 minutes. The structure and purity of synthetized 2-pyridone moiety were
confirmed by melting point, FT-IR, 1
H NMR and UV-Vis spectra. The efficiency of the
presented method for the synthesis of 2-pyridone based molecules has promising scaleup potential.
PB  - Belgrade : Association of Chemists and Chemical Engineers of Serbia UHTS
C3  - Conference proceedings / International Scientific Conference Environmental Impact of Illegal Construction, Poor Planning and Design IMPEDE 2019, 10-11 October 2019, Belgrade, Serbia
T1  - Development of Green Chemical Process: The Reaction of Condensation in a Continuous Flow Microreactor System
EP  - 133
SP  - 129
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6909
ER  - 
@conference{
author = "Tadić, Julijana and Svetozarević, Milica and Dajić, Ana and Mihajlović, Marina and Jovanović, Mića and Mijin, Dušan",
year = "2019",
abstract = "Aromatic heterocyclic compounds containing nitrogen in their structure have attracted
considerable interest in medicine, because of their certain pharmacological properties
including anticancer, anti-inflammatory, antihypertensive, antibacterial, antifungal and
antiviral activities. Among them, derivatives with 2-pyridone moiety are particularly
notable due to their wide application in pharmacological and dye industry. A usual
procedure for synthesis of 2-pyridone moiety is classic condensation reaction of 1,3-
dicarbonyl compounds with cyanoacetamide. However, in the case of various
substituted reactants, drawback of this reaction can be a low yield of desirable products
and long reaction time. This factor has led to the development of different methods for
synthesis in order to overcome these defects. The microreactor technology and flow
chemistry could play a significant role in the improving of organic synthesis efficiency.
The microreactor approach could provide enhanced productivity, fast conversion and
altogether less hazardous chemical synthesis. Furthermore, it pushes towards designing
of chemistry with a lower environmental and economic impact. In this study the
synthesis of 2-pyridone moiety in a continuous flow coil-type microreactor system was
examined. In order to optimize reaction conditions, flow rates of starting reagents were
varied. The desirable 2-pyridone was obtained in satisfactory yield of circa 60% in less
than 10 minutes. The structure and purity of synthetized 2-pyridone moiety were
confirmed by melting point, FT-IR, 1
H NMR and UV-Vis spectra. The efficiency of the
presented method for the synthesis of 2-pyridone based molecules has promising scaleup potential.",
publisher = "Belgrade : Association of Chemists and Chemical Engineers of Serbia UHTS",
journal = "Conference proceedings / International Scientific Conference Environmental Impact of Illegal Construction, Poor Planning and Design IMPEDE 2019, 10-11 October 2019, Belgrade, Serbia",
title = "Development of Green Chemical Process: The Reaction of Condensation in a Continuous Flow Microreactor System",
pages = "133-129",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6909"
}
Tadić, J., Svetozarević, M., Dajić, A., Mihajlović, M., Jovanović, M.,& Mijin, D.. (2019). Development of Green Chemical Process: The Reaction of Condensation in a Continuous Flow Microreactor System. in Conference proceedings / International Scientific Conference Environmental Impact of Illegal Construction, Poor Planning and Design IMPEDE 2019, 10-11 October 2019, Belgrade, Serbia
Belgrade : Association of Chemists and Chemical Engineers of Serbia UHTS., 129-133.
https://hdl.handle.net/21.15107/rcub_technorep_6909
Tadić J, Svetozarević M, Dajić A, Mihajlović M, Jovanović M, Mijin D. Development of Green Chemical Process: The Reaction of Condensation in a Continuous Flow Microreactor System. in Conference proceedings / International Scientific Conference Environmental Impact of Illegal Construction, Poor Planning and Design IMPEDE 2019, 10-11 October 2019, Belgrade, Serbia. 2019;:129-133.
https://hdl.handle.net/21.15107/rcub_technorep_6909 .
Tadić, Julijana, Svetozarević, Milica, Dajić, Ana, Mihajlović, Marina, Jovanović, Mića, Mijin, Dušan, "Development of Green Chemical Process: The Reaction of Condensation in a Continuous Flow Microreactor System" in Conference proceedings / International Scientific Conference Environmental Impact of Illegal Construction, Poor Planning and Design IMPEDE 2019, 10-11 October 2019, Belgrade, Serbia (2019):129-133,
https://hdl.handle.net/21.15107/rcub_technorep_6909 .

Are the Tube Microreactors Future of Wastewater Treatment?

Dajić, Ana; Mihajlović, Marina; Svetozarević, Milica; Tadić, Julijana; Jovanović, Mića

(Belgrade : Association of Chemists and Chemical Engineers of Serbia UHTS, 2019)

TY  - CONF
AU  - Dajić, Ana
AU  - Mihajlović, Marina
AU  - Svetozarević, Milica
AU  - Tadić, Julijana
AU  - Jovanović, Mića
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6654
AB  - In the industry, wastewater is important environmental problem. Due to the growing
environmental concern this problem became one of key issues. Large amounts of highly
contaminated wastewater, as consequence of industrial use, are important environmental
polluters. Before discharging, wastewater has to be treated to achieve quality prescribed
by law. One of solutions could be decomposition of pollutants. The decomposition of
pollutants from industrial wastewaters is of critical importance in order to maintain a
clean environment. Many process commonly used in polluter degradation processes
commonly use different harmful chemicals or leads to formation of potentially harmful
byproducts. Treatment of wastewater from industry in microreactor system is new
ecological solution. Over the last few decades microreactors have been increasingly
recognized as being an alternative to conventional batch reactors in chemical industry.
Application of these systems have aim to transform conventional into more productive
and environmental friendlier process. They are characterized by micrometer dimensions
and continuous mode, resulting in significant intensification of the mass and heat
transfer. Microreactor systems are already find application in chemical industry,
biotechnology, pharmaceutical industry and medicine. Decomposition of pollutants in
wastewater is complex, but microreactors allow purification with low quantities of
chemical reagents. This paper represents review of possible fields of wastewater
purification – waste material decomposition in microreactor systems.
PB  - Belgrade : Association of Chemists and Chemical Engineers of Serbia UHTS
C3  - Conference proceedings / International Scientific Conference Environmental Impact of Illegal Construction, Poor Planning and Design IMPEDE 2019, 10-11 October 2019, Belgrade, Serbia
T1  - Are the Tube Microreactors Future of Wastewater Treatment?
EP  - 112
SP  - 107
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6654
ER  - 
@conference{
author = "Dajić, Ana and Mihajlović, Marina and Svetozarević, Milica and Tadić, Julijana and Jovanović, Mića",
year = "2019",
abstract = "In the industry, wastewater is important environmental problem. Due to the growing
environmental concern this problem became one of key issues. Large amounts of highly
contaminated wastewater, as consequence of industrial use, are important environmental
polluters. Before discharging, wastewater has to be treated to achieve quality prescribed
by law. One of solutions could be decomposition of pollutants. The decomposition of
pollutants from industrial wastewaters is of critical importance in order to maintain a
clean environment. Many process commonly used in polluter degradation processes
commonly use different harmful chemicals or leads to formation of potentially harmful
byproducts. Treatment of wastewater from industry in microreactor system is new
ecological solution. Over the last few decades microreactors have been increasingly
recognized as being an alternative to conventional batch reactors in chemical industry.
Application of these systems have aim to transform conventional into more productive
and environmental friendlier process. They are characterized by micrometer dimensions
and continuous mode, resulting in significant intensification of the mass and heat
transfer. Microreactor systems are already find application in chemical industry,
biotechnology, pharmaceutical industry and medicine. Decomposition of pollutants in
wastewater is complex, but microreactors allow purification with low quantities of
chemical reagents. This paper represents review of possible fields of wastewater
purification – waste material decomposition in microreactor systems.",
publisher = "Belgrade : Association of Chemists and Chemical Engineers of Serbia UHTS",
journal = "Conference proceedings / International Scientific Conference Environmental Impact of Illegal Construction, Poor Planning and Design IMPEDE 2019, 10-11 October 2019, Belgrade, Serbia",
title = "Are the Tube Microreactors Future of Wastewater Treatment?",
pages = "112-107",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6654"
}
Dajić, A., Mihajlović, M., Svetozarević, M., Tadić, J.,& Jovanović, M.. (2019). Are the Tube Microreactors Future of Wastewater Treatment?. in Conference proceedings / International Scientific Conference Environmental Impact of Illegal Construction, Poor Planning and Design IMPEDE 2019, 10-11 October 2019, Belgrade, Serbia
Belgrade : Association of Chemists and Chemical Engineers of Serbia UHTS., 107-112.
https://hdl.handle.net/21.15107/rcub_technorep_6654
Dajić A, Mihajlović M, Svetozarević M, Tadić J, Jovanović M. Are the Tube Microreactors Future of Wastewater Treatment?. in Conference proceedings / International Scientific Conference Environmental Impact of Illegal Construction, Poor Planning and Design IMPEDE 2019, 10-11 October 2019, Belgrade, Serbia. 2019;:107-112.
https://hdl.handle.net/21.15107/rcub_technorep_6654 .
Dajić, Ana, Mihajlović, Marina, Svetozarević, Milica, Tadić, Julijana, Jovanović, Mića, "Are the Tube Microreactors Future of Wastewater Treatment?" in Conference proceedings / International Scientific Conference Environmental Impact of Illegal Construction, Poor Planning and Design IMPEDE 2019, 10-11 October 2019, Belgrade, Serbia (2019):107-112,
https://hdl.handle.net/21.15107/rcub_technorep_6654 .

Advantages of Microreactor Technology over Conventional Methods in Enzymatic Wastewater Treatment – Environmental Application of Enzymes

Svetozarević, Milica; Tadić, Julijana; Mihajlović, Marina; Dajić, Ana; Jovanović, Mića

(Belgrade : Association of Chemists and Chemical Engineers of Serbia UHTS, 2019)

TY  - CONF
AU  - Svetozarević, Milica
AU  - Tadić, Julijana
AU  - Mihajlović, Marina
AU  - Dajić, Ana
AU  - Jovanović, Mića
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6655
AB  - Wastewater treatment is one of the most analysed issue in theory and practice because
of its current and vast significance nowadays. Wide range of chemical, physical and
biochemical processes are developed for wastewater treatment. Although biochemical
processes are the most eco-friendly when compared to chemical and physical, they are
still not the leading type of technology in this field. In recent years, microreactors are
trending because of their particular characteristics that can be utilized in numerous
areas. Continuous flow, higher reaction yields, scale independant and high selectivity
are just a few of the beneficial characteristics of microreactors. Due to the micro
channels, turbulent flow regime is avoided. Furthermore, high surface-to-area ratios aid
in far greater and faster heat and mass transfer than in common reactors. Another asset
of microreactors is short diffusion pathways, that together with small reaction pathways
add to its favorable attributes. When it comes to enzymes, due to their small size and
mild reaction conditions requirements, they are ideal for working in microreactos.
Enzymes can be isolated from different sources, but isolation from plant waste material
is what makes them even more interesting. Because of the above mentioned
microreactor’s pros, several enzyme’s disadvantagious properties are overcome. In this
study, a review of the positive characteristic of enzyme microreators in wastwater
treatment will be discussed.
PB  - Belgrade : Association of Chemists and Chemical Engineers of Serbia UHTS
C3  - Conference proceedings / International Scientific Conference Environmental Impact of Illegal Construction, Poor Planning and Design IMPEDE 2019, 10-11 October 2019, Belgrade, Serbia
T1  - Advantages of Microreactor Technology over Conventional Methods in Enzymatic Wastewater Treatment – Environmental Application of Enzymes
EP  - 97
SP  - 89
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6655
ER  - 
@conference{
author = "Svetozarević, Milica and Tadić, Julijana and Mihajlović, Marina and Dajić, Ana and Jovanović, Mića",
year = "2019",
abstract = "Wastewater treatment is one of the most analysed issue in theory and practice because
of its current and vast significance nowadays. Wide range of chemical, physical and
biochemical processes are developed for wastewater treatment. Although biochemical
processes are the most eco-friendly when compared to chemical and physical, they are
still not the leading type of technology in this field. In recent years, microreactors are
trending because of their particular characteristics that can be utilized in numerous
areas. Continuous flow, higher reaction yields, scale independant and high selectivity
are just a few of the beneficial characteristics of microreactors. Due to the micro
channels, turbulent flow regime is avoided. Furthermore, high surface-to-area ratios aid
in far greater and faster heat and mass transfer than in common reactors. Another asset
of microreactors is short diffusion pathways, that together with small reaction pathways
add to its favorable attributes. When it comes to enzymes, due to their small size and
mild reaction conditions requirements, they are ideal for working in microreactos.
Enzymes can be isolated from different sources, but isolation from plant waste material
is what makes them even more interesting. Because of the above mentioned
microreactor’s pros, several enzyme’s disadvantagious properties are overcome. In this
study, a review of the positive characteristic of enzyme microreators in wastwater
treatment will be discussed.",
publisher = "Belgrade : Association of Chemists and Chemical Engineers of Serbia UHTS",
journal = "Conference proceedings / International Scientific Conference Environmental Impact of Illegal Construction, Poor Planning and Design IMPEDE 2019, 10-11 October 2019, Belgrade, Serbia",
title = "Advantages of Microreactor Technology over Conventional Methods in Enzymatic Wastewater Treatment – Environmental Application of Enzymes",
pages = "97-89",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6655"
}
Svetozarević, M., Tadić, J., Mihajlović, M., Dajić, A.,& Jovanović, M.. (2019). Advantages of Microreactor Technology over Conventional Methods in Enzymatic Wastewater Treatment – Environmental Application of Enzymes. in Conference proceedings / International Scientific Conference Environmental Impact of Illegal Construction, Poor Planning and Design IMPEDE 2019, 10-11 October 2019, Belgrade, Serbia
Belgrade : Association of Chemists and Chemical Engineers of Serbia UHTS., 89-97.
https://hdl.handle.net/21.15107/rcub_technorep_6655
Svetozarević M, Tadić J, Mihajlović M, Dajić A, Jovanović M. Advantages of Microreactor Technology over Conventional Methods in Enzymatic Wastewater Treatment – Environmental Application of Enzymes. in Conference proceedings / International Scientific Conference Environmental Impact of Illegal Construction, Poor Planning and Design IMPEDE 2019, 10-11 October 2019, Belgrade, Serbia. 2019;:89-97.
https://hdl.handle.net/21.15107/rcub_technorep_6655 .
Svetozarević, Milica, Tadić, Julijana, Mihajlović, Marina, Dajić, Ana, Jovanović, Mića, "Advantages of Microreactor Technology over Conventional Methods in Enzymatic Wastewater Treatment – Environmental Application of Enzymes" in Conference proceedings / International Scientific Conference Environmental Impact of Illegal Construction, Poor Planning and Design IMPEDE 2019, 10-11 October 2019, Belgrade, Serbia (2019):89-97,
https://hdl.handle.net/21.15107/rcub_technorep_6655 .

Framework of new landfill GHG policy in developing countries: Case study of Serbia

Mihajlović, Marina; Pešić, Radmilo; Jovanović, Mica B.

(Wiley Periodicals, Inc, San Francisco, 2019)

TY  - JOUR
AU  - Mihajlović, Marina
AU  - Pešić, Radmilo
AU  - Jovanović, Mica B.
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4222
AB  - This paper deals with greenhouse gas (GHG) emissions originating from changes in the waste sector in developing and transitional economies. Using a Serbian case study, the effects of different waste disposal techniques on GHG emissions were analyzed in three scenarios: the current one, the worst one, and the best one. According to the Serbian national-waste management strategy, a large number of dumpsites and unsanitary landfills should be merged into several regional sanitary landfills. Results obtained from the SWM-GHG Calculator have shown potentially higher emissions from modern regional landfills than from dumpsites. Related environmental policy should therefore be analyzed in detail and applied. Environmental policy options are analyzed using the SWOT technique. The policy option to be implemented depends on country-specific circumstances, such as the adequate functioning of institutions, the effectiveness of the judicial system, the established legal framework, and the general level of competence in the waste management sector. If all of these conditions are in place, the polluter pays' option is the superior one. However, if the level of knowledge and capacity in waste sector is low, and if there are no adequate institutions, or if the judicial system is inefficient, the first option appears to be the right one.
PB  - Wiley Periodicals, Inc, San Francisco
T2  - Greenhouse Gases-Science and Technology
T1  - Framework of new landfill GHG policy in developing countries: Case study of Serbia
EP  - 159
IS  - 2
SP  - 152
VL  - 9
DO  - 10.1002/ghg.1854
ER  - 
@article{
author = "Mihajlović, Marina and Pešić, Radmilo and Jovanović, Mica B.",
year = "2019",
abstract = "This paper deals with greenhouse gas (GHG) emissions originating from changes in the waste sector in developing and transitional economies. Using a Serbian case study, the effects of different waste disposal techniques on GHG emissions were analyzed in three scenarios: the current one, the worst one, and the best one. According to the Serbian national-waste management strategy, a large number of dumpsites and unsanitary landfills should be merged into several regional sanitary landfills. Results obtained from the SWM-GHG Calculator have shown potentially higher emissions from modern regional landfills than from dumpsites. Related environmental policy should therefore be analyzed in detail and applied. Environmental policy options are analyzed using the SWOT technique. The policy option to be implemented depends on country-specific circumstances, such as the adequate functioning of institutions, the effectiveness of the judicial system, the established legal framework, and the general level of competence in the waste management sector. If all of these conditions are in place, the polluter pays' option is the superior one. However, if the level of knowledge and capacity in waste sector is low, and if there are no adequate institutions, or if the judicial system is inefficient, the first option appears to be the right one.",
publisher = "Wiley Periodicals, Inc, San Francisco",
journal = "Greenhouse Gases-Science and Technology",
title = "Framework of new landfill GHG policy in developing countries: Case study of Serbia",
pages = "159-152",
number = "2",
volume = "9",
doi = "10.1002/ghg.1854"
}
Mihajlović, M., Pešić, R.,& Jovanović, M. B.. (2019). Framework of new landfill GHG policy in developing countries: Case study of Serbia. in Greenhouse Gases-Science and Technology
Wiley Periodicals, Inc, San Francisco., 9(2), 152-159.
https://doi.org/10.1002/ghg.1854
Mihajlović M, Pešić R, Jovanović MB. Framework of new landfill GHG policy in developing countries: Case study of Serbia. in Greenhouse Gases-Science and Technology. 2019;9(2):152-159.
doi:10.1002/ghg.1854 .
Mihajlović, Marina, Pešić, Radmilo, Jovanović, Mica B., "Framework of new landfill GHG policy in developing countries: Case study of Serbia" in Greenhouse Gases-Science and Technology, 9, no. 2 (2019):152-159,
https://doi.org/10.1002/ghg.1854 . .
6
4
6

Continuous flow synthesis of some 6-and 1,6-substituted 3-cyano-4-methyl-2-pyridones

Tadić, Julijana; Mihajlović, Marina; Jovanović, Mica; Mijin, Dušan

(Srpsko hemijsko društvo, Beograd, 2019)

TY  - JOUR
AU  - Tadić, Julijana
AU  - Mihajlović, Marina
AU  - Jovanović, Mica
AU  - Mijin, Dušan
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4234
AB  - In this study, six 6- and 1,6-substituted-3-cyano-4-methyl-2-pyridones were synthesized in a continuous flow microreactor system. The syntheses were realized at room temperature and the obtained results were compared to those achieved within classical syntheses. In order to optimize the continuous flow syntheses and increase the yield of the products, the retention time in the microreactor was varied by changing the flow rates of the reactant solutions. Furthermore, the reaction was optimized for 3-cyano-4,6-dimethyl-2-pyridone and 3-cyano-6-hydroxy-4-methyl-2-pyridone, which are comercially important in the pharmaceutical and dye industries. Both 2-pyridones were obtained in satisfactory yield of circa 60 % in less than 10 min. The resulting compounds were characterized by their melting points, FT-IR, H-1-NMR and UV-Vis spectra. The efficiency of the presented method for the synthesis of 2-pyridone-based molecules has promising potential for industrial production.
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - Continuous flow synthesis of some 6-and 1,6-substituted 3-cyano-4-methyl-2-pyridones
EP  - 538
IS  - 6
SP  - 531
VL  - 84
DO  - 10.2298/JSC180703092T
ER  - 
@article{
author = "Tadić, Julijana and Mihajlović, Marina and Jovanović, Mica and Mijin, Dušan",
year = "2019",
abstract = "In this study, six 6- and 1,6-substituted-3-cyano-4-methyl-2-pyridones were synthesized in a continuous flow microreactor system. The syntheses were realized at room temperature and the obtained results were compared to those achieved within classical syntheses. In order to optimize the continuous flow syntheses and increase the yield of the products, the retention time in the microreactor was varied by changing the flow rates of the reactant solutions. Furthermore, the reaction was optimized for 3-cyano-4,6-dimethyl-2-pyridone and 3-cyano-6-hydroxy-4-methyl-2-pyridone, which are comercially important in the pharmaceutical and dye industries. Both 2-pyridones were obtained in satisfactory yield of circa 60 % in less than 10 min. The resulting compounds were characterized by their melting points, FT-IR, H-1-NMR and UV-Vis spectra. The efficiency of the presented method for the synthesis of 2-pyridone-based molecules has promising potential for industrial production.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Continuous flow synthesis of some 6-and 1,6-substituted 3-cyano-4-methyl-2-pyridones",
pages = "538-531",
number = "6",
volume = "84",
doi = "10.2298/JSC180703092T"
}
Tadić, J., Mihajlović, M., Jovanović, M.,& Mijin, D.. (2019). Continuous flow synthesis of some 6-and 1,6-substituted 3-cyano-4-methyl-2-pyridones. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 84(6), 531-538.
https://doi.org/10.2298/JSC180703092T
Tadić J, Mihajlović M, Jovanović M, Mijin D. Continuous flow synthesis of some 6-and 1,6-substituted 3-cyano-4-methyl-2-pyridones. in Journal of the Serbian Chemical Society. 2019;84(6):531-538.
doi:10.2298/JSC180703092T .
Tadić, Julijana, Mihajlović, Marina, Jovanović, Mica, Mijin, Dušan, "Continuous flow synthesis of some 6-and 1,6-substituted 3-cyano-4-methyl-2-pyridones" in Journal of the Serbian Chemical Society, 84, no. 6 (2019):531-538,
https://doi.org/10.2298/JSC180703092T . .
4
1
4

Improvement of the Textile Industry Wastewater Decolorization Process Using Capillary Microreactor Technology

Dajić, Ana; Mihajlović, Marina; Mandić-Rajcević, Stefan; Mijin, Dušan; Jovanović, Mica; Jovanović, Jovan

(Springer International Publishing Ag, Cham, 2019)

TY  - JOUR
AU  - Dajić, Ana
AU  - Mihajlović, Marina
AU  - Mandić-Rajcević, Stefan
AU  - Mijin, Dušan
AU  - Jovanović, Mica
AU  - Jovanović, Jovan
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4313
AB  - Dyes are an important class of pollutants because large amounts are often found in the environment as a result of their extensive industrial use. Traditional wastewater treatment methods often lead to high energy costs, formation of by-products, and the production of sludge. This paper analyzes the possibility of using a new, sustainable approach to water decolorization with reduced consumption of chemicals. In microreactor experiments, reactant molar ratios, volumetric flow rate, and microreactor length and diameter were varied. The obtained results showed that batch decolorization required 250-500 times higher molar ratios to achieve comparable decolorization (70-90%) and at least three times longer residence time. Microreactor experiments demonstrated that higher microreactor lengths and molar ratios influence positively the decolorization process, although satisfactory results are also achieved with medium microreactor lengths and lower molar ratios. Higher fluids velocities contribute to the decolorization process, but the best results were obtained using a medium velocity (in a 5.8m microreactor system) to achieve the highest possible mixing intensity and long enough residence time. Microreactor systems have achieved significantly better decolorization results, considering any combination of microreactor length, molar ratio, diameter, flow rate, and residence time, than a batch system. Thus, a medium length microreactor system, with a low concentration of NaOCl, low flow rate, small diameter, and medium residence time can achieve satisfactory decolorization results, but with a lower consumption of chemicals, energy, equipment, and better environmental impact. Article HighlightsColored wastewater was decolorized using batch and microreactor systems.Various microreactor lengths, diameters, and mixture velocities were tested.Microreactor system required 500 times lower amounts of decolorizing agent.
PB  - Springer International Publishing Ag, Cham
T2  - International Journal of Environmental Research
T1  - Improvement of the Textile Industry Wastewater Decolorization Process Using Capillary Microreactor Technology
EP  - 222
IS  - 1
SP  - 213
VL  - 13
DO  - 10.1007/s41742-018-0162-3
ER  - 
@article{
author = "Dajić, Ana and Mihajlović, Marina and Mandić-Rajcević, Stefan and Mijin, Dušan and Jovanović, Mica and Jovanović, Jovan",
year = "2019",
abstract = "Dyes are an important class of pollutants because large amounts are often found in the environment as a result of their extensive industrial use. Traditional wastewater treatment methods often lead to high energy costs, formation of by-products, and the production of sludge. This paper analyzes the possibility of using a new, sustainable approach to water decolorization with reduced consumption of chemicals. In microreactor experiments, reactant molar ratios, volumetric flow rate, and microreactor length and diameter were varied. The obtained results showed that batch decolorization required 250-500 times higher molar ratios to achieve comparable decolorization (70-90%) and at least three times longer residence time. Microreactor experiments demonstrated that higher microreactor lengths and molar ratios influence positively the decolorization process, although satisfactory results are also achieved with medium microreactor lengths and lower molar ratios. Higher fluids velocities contribute to the decolorization process, but the best results were obtained using a medium velocity (in a 5.8m microreactor system) to achieve the highest possible mixing intensity and long enough residence time. Microreactor systems have achieved significantly better decolorization results, considering any combination of microreactor length, molar ratio, diameter, flow rate, and residence time, than a batch system. Thus, a medium length microreactor system, with a low concentration of NaOCl, low flow rate, small diameter, and medium residence time can achieve satisfactory decolorization results, but with a lower consumption of chemicals, energy, equipment, and better environmental impact. Article HighlightsColored wastewater was decolorized using batch and microreactor systems.Various microreactor lengths, diameters, and mixture velocities were tested.Microreactor system required 500 times lower amounts of decolorizing agent.",
publisher = "Springer International Publishing Ag, Cham",
journal = "International Journal of Environmental Research",
title = "Improvement of the Textile Industry Wastewater Decolorization Process Using Capillary Microreactor Technology",
pages = "222-213",
number = "1",
volume = "13",
doi = "10.1007/s41742-018-0162-3"
}
Dajić, A., Mihajlović, M., Mandić-Rajcević, S., Mijin, D., Jovanović, M.,& Jovanović, J.. (2019). Improvement of the Textile Industry Wastewater Decolorization Process Using Capillary Microreactor Technology. in International Journal of Environmental Research
Springer International Publishing Ag, Cham., 13(1), 213-222.
https://doi.org/10.1007/s41742-018-0162-3
Dajić A, Mihajlović M, Mandić-Rajcević S, Mijin D, Jovanović M, Jovanović J. Improvement of the Textile Industry Wastewater Decolorization Process Using Capillary Microreactor Technology. in International Journal of Environmental Research. 2019;13(1):213-222.
doi:10.1007/s41742-018-0162-3 .
Dajić, Ana, Mihajlović, Marina, Mandić-Rajcević, Stefan, Mijin, Dušan, Jovanović, Mica, Jovanović, Jovan, "Improvement of the Textile Industry Wastewater Decolorization Process Using Capillary Microreactor Technology" in International Journal of Environmental Research, 13, no. 1 (2019):213-222,
https://doi.org/10.1007/s41742-018-0162-3 . .
6
3
6

Ultrasonographic assessment of the maxillary artery and middle meningeal artery in the infratemporal fossa

Lepić, Toplica; Lepić, Milan; Mandić-Rajčević, Stefan

(John Wiley and Sons Inc, 2019)

TY  - JOUR
AU  - Lepić, Toplica
AU  - Lepić, Milan
AU  - Mandić-Rajčević, Stefan
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5914
AB  - Purpose: To investigate with Doppler ultrasonography the maxillary and middle meningeal arteries in the infratemporal fossa, and describe their hemodynamic characteristics. Methods: We included 24 female and 11 male volunteers without vascular diseases, with a median age of 43 years. We used the acoustic window, enlarged by subjects half-opening their mouth, located below the zygomatic arch, in front of temporo-mandibular joint, to reach the maxillary and middle meningeal arteries. Results: In the 35 subjects, 112 arteries were visualized successfully: 60 maxillary (85.7%), and 52 middle meningeal arteries (74.3%), at a depth of 2.40 and 2.50 cm, respectively. Their blood flow was directed anteriorly and away from the probe. While all the measured hemodynamic characteristics differed significantly between the maxillary and the middle meningeal artery (P < 0.001), there was no significant difference between male and female subjects, nor between the left or the right side. Conclusions: The maxillary and middle meningeal arteries can be insonated in the infratemporal fossa through the easily accessible acoustic window below the zygomatic arch, when the patient holds his mouth half open. They can be differentiated by their ultrasonographic characteristics and blood flow features.
PB  - John Wiley and Sons Inc
T2  - Journal of Clinical Ultrasound
T1  - Ultrasonographic assessment of the maxillary artery and middle meningeal artery in the infratemporal fossa
EP  - 411
IS  - 7
SP  - 405
VL  - 47
DO  - 10.1002/jcu.22712
ER  - 
@article{
author = "Lepić, Toplica and Lepić, Milan and Mandić-Rajčević, Stefan",
year = "2019",
abstract = "Purpose: To investigate with Doppler ultrasonography the maxillary and middle meningeal arteries in the infratemporal fossa, and describe their hemodynamic characteristics. Methods: We included 24 female and 11 male volunteers without vascular diseases, with a median age of 43 years. We used the acoustic window, enlarged by subjects half-opening their mouth, located below the zygomatic arch, in front of temporo-mandibular joint, to reach the maxillary and middle meningeal arteries. Results: In the 35 subjects, 112 arteries were visualized successfully: 60 maxillary (85.7%), and 52 middle meningeal arteries (74.3%), at a depth of 2.40 and 2.50 cm, respectively. Their blood flow was directed anteriorly and away from the probe. While all the measured hemodynamic characteristics differed significantly between the maxillary and the middle meningeal artery (P < 0.001), there was no significant difference between male and female subjects, nor between the left or the right side. Conclusions: The maxillary and middle meningeal arteries can be insonated in the infratemporal fossa through the easily accessible acoustic window below the zygomatic arch, when the patient holds his mouth half open. They can be differentiated by their ultrasonographic characteristics and blood flow features.",
publisher = "John Wiley and Sons Inc",
journal = "Journal of Clinical Ultrasound",
title = "Ultrasonographic assessment of the maxillary artery and middle meningeal artery in the infratemporal fossa",
pages = "411-405",
number = "7",
volume = "47",
doi = "10.1002/jcu.22712"
}
Lepić, T., Lepić, M.,& Mandić-Rajčević, S.. (2019). Ultrasonographic assessment of the maxillary artery and middle meningeal artery in the infratemporal fossa. in Journal of Clinical Ultrasound
John Wiley and Sons Inc., 47(7), 405-411.
https://doi.org/10.1002/jcu.22712
Lepić T, Lepić M, Mandić-Rajčević S. Ultrasonographic assessment of the maxillary artery and middle meningeal artery in the infratemporal fossa. in Journal of Clinical Ultrasound. 2019;47(7):405-411.
doi:10.1002/jcu.22712 .
Lepić, Toplica, Lepić, Milan, Mandić-Rajčević, Stefan, "Ultrasonographic assessment of the maxillary artery and middle meningeal artery in the infratemporal fossa" in Journal of Clinical Ultrasound, 47, no. 7 (2019):405-411,
https://doi.org/10.1002/jcu.22712 . .
6
6

Evaluating a primary healthcare centre's preparedness for disasters using the hospital safety index: Lessons learned from the 2014 floods in Obrenovac, Serbia

Lapčević, Zoran; Mandić-Rajčević, Stefan; Lepić, Milan; Jovanović, Mića

(Elsevier Ltd, 2019)

TY  - JOUR
AU  - Lapčević, Zoran
AU  - Mandić-Rajčević, Stefan
AU  - Lepić, Milan
AU  - Jovanović, Mića
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5889
AB  - Various organizations have endeavored to develop assessment methods for the identification and management of weaknesses in hospital disaster preparedness. Although the largest number of patients receive their regular care at the primary level, there is no internationally validated tool for the rapid safety assessment of primary health care centers (PHC). Flooding accounts for almost 50% of all disasters related to weather, and climate models consider these events as highly probable in the future. In May 2014, heavy rain caused floods affecting around 1.6 million people in Serbia, leaving the municipality of Obrenovac most severely impacted. This paper aims at assessing the safety of PHC Obrenovac using the Hospital Safety Index (HSI), evaluating the usefulness of HSI for safety assessment of PHCs, and drawing lessons from the 2014 floods. PHC Obrenovac had an overall safety index of 0.82, with structural, nonstructural safety, and disaster management indices of 0.95, 0.74, and 0.75, respectively, implying it is likely to function in disasters. A detailed analysis of individual HSI items underlined the necessary improvements in the field of emergency power and water supply, telecommunication, and emergency medical supplies, which rendered the PHC non-functional during the 2014 floods. Most items were considered of same relevance for primary healthcare centers as for hospitals, excluding some items in the medical equipment, patient care, and support services. Fine-tuning the HSI to primary healthcare settings, officially translating it into different languages, facilitating scoring and analysis could result in a valid safety evaluation tool of primary healthcare facilities.
PB  - Elsevier Ltd
T2  - International Journal of Disaster Risk Reduction
T1  - Evaluating a primary healthcare centre's preparedness for disasters using the hospital safety index: Lessons learned from the 2014 floods in Obrenovac, Serbia
EP  - 442
SP  - 436
VL  - 34
DO  - 10.1016/j.ijdrr.2018.12.014
ER  - 
@article{
author = "Lapčević, Zoran and Mandić-Rajčević, Stefan and Lepić, Milan and Jovanović, Mića",
year = "2019",
abstract = "Various organizations have endeavored to develop assessment methods for the identification and management of weaknesses in hospital disaster preparedness. Although the largest number of patients receive their regular care at the primary level, there is no internationally validated tool for the rapid safety assessment of primary health care centers (PHC). Flooding accounts for almost 50% of all disasters related to weather, and climate models consider these events as highly probable in the future. In May 2014, heavy rain caused floods affecting around 1.6 million people in Serbia, leaving the municipality of Obrenovac most severely impacted. This paper aims at assessing the safety of PHC Obrenovac using the Hospital Safety Index (HSI), evaluating the usefulness of HSI for safety assessment of PHCs, and drawing lessons from the 2014 floods. PHC Obrenovac had an overall safety index of 0.82, with structural, nonstructural safety, and disaster management indices of 0.95, 0.74, and 0.75, respectively, implying it is likely to function in disasters. A detailed analysis of individual HSI items underlined the necessary improvements in the field of emergency power and water supply, telecommunication, and emergency medical supplies, which rendered the PHC non-functional during the 2014 floods. Most items were considered of same relevance for primary healthcare centers as for hospitals, excluding some items in the medical equipment, patient care, and support services. Fine-tuning the HSI to primary healthcare settings, officially translating it into different languages, facilitating scoring and analysis could result in a valid safety evaluation tool of primary healthcare facilities.",
publisher = "Elsevier Ltd",
journal = "International Journal of Disaster Risk Reduction",
title = "Evaluating a primary healthcare centre's preparedness for disasters using the hospital safety index: Lessons learned from the 2014 floods in Obrenovac, Serbia",
pages = "442-436",
volume = "34",
doi = "10.1016/j.ijdrr.2018.12.014"
}
Lapčević, Z., Mandić-Rajčević, S., Lepić, M.,& Jovanović, M.. (2019). Evaluating a primary healthcare centre's preparedness for disasters using the hospital safety index: Lessons learned from the 2014 floods in Obrenovac, Serbia. in International Journal of Disaster Risk Reduction
Elsevier Ltd., 34, 436-442.
https://doi.org/10.1016/j.ijdrr.2018.12.014
Lapčević Z, Mandić-Rajčević S, Lepić M, Jovanović M. Evaluating a primary healthcare centre's preparedness for disasters using the hospital safety index: Lessons learned from the 2014 floods in Obrenovac, Serbia. in International Journal of Disaster Risk Reduction. 2019;34:436-442.
doi:10.1016/j.ijdrr.2018.12.014 .
Lapčević, Zoran, Mandić-Rajčević, Stefan, Lepić, Milan, Jovanović, Mića, "Evaluating a primary healthcare centre's preparedness for disasters using the hospital safety index: Lessons learned from the 2014 floods in Obrenovac, Serbia" in International Journal of Disaster Risk Reduction, 34 (2019):436-442,
https://doi.org/10.1016/j.ijdrr.2018.12.014 . .
26
22

The removal of Zn2+, Pb2+, and As(V) ions by lime activated fly ash and valorization of the exhausted adsorbent

Karanac, Milica; Đolić, Maja; Veljović, Đorđe; Rajaković-Ognjanović, Vladana; Veličković, Zlate; Pavićević, Vladimir; Marinković, Aleksandar

(Pergamon-Elsevier Science Ltd, Oxford, 2018)

TY  - JOUR
AU  - Karanac, Milica
AU  - Đolić, Maja
AU  - Veljović, Đorđe
AU  - Rajaković-Ognjanović, Vladana
AU  - Veličković, Zlate
AU  - Pavićević, Vladimir
AU  - Marinković, Aleksandar
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3841
AB  - This study focuses on the use of raw fly ash (FA) and modified fly ash - activated by lime (MFA), as effective and low-cost adsorbents for the removal of heavy metals (Zn2+, Pb2+ and As(V)), followed by the revalorization of the exhausted adsorbent. The granulometric, elemental analysis, point of zero charge (pH(pzc), radiochemical and structural characterization were conducted using X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET), scanning electron microscopy (SEM), Fourier transform infrared (FTIR) and gamma spectrometry techniques. The optimal conditions and key factors influencing the adsorption process were assessed using the response surface method (RSM). The adsorption capacity of the MFA adsorbent for Zn2+, Pb2+ and As(V) removal, calculated by the Langmuir model, was found to be 33.13, 26.06, and 29.71 mg g(-1), respectively. The kinetic and thermodynamic parameters indicated that the adsorption process is spontaneous and endothermic. Due to their low desorption potential of the exhausted adsorbents, their effective reuse was established to be feasible. For this reason, the valorization of this material as an additive in construction materials was thereafter studied, where testing its toxicity leaching (TCLP) as well as the mechanical properties of construction material containing exhausted MFA confirmed its safe use. Hence, this study points to a possible "two-in-one" reuse of coal ash, initially as an adsorbent and later as an additive in a construction material.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Waste Management
T1  - The removal of Zn2+, Pb2+, and As(V) ions by lime activated fly ash and valorization of the exhausted adsorbent
EP  - 378
SP  - 366
VL  - 78
DO  - 10.1016/j.wasman.2018.05.052
ER  - 
@article{
author = "Karanac, Milica and Đolić, Maja and Veljović, Đorđe and Rajaković-Ognjanović, Vladana and Veličković, Zlate and Pavićević, Vladimir and Marinković, Aleksandar",
year = "2018",
abstract = "This study focuses on the use of raw fly ash (FA) and modified fly ash - activated by lime (MFA), as effective and low-cost adsorbents for the removal of heavy metals (Zn2+, Pb2+ and As(V)), followed by the revalorization of the exhausted adsorbent. The granulometric, elemental analysis, point of zero charge (pH(pzc), radiochemical and structural characterization were conducted using X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET), scanning electron microscopy (SEM), Fourier transform infrared (FTIR) and gamma spectrometry techniques. The optimal conditions and key factors influencing the adsorption process were assessed using the response surface method (RSM). The adsorption capacity of the MFA adsorbent for Zn2+, Pb2+ and As(V) removal, calculated by the Langmuir model, was found to be 33.13, 26.06, and 29.71 mg g(-1), respectively. The kinetic and thermodynamic parameters indicated that the adsorption process is spontaneous and endothermic. Due to their low desorption potential of the exhausted adsorbents, their effective reuse was established to be feasible. For this reason, the valorization of this material as an additive in construction materials was thereafter studied, where testing its toxicity leaching (TCLP) as well as the mechanical properties of construction material containing exhausted MFA confirmed its safe use. Hence, this study points to a possible "two-in-one" reuse of coal ash, initially as an adsorbent and later as an additive in a construction material.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Waste Management",
title = "The removal of Zn2+, Pb2+, and As(V) ions by lime activated fly ash and valorization of the exhausted adsorbent",
pages = "378-366",
volume = "78",
doi = "10.1016/j.wasman.2018.05.052"
}
Karanac, M., Đolić, M., Veljović, Đ., Rajaković-Ognjanović, V., Veličković, Z., Pavićević, V.,& Marinković, A.. (2018). The removal of Zn2+, Pb2+, and As(V) ions by lime activated fly ash and valorization of the exhausted adsorbent. in Waste Management
Pergamon-Elsevier Science Ltd, Oxford., 78, 366-378.
https://doi.org/10.1016/j.wasman.2018.05.052
Karanac M, Đolić M, Veljović Đ, Rajaković-Ognjanović V, Veličković Z, Pavićević V, Marinković A. The removal of Zn2+, Pb2+, and As(V) ions by lime activated fly ash and valorization of the exhausted adsorbent. in Waste Management. 2018;78:366-378.
doi:10.1016/j.wasman.2018.05.052 .
Karanac, Milica, Đolić, Maja, Veljović, Đorđe, Rajaković-Ognjanović, Vladana, Veličković, Zlate, Pavićević, Vladimir, Marinković, Aleksandar, "The removal of Zn2+, Pb2+, and As(V) ions by lime activated fly ash and valorization of the exhausted adsorbent" in Waste Management, 78 (2018):366-378,
https://doi.org/10.1016/j.wasman.2018.05.052 . .
41
23
43

Efficient multistep arsenate removal onto magnetite modified fly ash

Karanac, Milica; Đolić, Maja; Veličković, Zlate; Kapidžić, Ana; Ivanovski, Valentin N.; Mitrić, Miodrag; Marinković, Aleksandar

(Academic Press Ltd- Elsevier Science Ltd, London, 2018)

TY  - JOUR
AU  - Karanac, Milica
AU  - Đolić, Maja
AU  - Veličković, Zlate
AU  - Kapidžić, Ana
AU  - Ivanovski, Valentin N.
AU  - Mitrić, Miodrag
AU  - Marinković, Aleksandar
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3877
AB  - The modification of the fly ash (FA) by magnetite (M) was performed to obtain FAM adsorbent with improved adsorption efficiency for arsenate removal from water. The novel low cost adsorbents are characterized by liquid nitrogen porosimetry (BET), scanning electron microscopy (SEM), X-ray diffraction (XRD), Mossbauer spectroscopy (MB) and Fourier transform infrared (FTIR) spectroscopy. The optimal conditions and key factors influencing the adsorbent synthesis are assessed using the response surface method (RSM). The adsorption experiment was carried out in a batch system by varying the contact time, temperature, pH, and mass of the adsorbent. The adsorption capacity of the FAM adsorbent for As(V), calculated by Langmuir model, was 19.14 mg g(-1). The thermodynamic parameters showed spontaneity of adsorption with low endothermic character. The kinetic data followed the pseudo-second-order kinetic model (PSO), and Weber-Morris model indicated intra-particle diffusion as rate limiting step. Alternative to low desorption capability of the FAM was found by five consecutive adsorption/magnetite precipitation processes which gave exhausted layered adsorbent with 65.78 mg g(-1) capacity. This research also has shed light on the mechanism of As(V)-ion adsorption, presenting a promising solution for the valorization of a widely abundant industrial waste.
PB  - Academic Press Ltd- Elsevier Science Ltd, London
T2  - Journal of Environmental Management
T1  - Efficient multistep arsenate removal onto magnetite modified fly ash
EP  - 276
SP  - 263
VL  - 224
DO  - 10.1016/j.jenvman.2018.07.051
ER  - 
@article{
author = "Karanac, Milica and Đolić, Maja and Veličković, Zlate and Kapidžić, Ana and Ivanovski, Valentin N. and Mitrić, Miodrag and Marinković, Aleksandar",
year = "2018",
abstract = "The modification of the fly ash (FA) by magnetite (M) was performed to obtain FAM adsorbent with improved adsorption efficiency for arsenate removal from water. The novel low cost adsorbents are characterized by liquid nitrogen porosimetry (BET), scanning electron microscopy (SEM), X-ray diffraction (XRD), Mossbauer spectroscopy (MB) and Fourier transform infrared (FTIR) spectroscopy. The optimal conditions and key factors influencing the adsorbent synthesis are assessed using the response surface method (RSM). The adsorption experiment was carried out in a batch system by varying the contact time, temperature, pH, and mass of the adsorbent. The adsorption capacity of the FAM adsorbent for As(V), calculated by Langmuir model, was 19.14 mg g(-1). The thermodynamic parameters showed spontaneity of adsorption with low endothermic character. The kinetic data followed the pseudo-second-order kinetic model (PSO), and Weber-Morris model indicated intra-particle diffusion as rate limiting step. Alternative to low desorption capability of the FAM was found by five consecutive adsorption/magnetite precipitation processes which gave exhausted layered adsorbent with 65.78 mg g(-1) capacity. This research also has shed light on the mechanism of As(V)-ion adsorption, presenting a promising solution for the valorization of a widely abundant industrial waste.",
publisher = "Academic Press Ltd- Elsevier Science Ltd, London",
journal = "Journal of Environmental Management",
title = "Efficient multistep arsenate removal onto magnetite modified fly ash",
pages = "276-263",
volume = "224",
doi = "10.1016/j.jenvman.2018.07.051"
}
Karanac, M., Đolić, M., Veličković, Z., Kapidžić, A., Ivanovski, V. N., Mitrić, M.,& Marinković, A.. (2018). Efficient multistep arsenate removal onto magnetite modified fly ash. in Journal of Environmental Management
Academic Press Ltd- Elsevier Science Ltd, London., 224, 263-276.
https://doi.org/10.1016/j.jenvman.2018.07.051
Karanac M, Đolić M, Veličković Z, Kapidžić A, Ivanovski VN, Mitrić M, Marinković A. Efficient multistep arsenate removal onto magnetite modified fly ash. in Journal of Environmental Management. 2018;224:263-276.
doi:10.1016/j.jenvman.2018.07.051 .
Karanac, Milica, Đolić, Maja, Veličković, Zlate, Kapidžić, Ana, Ivanovski, Valentin N., Mitrić, Miodrag, Marinković, Aleksandar, "Efficient multistep arsenate removal onto magnetite modified fly ash" in Journal of Environmental Management, 224 (2018):263-276,
https://doi.org/10.1016/j.jenvman.2018.07.051 . .
1
33
15
31

Environmental and take-home lead exposure in children living in the vicinity of a lead battery smelter in Serbia

Mandić-Rajčević, Stefan; Bulat, Zorica; Matović, Vesna; Popević, Martin; Lepić, Milan; Mandić, Bojana; Jovanović, Mića; Haufroid, Vincent; Žarković, Miloš; Bulat, Petar

(Academic Press Inc., 2018)

TY  - JOUR
AU  - Mandić-Rajčević, Stefan
AU  - Bulat, Zorica
AU  - Matović, Vesna
AU  - Popević, Martin
AU  - Lepić, Milan
AU  - Mandić, Bojana
AU  - Jovanović, Mića
AU  - Haufroid, Vincent
AU  - Žarković, Miloš
AU  - Bulat, Petar
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5873
AB  - Blood lead levels (BLLs) have been falling steadily worldwide due to restricted use of lead (Pb) and its compounds. although they remain above preindustrial Pb levels. Elevated BLL can still be found in children living near secondary Pb smelters that represent around 50% of Pb production. There have been no studies on Pb exposure in children living in Serbia ever since the 1980s. The aim of this study was to evaluate the BLLs in children living in two villages in Serbia (Zajača, the location of a secondary lead smelter, and Paskovac, 5 km away), identify the primary determinants of children's BLLs, and investigate the impact of BLLs on children's health symptoms and school achievement. The study was conducted in 2011 on 127 children, aged 1–18 years, whose BLLs were measured using inductively coupled argon plasma mass spectrometry (ICP-MS). The median BLL in children was 12 μg/dl, with a significantly higher value of 17.5 μg/dl in Zajača, compared to 7.6 μg/dl in Paskovac. Only 1 out of 75 and 12 out of 52 children from Zajača and Paskovac, respectively, had BLLs below the CDC recommended 5 μg/dl level. Living near the smelter resulted in 19 times, and having a father who works in the plant 4 times higher odds of elevated BLLs. No significant effects of elevated BLLs health symptoms were seen in this study. BLLs of children living near a battery recycling plant in Serbia, an upper-middle income European country, were in the range and even higher than those of children living in developing countries. For the first time, the contribution of environmental and take-home lead exposure was quantified using mixed-effect modeling, and our results indicate a contribution of 25–40% of the take-home lead exposure to the BLLs of children living in the vicinity of a secondary lead smelter.
PB  - Academic Press Inc.
T2  - Environmental Research
T1  - Environmental and take-home lead exposure in children living in the vicinity of a lead battery smelter in Serbia
EP  - 734
SP  - 725
VL  - 167
DO  - 10.1016/j.envres.2018.08.031
ER  - 
@article{
author = "Mandić-Rajčević, Stefan and Bulat, Zorica and Matović, Vesna and Popević, Martin and Lepić, Milan and Mandić, Bojana and Jovanović, Mića and Haufroid, Vincent and Žarković, Miloš and Bulat, Petar",
year = "2018",
abstract = "Blood lead levels (BLLs) have been falling steadily worldwide due to restricted use of lead (Pb) and its compounds. although they remain above preindustrial Pb levels. Elevated BLL can still be found in children living near secondary Pb smelters that represent around 50% of Pb production. There have been no studies on Pb exposure in children living in Serbia ever since the 1980s. The aim of this study was to evaluate the BLLs in children living in two villages in Serbia (Zajača, the location of a secondary lead smelter, and Paskovac, 5 km away), identify the primary determinants of children's BLLs, and investigate the impact of BLLs on children's health symptoms and school achievement. The study was conducted in 2011 on 127 children, aged 1–18 years, whose BLLs were measured using inductively coupled argon plasma mass spectrometry (ICP-MS). The median BLL in children was 12 μg/dl, with a significantly higher value of 17.5 μg/dl in Zajača, compared to 7.6 μg/dl in Paskovac. Only 1 out of 75 and 12 out of 52 children from Zajača and Paskovac, respectively, had BLLs below the CDC recommended 5 μg/dl level. Living near the smelter resulted in 19 times, and having a father who works in the plant 4 times higher odds of elevated BLLs. No significant effects of elevated BLLs health symptoms were seen in this study. BLLs of children living near a battery recycling plant in Serbia, an upper-middle income European country, were in the range and even higher than those of children living in developing countries. For the first time, the contribution of environmental and take-home lead exposure was quantified using mixed-effect modeling, and our results indicate a contribution of 25–40% of the take-home lead exposure to the BLLs of children living in the vicinity of a secondary lead smelter.",
publisher = "Academic Press Inc.",
journal = "Environmental Research",
title = "Environmental and take-home lead exposure in children living in the vicinity of a lead battery smelter in Serbia",
pages = "734-725",
volume = "167",
doi = "10.1016/j.envres.2018.08.031"
}
Mandić-Rajčević, S., Bulat, Z., Matović, V., Popević, M., Lepić, M., Mandić, B., Jovanović, M., Haufroid, V., Žarković, M.,& Bulat, P.. (2018). Environmental and take-home lead exposure in children living in the vicinity of a lead battery smelter in Serbia. in Environmental Research
Academic Press Inc.., 167, 725-734.
https://doi.org/10.1016/j.envres.2018.08.031
Mandić-Rajčević S, Bulat Z, Matović V, Popević M, Lepić M, Mandić B, Jovanović M, Haufroid V, Žarković M, Bulat P. Environmental and take-home lead exposure in children living in the vicinity of a lead battery smelter in Serbia. in Environmental Research. 2018;167:725-734.
doi:10.1016/j.envres.2018.08.031 .
Mandić-Rajčević, Stefan, Bulat, Zorica, Matović, Vesna, Popević, Martin, Lepić, Milan, Mandić, Bojana, Jovanović, Mića, Haufroid, Vincent, Žarković, Miloš, Bulat, Petar, "Environmental and take-home lead exposure in children living in the vicinity of a lead battery smelter in Serbia" in Environmental Research, 167 (2018):725-734,
https://doi.org/10.1016/j.envres.2018.08.031 . .
15
16

Breaking of double emulsions based on electrohydrodynamics principles

Spasić, Aleksandar; Jovanović, Jovan M.; Manojlović, Vaso; Jovanović, Mica

(Academic Press Inc Elsevier Science, San Diego, 2016)

TY  - JOUR
AU  - Spasić, Aleksandar
AU  - Jovanović, Jovan M.
AU  - Manojlović, Vaso
AU  - Jovanović, Mica
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3222
AB  - This research focuses on the modeling of the liquid-liquid dispersed system, including particular insight on the electrocoalescence (EC) process that occurs during the breaking of double emulsions. The representative system, used in this work, was taken from the pilot plant for solvent extraction of uranium from wet phosphoric acid. The chosen framework required for elucidation of the EC process is based on the electrohydrodynamic (EHD) principles. During the model development it was necessary to consider several theoretical concepts for easier understanding and description of the related events. The first is the concept of entities, and corresponding classification of finely dispersed systems. The second concept is an introduction of almost forgotten basic electrodynamics element the memdiode or memristor as a current controlled device, and corresponding memristive systems. Hence, the conclusions that may be withdrawn from the presented results and findings could enable easier designing of the solutions for a breaking of double emulsions problems, that is, the entrainment problems that may arise in some pilot or industrial plants. Finally, the perspectives and the remaining challenges, considering the here discussed concepts and model based on the EHD principles, are mentioned.
PB  - Academic Press Inc Elsevier Science, San Diego
T2  - Journal of Colloid and Interface Science
T1  - Breaking of double emulsions based on electrohydrodynamics principles
EP  - 172
SP  - 165
VL  - 479
DO  - 10.1016/j.jcis.2016.06.061
ER  - 
@article{
author = "Spasić, Aleksandar and Jovanović, Jovan M. and Manojlović, Vaso and Jovanović, Mica",
year = "2016",
abstract = "This research focuses on the modeling of the liquid-liquid dispersed system, including particular insight on the electrocoalescence (EC) process that occurs during the breaking of double emulsions. The representative system, used in this work, was taken from the pilot plant for solvent extraction of uranium from wet phosphoric acid. The chosen framework required for elucidation of the EC process is based on the electrohydrodynamic (EHD) principles. During the model development it was necessary to consider several theoretical concepts for easier understanding and description of the related events. The first is the concept of entities, and corresponding classification of finely dispersed systems. The second concept is an introduction of almost forgotten basic electrodynamics element the memdiode or memristor as a current controlled device, and corresponding memristive systems. Hence, the conclusions that may be withdrawn from the presented results and findings could enable easier designing of the solutions for a breaking of double emulsions problems, that is, the entrainment problems that may arise in some pilot or industrial plants. Finally, the perspectives and the remaining challenges, considering the here discussed concepts and model based on the EHD principles, are mentioned.",
publisher = "Academic Press Inc Elsevier Science, San Diego",
journal = "Journal of Colloid and Interface Science",
title = "Breaking of double emulsions based on electrohydrodynamics principles",
pages = "172-165",
volume = "479",
doi = "10.1016/j.jcis.2016.06.061"
}
Spasić, A., Jovanović, J. M., Manojlović, V.,& Jovanović, M.. (2016). Breaking of double emulsions based on electrohydrodynamics principles. in Journal of Colloid and Interface Science
Academic Press Inc Elsevier Science, San Diego., 479, 165-172.
https://doi.org/10.1016/j.jcis.2016.06.061
Spasić A, Jovanović JM, Manojlović V, Jovanović M. Breaking of double emulsions based on electrohydrodynamics principles. in Journal of Colloid and Interface Science. 2016;479:165-172.
doi:10.1016/j.jcis.2016.06.061 .
Spasić, Aleksandar, Jovanović, Jovan M., Manojlović, Vaso, Jovanović, Mica, "Breaking of double emulsions based on electrohydrodynamics principles" in Journal of Colloid and Interface Science, 479 (2016):165-172,
https://doi.org/10.1016/j.jcis.2016.06.061 . .
6
3
8

Risk maps for industrial occupational health and safety

Mandić-Rajčević, Stefan; Karanac, Milica; Mihajlović, Marina; Jovanović, Mića

(Univerzitet u Nišu, Niš, 2016)

TY  - JOUR
AU  - Mandić-Rajčević, Stefan
AU  - Karanac, Milica
AU  - Mihajlović, Marina
AU  - Jovanović, Mića
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3198
AB  - Risk assessment is a complex process, of which the outputs are often to be used by decision makers for policy development and risk management. Risk communication in Environmental sciences is often made simpler using risk maps, a method introduced in the early 60s in the United States, but evolved and rapidly developed following the advances in computer science and wide availability of personal computers. This methodology is widely used in Environmental sciences, but due to many similarities, it can be successfully applied to occupational health and safety, where workers may be exposed to multiple chemical, physical or biological agents. In this article we introduce the basic principles of risk mapping, and demonstrate an example of exploring risk using risk maps in a theoretical industrial site where workers are exposed to noise. Advantages and disadvantages of this system are discussed, and recommendations for successful use of risk maps in the field of occupational health and safety are outlined.
AB  - Procena rizika je kompleksan proces čiji se rezultati koriste za kreiranje politike bezbednosti i upravljanje rizikom. Za komunikaciju rizika u oblasti zaštite životne sredine često se koriste mape rizika, najpre u Sjedinjenim Američkim Državama početkom 60-tih godina. Ova metodologija u širokoj je upotrebi u oblasti zaštite životne sredine, a s obzirom na mnoge sličnosti, može se uspešno primeniti i na bezbednost i zdravlje na radu, gde su radnici često izloženi velikom broju hemijskih, fizičkih i bioloških štetnosti. U ovom radu su prikazani osnovni principi mapiranja rizika, praćeni teoretskim primerom konstrukcije mape rizika za industrijsko postrojenje gde su radnici izloženi buci. Predstavljene su prednosti i mane ove metodologije, uz preporuke za uspešnu upotrebu mapa rizika u oblasti bezbednosti i zdravlja na radu.
PB  - Univerzitet u Nišu, Niš
T2  - Facta universitatis - series: Working and Living Environmental Protection
T1  - Risk maps for industrial occupational health and safety
T1  - Mape rizika za zdravlje i bezbednost na radu u industriji
EP  - 72
IS  - 1
SP  - 63
VL  - 13
UR  - https://hdl.handle.net/21.15107/rcub_technorep_3198
ER  - 
@article{
author = "Mandić-Rajčević, Stefan and Karanac, Milica and Mihajlović, Marina and Jovanović, Mića",
year = "2016",
abstract = "Risk assessment is a complex process, of which the outputs are often to be used by decision makers for policy development and risk management. Risk communication in Environmental sciences is often made simpler using risk maps, a method introduced in the early 60s in the United States, but evolved and rapidly developed following the advances in computer science and wide availability of personal computers. This methodology is widely used in Environmental sciences, but due to many similarities, it can be successfully applied to occupational health and safety, where workers may be exposed to multiple chemical, physical or biological agents. In this article we introduce the basic principles of risk mapping, and demonstrate an example of exploring risk using risk maps in a theoretical industrial site where workers are exposed to noise. Advantages and disadvantages of this system are discussed, and recommendations for successful use of risk maps in the field of occupational health and safety are outlined., Procena rizika je kompleksan proces čiji se rezultati koriste za kreiranje politike bezbednosti i upravljanje rizikom. Za komunikaciju rizika u oblasti zaštite životne sredine često se koriste mape rizika, najpre u Sjedinjenim Američkim Državama početkom 60-tih godina. Ova metodologija u širokoj je upotrebi u oblasti zaštite životne sredine, a s obzirom na mnoge sličnosti, može se uspešno primeniti i na bezbednost i zdravlje na radu, gde su radnici često izloženi velikom broju hemijskih, fizičkih i bioloških štetnosti. U ovom radu su prikazani osnovni principi mapiranja rizika, praćeni teoretskim primerom konstrukcije mape rizika za industrijsko postrojenje gde su radnici izloženi buci. Predstavljene su prednosti i mane ove metodologije, uz preporuke za uspešnu upotrebu mapa rizika u oblasti bezbednosti i zdravlja na radu.",
publisher = "Univerzitet u Nišu, Niš",
journal = "Facta universitatis - series: Working and Living Environmental Protection",
title = "Risk maps for industrial occupational health and safety, Mape rizika za zdravlje i bezbednost na radu u industriji",
pages = "72-63",
number = "1",
volume = "13",
url = "https://hdl.handle.net/21.15107/rcub_technorep_3198"
}
Mandić-Rajčević, S., Karanac, M., Mihajlović, M.,& Jovanović, M.. (2016). Risk maps for industrial occupational health and safety. in Facta universitatis - series: Working and Living Environmental Protection
Univerzitet u Nišu, Niš., 13(1), 63-72.
https://hdl.handle.net/21.15107/rcub_technorep_3198
Mandić-Rajčević S, Karanac M, Mihajlović M, Jovanović M. Risk maps for industrial occupational health and safety. in Facta universitatis - series: Working and Living Environmental Protection. 2016;13(1):63-72.
https://hdl.handle.net/21.15107/rcub_technorep_3198 .
Mandić-Rajčević, Stefan, Karanac, Milica, Mihajlović, Marina, Jovanović, Mića, "Risk maps for industrial occupational health and safety" in Facta universitatis - series: Working and Living Environmental Protection, 13, no. 1 (2016):63-72,
https://hdl.handle.net/21.15107/rcub_technorep_3198 .

Volatile organic compounds (VOC) policy innovation in petrochemicals river barge transportation

Mihajlović, Marina; Jovanović, Mica; Pesić, Radmilo; Jovanović, Jovan; Milanović, Zorica

(Elsevier Sci Ltd, Oxford, 2016)

TY  - JOUR
AU  - Mihajlović, Marina
AU  - Jovanović, Mica
AU  - Pesić, Radmilo
AU  - Jovanović, Jovan
AU  - Milanović, Zorica
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3378
AB  - The aim of this paper was to emphasise the need for a volatile organic compounds VOC policy review in the field of river barge transportation of petrochemicals. Review of the VOC policy shows that barges neither fall under an integrated pollution prevention and control permit nor any other regulation or incentive related environmental policy. Current situation and trend in this area is presented through a case study of the Danube River, Serbia. The case study shows that evaporative losses have increased c ca 22 times in period 2006-2010 and, that vapour collection system can reduce VOC emissions by up to 3 times. A proposal for improved VOC policy has been developed in detail based on the following elements: a) The appropriate Best Available Techniques reference document (BREF) should include the transport sector; b) Mandatory reporting of VOC emitted during barge transport of crude oil and crude oil derivates should be introduced, and c) A pollution charge should be introduced on all barges without vapour collection system installed "onboard". Three potential scenarios for the VOC charge are presented, which vary according to the charge introducing dynamics. The differences between scenarios are in initial levels of charge, but the final charge is same for all three and it is proposed to be 220 (sic) per capacity ton.
PB  - Elsevier Sci Ltd, Oxford
T2  - Journal of Cleaner Production
T1  - Volatile organic compounds (VOC) policy innovation in petrochemicals river barge transportation
EP  - 1567
SP  - 1559
VL  - 112
DO  - 10.1016/j.jclepro.2015.04.080
ER  - 
@article{
author = "Mihajlović, Marina and Jovanović, Mica and Pesić, Radmilo and Jovanović, Jovan and Milanović, Zorica",
year = "2016",
abstract = "The aim of this paper was to emphasise the need for a volatile organic compounds VOC policy review in the field of river barge transportation of petrochemicals. Review of the VOC policy shows that barges neither fall under an integrated pollution prevention and control permit nor any other regulation or incentive related environmental policy. Current situation and trend in this area is presented through a case study of the Danube River, Serbia. The case study shows that evaporative losses have increased c ca 22 times in period 2006-2010 and, that vapour collection system can reduce VOC emissions by up to 3 times. A proposal for improved VOC policy has been developed in detail based on the following elements: a) The appropriate Best Available Techniques reference document (BREF) should include the transport sector; b) Mandatory reporting of VOC emitted during barge transport of crude oil and crude oil derivates should be introduced, and c) A pollution charge should be introduced on all barges without vapour collection system installed "onboard". Three potential scenarios for the VOC charge are presented, which vary according to the charge introducing dynamics. The differences between scenarios are in initial levels of charge, but the final charge is same for all three and it is proposed to be 220 (sic) per capacity ton.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Journal of Cleaner Production",
title = "Volatile organic compounds (VOC) policy innovation in petrochemicals river barge transportation",
pages = "1567-1559",
volume = "112",
doi = "10.1016/j.jclepro.2015.04.080"
}
Mihajlović, M., Jovanović, M., Pesić, R., Jovanović, J.,& Milanović, Z.. (2016). Volatile organic compounds (VOC) policy innovation in petrochemicals river barge transportation. in Journal of Cleaner Production
Elsevier Sci Ltd, Oxford., 112, 1559-1567.
https://doi.org/10.1016/j.jclepro.2015.04.080
Mihajlović M, Jovanović M, Pesić R, Jovanović J, Milanović Z. Volatile organic compounds (VOC) policy innovation in petrochemicals river barge transportation. in Journal of Cleaner Production. 2016;112:1559-1567.
doi:10.1016/j.jclepro.2015.04.080 .
Mihajlović, Marina, Jovanović, Mica, Pesić, Radmilo, Jovanović, Jovan, Milanović, Zorica, "Volatile organic compounds (VOC) policy innovation in petrochemicals river barge transportation" in Journal of Cleaner Production, 112 (2016):1559-1567,
https://doi.org/10.1016/j.jclepro.2015.04.080 . .
17
10
19

Continuous improvement concepts as a link between quality assurance and implementation of cleaner production - case study in the generic pharmaceutical industry

Boltić, Zorana; Jovanović, Mica; Petrović, Slobodan; Božanić, Vojislav; Mihajlović, Marina

(Savez hemijskih inženjera, Beograd, 2016)

TY  - JOUR
AU  - Boltić, Zorana
AU  - Jovanović, Mica
AU  - Petrović, Slobodan
AU  - Božanić, Vojislav
AU  - Mihajlović, Marina
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3449
AB  - The subject and the research objective presented in this article is establishing of the relationship between quality assurance and implementation of cleaner production in the generic pharmaceutical industry through the comprehensive concept of continuous improvement. This is mostly related to application of Lean and Six Sigma tools and techniques for process improvement and their link to other known concepts used in the industrial environment, especially manufacturing of generic pharmaceutical products from which two representative case studies were selected for comparative analysis, also considering relevant regulatory requirements in the field of quality management, as well as appropriate quality standards. Although the methodology discussed in this conceptual and practice oriented article is strongly related to chemical engineering, the focus is mainly on process industry, i.e., production systems, rather than any specific technological process itself. The scope of this research is an engineering approach to evaluation of the production systems in terms of continuous improvement concepts application, considering both quality aspects and efficiency of such systems.
PB  - Savez hemijskih inženjera, Beograd
T2  - Chemical Industry & Chemical Engineering Quarterly
T1  - Continuous improvement concepts as a link between quality assurance and implementation of cleaner production - case study in the generic pharmaceutical industry
EP  - 64
IS  - 1
SP  - 55
VL  - 22
DO  - 10.2298/CICEQ150430019B
ER  - 
@article{
author = "Boltić, Zorana and Jovanović, Mica and Petrović, Slobodan and Božanić, Vojislav and Mihajlović, Marina",
year = "2016",
abstract = "The subject and the research objective presented in this article is establishing of the relationship between quality assurance and implementation of cleaner production in the generic pharmaceutical industry through the comprehensive concept of continuous improvement. This is mostly related to application of Lean and Six Sigma tools and techniques for process improvement and their link to other known concepts used in the industrial environment, especially manufacturing of generic pharmaceutical products from which two representative case studies were selected for comparative analysis, also considering relevant regulatory requirements in the field of quality management, as well as appropriate quality standards. Although the methodology discussed in this conceptual and practice oriented article is strongly related to chemical engineering, the focus is mainly on process industry, i.e., production systems, rather than any specific technological process itself. The scope of this research is an engineering approach to evaluation of the production systems in terms of continuous improvement concepts application, considering both quality aspects and efficiency of such systems.",
publisher = "Savez hemijskih inženjera, Beograd",
journal = "Chemical Industry & Chemical Engineering Quarterly",
title = "Continuous improvement concepts as a link between quality assurance and implementation of cleaner production - case study in the generic pharmaceutical industry",
pages = "64-55",
number = "1",
volume = "22",
doi = "10.2298/CICEQ150430019B"
}
Boltić, Z., Jovanović, M., Petrović, S., Božanić, V.,& Mihajlović, M.. (2016). Continuous improvement concepts as a link between quality assurance and implementation of cleaner production - case study in the generic pharmaceutical industry. in Chemical Industry & Chemical Engineering Quarterly
Savez hemijskih inženjera, Beograd., 22(1), 55-64.
https://doi.org/10.2298/CICEQ150430019B
Boltić Z, Jovanović M, Petrović S, Božanić V, Mihajlović M. Continuous improvement concepts as a link between quality assurance and implementation of cleaner production - case study in the generic pharmaceutical industry. in Chemical Industry & Chemical Engineering Quarterly. 2016;22(1):55-64.
doi:10.2298/CICEQ150430019B .
Boltić, Zorana, Jovanović, Mica, Petrović, Slobodan, Božanić, Vojislav, Mihajlović, Marina, "Continuous improvement concepts as a link between quality assurance and implementation of cleaner production - case study in the generic pharmaceutical industry" in Chemical Industry & Chemical Engineering Quarterly, 22, no. 1 (2016):55-64,
https://doi.org/10.2298/CICEQ150430019B . .
9
6
9

Landfill design: need for improvement of water and soil protection requirements in EU Landfill Directive

Dajić, Ana; Mihajlović, Marina; Jovanović, Mica; Karanac, Milica; Stevanović, Dimitrije; Jovanović, Jovan

(Springer, New York, 2016)

TY  - JOUR
AU  - Dajić, Ana
AU  - Mihajlović, Marina
AU  - Jovanović, Mica
AU  - Karanac, Milica
AU  - Stevanović, Dimitrije
AU  - Jovanović, Jovan
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3461
AB  - This paper deals with environmental policy issues related to a landfill design. The final product of numerous waste treatments should be placed on a landfill. Before waste disposal, the ground should be protected by a mineral layer with properties required by the related regulation. In order to prevent environment pollution, EU adopted the Landfill Directive 1999/31/EC. The most important technical requirements related to the characteristics of the layer material are water permeability and thickness. The performed comparative national regulatory analysis raised the question of the need for more uniform elaboration of the directive requirements over the whole European Union area (including EU candidates). The choice of the material for the impermeable mineral layer, which should be made during landfill design, is a very important decision. Methods for the determination of the permeability coefficient were analysed, showing that the Directive should define hydraulic gradient as a physical quantity and define its value through measurement of the permeability coefficient. The paper analyses whether some parts of the Directive, as landfill design BAT and base for national legislative acts, require further elaboration in order to provide sufficient information about proper protection of soil and water. Using integrated approach, seven amendments on the directive annex I were suggested related to (a) the meaning of the term artificially established geological barrier, (b) layer thickness,
PB  - Springer, New York
T2  - Clean Technologies and Environmental Policy
T1  - Landfill design: need for improvement of water and soil protection requirements in EU Landfill Directive
EP  - 764
IS  - 3
SP  - 753
VL  - 18
DO  - 10.1007/s10098-015-1046-2
ER  - 
@article{
author = "Dajić, Ana and Mihajlović, Marina and Jovanović, Mica and Karanac, Milica and Stevanović, Dimitrije and Jovanović, Jovan",
year = "2016",
abstract = "This paper deals with environmental policy issues related to a landfill design. The final product of numerous waste treatments should be placed on a landfill. Before waste disposal, the ground should be protected by a mineral layer with properties required by the related regulation. In order to prevent environment pollution, EU adopted the Landfill Directive 1999/31/EC. The most important technical requirements related to the characteristics of the layer material are water permeability and thickness. The performed comparative national regulatory analysis raised the question of the need for more uniform elaboration of the directive requirements over the whole European Union area (including EU candidates). The choice of the material for the impermeable mineral layer, which should be made during landfill design, is a very important decision. Methods for the determination of the permeability coefficient were analysed, showing that the Directive should define hydraulic gradient as a physical quantity and define its value through measurement of the permeability coefficient. The paper analyses whether some parts of the Directive, as landfill design BAT and base for national legislative acts, require further elaboration in order to provide sufficient information about proper protection of soil and water. Using integrated approach, seven amendments on the directive annex I were suggested related to (a) the meaning of the term artificially established geological barrier, (b) layer thickness,",
publisher = "Springer, New York",
journal = "Clean Technologies and Environmental Policy",
title = "Landfill design: need for improvement of water and soil protection requirements in EU Landfill Directive",
pages = "764-753",
number = "3",
volume = "18",
doi = "10.1007/s10098-015-1046-2"
}
Dajić, A., Mihajlović, M., Jovanović, M., Karanac, M., Stevanović, D.,& Jovanović, J.. (2016). Landfill design: need for improvement of water and soil protection requirements in EU Landfill Directive. in Clean Technologies and Environmental Policy
Springer, New York., 18(3), 753-764.
https://doi.org/10.1007/s10098-015-1046-2
Dajić A, Mihajlović M, Jovanović M, Karanac M, Stevanović D, Jovanović J. Landfill design: need for improvement of water and soil protection requirements in EU Landfill Directive. in Clean Technologies and Environmental Policy. 2016;18(3):753-764.
doi:10.1007/s10098-015-1046-2 .
Dajić, Ana, Mihajlović, Marina, Jovanović, Mica, Karanac, Milica, Stevanović, Dimitrije, Jovanović, Jovan, "Landfill design: need for improvement of water and soil protection requirements in EU Landfill Directive" in Clean Technologies and Environmental Policy, 18, no. 3 (2016):753-764,
https://doi.org/10.1007/s10098-015-1046-2 . .
26
12
27

Landfill design in Serbia

Karanac, Milica; Jovanović, Mića; Mihajlović, Marina; Dajić, Ana; Stevanović, Dimitrije; Jovanović, Jovan

(University of Belgrade, Technical Faculty in Bor, 2015)

TY  - JOUR
AU  - Karanac, Milica
AU  - Jovanović, Mića
AU  - Mihajlović, Marina
AU  - Dajić, Ana
AU  - Stevanović, Dimitrije
AU  - Jovanović, Jovan
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2931
AB  - Waste disposal is an important element of integrated waste management. In order to dispose of waste that is free of environmental risk, the proper design of landfills during their construction and/or closure is necessary. The first section of the paper presents the current state of landfills in Serbia, the second deals with problems in project design of landfills, especially in regard to their: a) program of waste disposal; b) impermeable layer; c) leaching collection and treatment; and d) gas collection and treatment. Analysis shows that many modern landfills in Serbia do not meet environmental protection requirements, therefore, they need reconstruction. All existing landfills owned by municipalities, as well as illegal dump sites, should be adequately closed. This paper presents the guidelines for successful landfill design which are to serve to meet the requirements and recommendations of Serbian and European regulations. Sound design of landfill technological elements should insure full sustainability of landfills in Serbia.
AB  - Deponovanje otpada je element integrisanog upravljanja otpadom. Valjano izrađeni projekti izgradnje i/ili zatvaranja deponije osiguravaju bezbedno odlaganje otpada, uz minimalne negativne uticaje na životnu sredinu. U prvom delu rada izvršen je pregled i analiza deponija u Republici Srbiji. U drugom delu rada, u funkciji analize, opisani su značajni elementi tehnološkog projektovanja savremenih deponija koji uključuju: a) program deponovanja, b) obezbeđivanje vodonepropusnosti dna i prekrivnog sloja, c) sakupljanje i tretman procednih voda i d) sakupljanje, tretman i iskorišćenje deponijskog gasa. U radu je konstatovano da postojeće, savremene deponije nisu u potpunosti projektovane u skladu sa propisima, te da je neophodna njihova rekonstrukcija. Takođe, postojeća smetilišta i divlje deponije neophodno je zatvoriti i sanirati. U ovom radu predstavljene su smernice za valjano tehnološko projektovanje deponija koje su u funkciji ispunjavanja zahteva i preporuka nacionalnih i evropskih propisa.
PB  - University of Belgrade, Technical Faculty in Bor
T2  - Recycling and Sustainable Development
T1  - Landfill design in Serbia
T1  - Prilog tehnološkom projektovanju deponija u Srbiji
EP  - 37
IS  - 1
SP  - 27
VL  - 8
DO  - 10.5937/ror1501027K
ER  - 
@article{
author = "Karanac, Milica and Jovanović, Mića and Mihajlović, Marina and Dajić, Ana and Stevanović, Dimitrije and Jovanović, Jovan",
year = "2015",
abstract = "Waste disposal is an important element of integrated waste management. In order to dispose of waste that is free of environmental risk, the proper design of landfills during their construction and/or closure is necessary. The first section of the paper presents the current state of landfills in Serbia, the second deals with problems in project design of landfills, especially in regard to their: a) program of waste disposal; b) impermeable layer; c) leaching collection and treatment; and d) gas collection and treatment. Analysis shows that many modern landfills in Serbia do not meet environmental protection requirements, therefore, they need reconstruction. All existing landfills owned by municipalities, as well as illegal dump sites, should be adequately closed. This paper presents the guidelines for successful landfill design which are to serve to meet the requirements and recommendations of Serbian and European regulations. Sound design of landfill technological elements should insure full sustainability of landfills in Serbia., Deponovanje otpada je element integrisanog upravljanja otpadom. Valjano izrađeni projekti izgradnje i/ili zatvaranja deponije osiguravaju bezbedno odlaganje otpada, uz minimalne negativne uticaje na životnu sredinu. U prvom delu rada izvršen je pregled i analiza deponija u Republici Srbiji. U drugom delu rada, u funkciji analize, opisani su značajni elementi tehnološkog projektovanja savremenih deponija koji uključuju: a) program deponovanja, b) obezbeđivanje vodonepropusnosti dna i prekrivnog sloja, c) sakupljanje i tretman procednih voda i d) sakupljanje, tretman i iskorišćenje deponijskog gasa. U radu je konstatovano da postojeće, savremene deponije nisu u potpunosti projektovane u skladu sa propisima, te da je neophodna njihova rekonstrukcija. Takođe, postojeća smetilišta i divlje deponije neophodno je zatvoriti i sanirati. U ovom radu predstavljene su smernice za valjano tehnološko projektovanje deponija koje su u funkciji ispunjavanja zahteva i preporuka nacionalnih i evropskih propisa.",
publisher = "University of Belgrade, Technical Faculty in Bor",
journal = "Recycling and Sustainable Development",
title = "Landfill design in Serbia, Prilog tehnološkom projektovanju deponija u Srbiji",
pages = "37-27",
number = "1",
volume = "8",
doi = "10.5937/ror1501027K"
}
Karanac, M., Jovanović, M., Mihajlović, M., Dajić, A., Stevanović, D.,& Jovanović, J.. (2015). Landfill design in Serbia. in Recycling and Sustainable Development
University of Belgrade, Technical Faculty in Bor., 8(1), 27-37.
https://doi.org/10.5937/ror1501027K
Karanac M, Jovanović M, Mihajlović M, Dajić A, Stevanović D, Jovanović J. Landfill design in Serbia. in Recycling and Sustainable Development. 2015;8(1):27-37.
doi:10.5937/ror1501027K .
Karanac, Milica, Jovanović, Mića, Mihajlović, Marina, Dajić, Ana, Stevanović, Dimitrije, Jovanović, Jovan, "Landfill design in Serbia" in Recycling and Sustainable Development, 8, no. 1 (2015):27-37,
https://doi.org/10.5937/ror1501027K . .
3

Reduction of volatile organic compounds emissions in crude oil industry by cleaner production principles.

Mihajlović, Marina

(Univerzitet u Beogradu, Tehnološko-metalurški fakultet, 2015)

TY  - THES
AU  - Mihajlović, Marina
PY  - 2015
UR  - http://eteze.bg.ac.rs/application/showtheses?thesesId=3096
UR  - https://fedorabg.bg.ac.rs/fedora/get/o:11376/bdef:Content/download
UR  - http://vbs.rs/scripts/cobiss?command=DISPLAY&base=70036&RID=47497487
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4628
AB  - Crude oil and its derivates are a significant source of VOC, i.e., volatile organic compounds. A goal of this research is to set a base for VOC emission reduction through engineering design and proactive actions as a cleaner production strategy. This doctoral dissertation analyses a possibilities of reducing diffuse VOC emissions and propose appropriate measures for it. Oil refinery VOC emissions need to be first quantified and then reduced by application of cleaner production principles. Influences of a particular parameter on obtained results are determined by the sensitivity analyses method. A case study as scientific method was used in order to: a) quantify and determine the gaseous VOC emissions trends and b) prepare the ground for a policy change in this area. Conducted case studies covered crude oil derivates manipulation processes (loading, wastewater treatment) and transport. Based on the results, proactive VOC emissions reduction measures are proposed. Diffuse emissions from crude oil fixed roof storage tank losses are cca. 0.5 kg per tone of crude oil. For floating roof, crude oil losses are 10-3 kg/t. Fuel oil (diesel fuel and heating oil) have the smallest evaporation losses, which are in order of magnitude 10–3 kg/tone. Liquids with higher Reid Vapour Pressure have very high evaporative losses for tanks with fixed roof, up to 2.07 kg/tone. A case study of petrochemicals river barge transportation on the Danube River in Serbia showed that evaporative losses have increased cca. 22 times in period 2006-2010 and, that vapour collection system can reduce VOC emissions by up to 3 times...
AB  - Industrija prerade nafte predstavlja jedan od najznačajnijih izvora lakoisparljivih organskih jedinjenja VOC (eng. Volatile Organic Compounds) u industrijskom sektoru. Cilј ovog naučnog istraživanja je postavlјanje osnova u tehnološkom projektovanju kojima se postiže smanjenje emisija VOC kroz definisanje proaktivne strategije kao važnog činioca čistije proizvodnje. Ova doktorska disertacija ispituje mogućnosti smanjenja difuznih VOC emisija i predlaže mere za njihovo smanjivanje. Štetne uticaje, koji su rezultat tehnoloških procesa u rafinerijama nafte, neophodno je najpre valjano kvantifikovati i zatim ublažiti primenom tehnika čistije proizvodnje. Metodom analize osetlјivosti ispitan je uticaj kritičnih parametara na kvantitet VOC emisija. Naučna metoda studije slučaja korišćena je za a) utvrđivanje kvantiteta i trenda kretanja gasovitih VOC emisija i b) radi utvrđivanja potrebe za definisanjem novih pristupa u ovoj oblasti. Studije slučaja, koje ispituju problem i njegovo rešenje u kontekstu realnog industrijskog okruženja, obuhvatile su procese manipulacije naftnim derivatima i njihov transport. Na osnovu rezultata studija slučaja predložene su metode za proaktivno delovanje u cilju smanjenja VOC emisija. Emisije iz skladišnih rezervoara sirove nafte iznose oko 0,5 kg/t za rezervoare sa fiksnim krovom, a 10–3 kg/t za rezervoare sa plutajućim krovom. Emisije dizela i mazuta su zanemarljivo male i iznose do 10–3 kg/t. Najmanje emisije isparljivih naftnih derivata javljaju se u slučaju rezervoara sa kupolastim krovom (oko 0,004 kg/t), a najviše u slučaju rezervoara sa fiksnim krovom (do 2,07 kg/t). Studija slučaja transporta nafte i naftnih derivata na reci Dunav u Republici Srbiji pokazala je porast emisija koje nastaju u toku pretakanja i plovidbe cca 22 puta u periodu 2006-2010. godina...
PB  - Univerzitet u Beogradu, Tehnološko-metalurški fakultet
T1  - Reduction of volatile organic compounds emissions in crude oil industry by cleaner production principles.
T1  - Smanjenje emisija lakoisparljivih organskih jedinjenja u industriji prerade nafte primenom čistije proizvodnje
UR  - https://hdl.handle.net/21.15107/rcub_technorep_4628
ER  - 
@phdthesis{
author = "Mihajlović, Marina",
year = "2015",
abstract = "Crude oil and its derivates are a significant source of VOC, i.e., volatile organic compounds. A goal of this research is to set a base for VOC emission reduction through engineering design and proactive actions as a cleaner production strategy. This doctoral dissertation analyses a possibilities of reducing diffuse VOC emissions and propose appropriate measures for it. Oil refinery VOC emissions need to be first quantified and then reduced by application of cleaner production principles. Influences of a particular parameter on obtained results are determined by the sensitivity analyses method. A case study as scientific method was used in order to: a) quantify and determine the gaseous VOC emissions trends and b) prepare the ground for a policy change in this area. Conducted case studies covered crude oil derivates manipulation processes (loading, wastewater treatment) and transport. Based on the results, proactive VOC emissions reduction measures are proposed. Diffuse emissions from crude oil fixed roof storage tank losses are cca. 0.5 kg per tone of crude oil. For floating roof, crude oil losses are 10-3 kg/t. Fuel oil (diesel fuel and heating oil) have the smallest evaporation losses, which are in order of magnitude 10–3 kg/tone. Liquids with higher Reid Vapour Pressure have very high evaporative losses for tanks with fixed roof, up to 2.07 kg/tone. A case study of petrochemicals river barge transportation on the Danube River in Serbia showed that evaporative losses have increased cca. 22 times in period 2006-2010 and, that vapour collection system can reduce VOC emissions by up to 3 times..., Industrija prerade nafte predstavlja jedan od najznačajnijih izvora lakoisparljivih organskih jedinjenja VOC (eng. Volatile Organic Compounds) u industrijskom sektoru. Cilј ovog naučnog istraživanja je postavlјanje osnova u tehnološkom projektovanju kojima se postiže smanjenje emisija VOC kroz definisanje proaktivne strategije kao važnog činioca čistije proizvodnje. Ova doktorska disertacija ispituje mogućnosti smanjenja difuznih VOC emisija i predlaže mere za njihovo smanjivanje. Štetne uticaje, koji su rezultat tehnoloških procesa u rafinerijama nafte, neophodno je najpre valjano kvantifikovati i zatim ublažiti primenom tehnika čistije proizvodnje. Metodom analize osetlјivosti ispitan je uticaj kritičnih parametara na kvantitet VOC emisija. Naučna metoda studije slučaja korišćena je za a) utvrđivanje kvantiteta i trenda kretanja gasovitih VOC emisija i b) radi utvrđivanja potrebe za definisanjem novih pristupa u ovoj oblasti. Studije slučaja, koje ispituju problem i njegovo rešenje u kontekstu realnog industrijskog okruženja, obuhvatile su procese manipulacije naftnim derivatima i njihov transport. Na osnovu rezultata studija slučaja predložene su metode za proaktivno delovanje u cilju smanjenja VOC emisija. Emisije iz skladišnih rezervoara sirove nafte iznose oko 0,5 kg/t za rezervoare sa fiksnim krovom, a 10–3 kg/t za rezervoare sa plutajućim krovom. Emisije dizela i mazuta su zanemarljivo male i iznose do 10–3 kg/t. Najmanje emisije isparljivih naftnih derivata javljaju se u slučaju rezervoara sa kupolastim krovom (oko 0,004 kg/t), a najviše u slučaju rezervoara sa fiksnim krovom (do 2,07 kg/t). Studija slučaja transporta nafte i naftnih derivata na reci Dunav u Republici Srbiji pokazala je porast emisija koje nastaju u toku pretakanja i plovidbe cca 22 puta u periodu 2006-2010. godina...",
publisher = "Univerzitet u Beogradu, Tehnološko-metalurški fakultet",
title = "Reduction of volatile organic compounds emissions in crude oil industry by cleaner production principles., Smanjenje emisija lakoisparljivih organskih jedinjenja u industriji prerade nafte primenom čistije proizvodnje",
url = "https://hdl.handle.net/21.15107/rcub_technorep_4628"
}
Mihajlović, M.. (2015). Reduction of volatile organic compounds emissions in crude oil industry by cleaner production principles.. 
Univerzitet u Beogradu, Tehnološko-metalurški fakultet..
https://hdl.handle.net/21.15107/rcub_technorep_4628
Mihajlović M. Reduction of volatile organic compounds emissions in crude oil industry by cleaner production principles.. 2015;.
https://hdl.handle.net/21.15107/rcub_technorep_4628 .
Mihajlović, Marina, "Reduction of volatile organic compounds emissions in crude oil industry by cleaner production principles." (2015),
https://hdl.handle.net/21.15107/rcub_technorep_4628 .

Application of process simulators in chemical engineering process design: Natural gas separation plant case study

Stevanović, Dimitrije; Jovanović, Mića B.; Mihajlović, Marina; Jovanović, Jovan M.; Grbavčić, Željko

(Association of Chemical Engineers of Serbia, 2014)

TY  - JOUR
AU  - Stevanović, Dimitrije
AU  - Jovanović, Mića B.
AU  - Mihajlović, Marina
AU  - Jovanović, Jovan M.
AU  - Grbavčić, Željko
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2640
AB  - Software for chemical processes modeling and simulation, in the past few decades, plays an important role in the development of chemical-process industry with its growing capabilities and wide range of application. Usage of process simulators in Serbia for the process design is very limited. This paper gives a brief overview of the numerous process simulators that are used in the chemical-process industry today. The conceptual design is responsible for most of the investment costs in chemical process industry. Importance of precise design on preliminary level is obvious. Wrong decisions made at the conceptual level could be carried out throughout the chain in process design to the detailed design procedures and procurement of equipment. Although preliminary design phase comprises only about 2% of the total cost of the project, it contributes significantly to the reduction of cost of the project by more than 30%. Therefore process simulators play important role in elimination of unnecessary errors in basic process design. Here is also shown a case study of parallel process simulated in different process simulators which tests the results, the reliability and usefulness of these programs in solving specific engineering tasks. Comparison of given simulation results confirm that the modern process simulators are at high level of confidence, no matter they are based on different models, equations, methods, operations, interfaces or data bases. Usage of software speeds up the arrival of optimized solution during the design and the operational procedures. Therefore software has significant impact on reducing time of pre-project phase such as research, conceptual design, and proving project abilities. Its development leads to the faster commercialization of industrial ideas.
AB  - Softveri za modelovanje i simulaciju tehnoloških procesa u poslednjih nekoliko decenija imaju značajnu ulogu u razvoju procesne industrije. Korišćenje procesnih simulatora,u našoj zemlji, za potrebe projektovanja tehnoloških procesa nije široko rasprostranjeno, a literatura je nedovoljna. U ovom radu je dat pregled savremenih procesnih simulatora i prikazane su njihove mogućnosti za projektovanja procesa u zavisnosti od grane hemijske industrije. Prikazna je studija slučaja tehnološkog procesa u više procesnih simulatora koja ispituje rezultate, pouzdanost i upotrebljivost ovih programa prilikom rešavanja konkretnih projektantskih zadatka na primeru postrojenja za separaciju prirodnog gasa. Date su uporedne karakteristike rezulata simuliranja separacije prirodnog gasa za potrebe projektovanja procesa, na osnovu simulacija u softverima različitih složenosti i kvaliteta. Procesni simulatori su pokazali svoju upotrebnu vrednost kao značajan oslonac projektantima, iako rezultati koje su pokazali međusobno imaju značajna odstupanja.
PB  - Association of Chemical Engineers of Serbia
T2  - Hemijska industrija
T1  - Application of process simulators in chemical engineering process design: Natural gas separation plant case study
T1  - Analiza simulatora tehnoloških procesa u funkciji projektovanja - studija slučaja separacije prirodnog gasa
EP  - 558
IS  - 5
SP  - 547
VL  - 68
DO  - 10.2298/HEMIND130424002S
ER  - 
@article{
author = "Stevanović, Dimitrije and Jovanović, Mića B. and Mihajlović, Marina and Jovanović, Jovan M. and Grbavčić, Željko",
year = "2014",
abstract = "Software for chemical processes modeling and simulation, in the past few decades, plays an important role in the development of chemical-process industry with its growing capabilities and wide range of application. Usage of process simulators in Serbia for the process design is very limited. This paper gives a brief overview of the numerous process simulators that are used in the chemical-process industry today. The conceptual design is responsible for most of the investment costs in chemical process industry. Importance of precise design on preliminary level is obvious. Wrong decisions made at the conceptual level could be carried out throughout the chain in process design to the detailed design procedures and procurement of equipment. Although preliminary design phase comprises only about 2% of the total cost of the project, it contributes significantly to the reduction of cost of the project by more than 30%. Therefore process simulators play important role in elimination of unnecessary errors in basic process design. Here is also shown a case study of parallel process simulated in different process simulators which tests the results, the reliability and usefulness of these programs in solving specific engineering tasks. Comparison of given simulation results confirm that the modern process simulators are at high level of confidence, no matter they are based on different models, equations, methods, operations, interfaces or data bases. Usage of software speeds up the arrival of optimized solution during the design and the operational procedures. Therefore software has significant impact on reducing time of pre-project phase such as research, conceptual design, and proving project abilities. Its development leads to the faster commercialization of industrial ideas., Softveri za modelovanje i simulaciju tehnoloških procesa u poslednjih nekoliko decenija imaju značajnu ulogu u razvoju procesne industrije. Korišćenje procesnih simulatora,u našoj zemlji, za potrebe projektovanja tehnoloških procesa nije široko rasprostranjeno, a literatura je nedovoljna. U ovom radu je dat pregled savremenih procesnih simulatora i prikazane su njihove mogućnosti za projektovanja procesa u zavisnosti od grane hemijske industrije. Prikazna je studija slučaja tehnološkog procesa u više procesnih simulatora koja ispituje rezultate, pouzdanost i upotrebljivost ovih programa prilikom rešavanja konkretnih projektantskih zadatka na primeru postrojenja za separaciju prirodnog gasa. Date su uporedne karakteristike rezulata simuliranja separacije prirodnog gasa za potrebe projektovanja procesa, na osnovu simulacija u softverima različitih složenosti i kvaliteta. Procesni simulatori su pokazali svoju upotrebnu vrednost kao značajan oslonac projektantima, iako rezultati koje su pokazali međusobno imaju značajna odstupanja.",
publisher = "Association of Chemical Engineers of Serbia",
journal = "Hemijska industrija",
title = "Application of process simulators in chemical engineering process design: Natural gas separation plant case study, Analiza simulatora tehnoloških procesa u funkciji projektovanja - studija slučaja separacije prirodnog gasa",
pages = "558-547",
number = "5",
volume = "68",
doi = "10.2298/HEMIND130424002S"
}
Stevanović, D., Jovanović, M. B., Mihajlović, M., Jovanović, J. M.,& Grbavčić, Ž.. (2014). Application of process simulators in chemical engineering process design: Natural gas separation plant case study. in Hemijska industrija
Association of Chemical Engineers of Serbia., 68(5), 547-558.
https://doi.org/10.2298/HEMIND130424002S
Stevanović D, Jovanović MB, Mihajlović M, Jovanović JM, Grbavčić Ž. Application of process simulators in chemical engineering process design: Natural gas separation plant case study. in Hemijska industrija. 2014;68(5):547-558.
doi:10.2298/HEMIND130424002S .
Stevanović, Dimitrije, Jovanović, Mića B., Mihajlović, Marina, Jovanović, Jovan M., Grbavčić, Željko, "Application of process simulators in chemical engineering process design: Natural gas separation plant case study" in Hemijska industrija, 68, no. 5 (2014):547-558,
https://doi.org/10.2298/HEMIND130424002S . .

Impermeable layers in landfill design

Karanac, Milica; Jovanović, Mića; Timmermans, Eugène; Mulleneers, Huib; Mihajlović, Marina; Jovanović, Jovan

(Association of Chemical Engineers of Serbia, 2013)

TY  - JOUR
AU  - Karanac, Milica
AU  - Jovanović, Mića
AU  - Timmermans, Eugène
AU  - Mulleneers, Huib
AU  - Mihajlović, Marina
AU  - Jovanović, Jovan
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2306
AB  - Landfills are complex systems that could potentially contaminate the environment. This needs to be prevented by providing impermeability during the landfill design. In this aim, the related regulations should be followed and adequate materials that provide impermeability should be used. The first part of the paper presents a review of the current regulations, interpretations, and recommendations from the U.S., EU and Republic of Serbia. Knowing that the Serbian regulation should fully follow the related European Directive, some inadequate formulations and terms were observed in the analyses related to the Directive Annex I, 3.2. Request of the Regulation that deals with the bottom of the landfill leakage is formulated differently than in the Directive as well. The mentioned problems enable some design solutions that are not among the best available techniques. In the second part, the paper presents a comparative analysis of possible alternatives in impermeable layer design, both for the bottom and landfill cover. Some materials like clay, CCL, GCL might not be able to satisfy the prescribed requirements. The longest lifetime and the lowest coefficient of permeability, as well as excellent mechanical, chemical and thermal stability, show the mixture of sand, bentonite and polymers (PEBSM).
AB  - Deponije predstavljaju složen sistem koji potencijalno može zagaditi životnu sredinu, što se sprečava obezbeđenjem vodonepropusnosti prilikom njihovog projektovanja. Prvi deo preglednog rada bavi se analizom odgovarajućih tehničkih propisa, tumačenja i preporuka iz SAD, EU i Srbije, u cilju podsticanja valjanog usaglašavanja domaće prakse i propisa sa najboljim dostupnim tehnikama na međunarodnom nivou. U drugom delu rada uporedno su analizirane alternative prilikom projektovanja vodonepropusnih slojeva za oblaganje dna i prekrivanje deponija. Opisane su slabosti i prednosti korišćenja prirodne gline, bentonita, geosintetičke glinene obloge i različitih mešavina peska, bentonita i polimera. Rad zaključno formuliše predlog unapređenja nacionalnog propisa o odlaganju otpada na deponije.
PB  - Association of Chemical Engineers of Serbia
T2  - Hemijska industrija
T1  - Impermeable layers in landfill design
T1  - Prilog projektovanju vodonepropusnih slojeva deponija
EP  - 973
IS  - 6
SP  - 961
VL  - 67
DO  - 10.2298/HEMIND121227012K
ER  - 
@article{
author = "Karanac, Milica and Jovanović, Mića and Timmermans, Eugène and Mulleneers, Huib and Mihajlović, Marina and Jovanović, Jovan",
year = "2013",
abstract = "Landfills are complex systems that could potentially contaminate the environment. This needs to be prevented by providing impermeability during the landfill design. In this aim, the related regulations should be followed and adequate materials that provide impermeability should be used. The first part of the paper presents a review of the current regulations, interpretations, and recommendations from the U.S., EU and Republic of Serbia. Knowing that the Serbian regulation should fully follow the related European Directive, some inadequate formulations and terms were observed in the analyses related to the Directive Annex I, 3.2. Request of the Regulation that deals with the bottom of the landfill leakage is formulated differently than in the Directive as well. The mentioned problems enable some design solutions that are not among the best available techniques. In the second part, the paper presents a comparative analysis of possible alternatives in impermeable layer design, both for the bottom and landfill cover. Some materials like clay, CCL, GCL might not be able to satisfy the prescribed requirements. The longest lifetime and the lowest coefficient of permeability, as well as excellent mechanical, chemical and thermal stability, show the mixture of sand, bentonite and polymers (PEBSM)., Deponije predstavljaju složen sistem koji potencijalno može zagaditi životnu sredinu, što se sprečava obezbeđenjem vodonepropusnosti prilikom njihovog projektovanja. Prvi deo preglednog rada bavi se analizom odgovarajućih tehničkih propisa, tumačenja i preporuka iz SAD, EU i Srbije, u cilju podsticanja valjanog usaglašavanja domaće prakse i propisa sa najboljim dostupnim tehnikama na međunarodnom nivou. U drugom delu rada uporedno su analizirane alternative prilikom projektovanja vodonepropusnih slojeva za oblaganje dna i prekrivanje deponija. Opisane su slabosti i prednosti korišćenja prirodne gline, bentonita, geosintetičke glinene obloge i različitih mešavina peska, bentonita i polimera. Rad zaključno formuliše predlog unapređenja nacionalnog propisa o odlaganju otpada na deponije.",
publisher = "Association of Chemical Engineers of Serbia",
journal = "Hemijska industrija",
title = "Impermeable layers in landfill design, Prilog projektovanju vodonepropusnih slojeva deponija",
pages = "973-961",
number = "6",
volume = "67",
doi = "10.2298/HEMIND121227012K"
}
Karanac, M., Jovanović, M., Timmermans, E., Mulleneers, H., Mihajlović, M.,& Jovanović, J.. (2013). Impermeable layers in landfill design. in Hemijska industrija
Association of Chemical Engineers of Serbia., 67(6), 961-973.
https://doi.org/10.2298/HEMIND121227012K
Karanac M, Jovanović M, Timmermans E, Mulleneers H, Mihajlović M, Jovanović J. Impermeable layers in landfill design. in Hemijska industrija. 2013;67(6):961-973.
doi:10.2298/HEMIND121227012K .
Karanac, Milica, Jovanović, Mića, Timmermans, Eugène, Mulleneers, Huib, Mihajlović, Marina, Jovanović, Jovan, "Impermeable layers in landfill design" in Hemijska industrija, 67, no. 6 (2013):961-973,
https://doi.org/10.2298/HEMIND121227012K . .
2
2
3

VOC emission from oil refinery and petrochemical wastewater treatment plant estimation

Mihajlović, Marina; Stevanović, Dimitrije; Jovanović, Jovan M.; Jovanović, Mića B.

(Association of Chemical Engineers of Serbia, 2013)

TY  - JOUR
AU  - Mihajlović, Marina
AU  - Stevanović, Dimitrije
AU  - Jovanović, Jovan M.
AU  - Jovanović, Mića B.
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2343
AB  - As a consequence of environmental legislation improvement in Serbia for industrial producers, especially future holders of Integrated Pollution Prevention Control (IPPC) license, it is necessary to report annually on emissions of pollutants emitted into the environment and pay certain environmental fees. Wastewater treatment plants can be significant sources of volatile organic compounds (VOCs) diffuse emissions, which are difficult to measure directly. Reporting obligations may also expand to benzene and other VOCs in the near future. This paper deals with gaseous emissions calculations from an API separator, based on emission factors and adequate software applications. The analyses results show that the estimated emission values are significantly different, depending on the applied method. VOC emissions have been estimated using US EPA and CONCAWE emissions factors. Calculated emissions range from 40 to 4500 tons/year for oil refinery WWTP of 2,000,000 m3/year. The calculations of benzene and toluene emissions have been performed using three methods: U.S. EPA emission factors, and WATER9 and Toxchem+ software. The calculated benzene and toluene emissions range from 5.5-60 and 0.7-20 tons/year, respectively. U.S. EPA emission factors give the highest values and Toxchem+ the lowest estimation values. Sensitivity analysis of obtained results included the following parameters: flow, temperature, oil content and the concentration of benzene and toluene in the effluent. The wide range of results indicates the need for their official interpretation for the conditions that are typical for Serbia if, in the future, the "polluter pays" principle should be applied to VOC and benzene emissions. The proposal is that adequate national emission factors should be established.
AB  - Stupanjem na snagu novih zakonskih akata, industrijski zagađivači u Srbiji - budući nosioci integrisane dozvole, dužni su da na godišnjem nivou izveštavaju o emisijama štetnih gasova koji se ispuštaju u životnu sredinu i da u skladu sa time plaćaju određene ekološke naknade. Obaveza izveštavanja u skorijoj budućnosti može se proširiti na benzen i druge lako isparljive ugljovodonike. Predmet analize ovog rada su primena emisionih faktora i softverske simulacije za proračun gasovitih emisija iz postrojenja za tretman otpadnih voda. Rezultati pokazuju da se izračunate vrednosti emisija značajno razlikuju od metode do metode, a u diskusiji se posebna pažnja obraća na procenu pouzdanosti svake od njih.
PB  - Association of Chemical Engineers of Serbia
T2  - Hemijska industrija
T1  - VOC emission from oil refinery and petrochemical wastewater treatment plant estimation
T1  - Procena emisija lakoisparljivih organskih jedinjenja iz postrojenja za primarni tretman otpadnih voda rafinerijskih i petrohemijskih postrojenja
EP  - 373
IS  - 2
SP  - 365
VL  - 67
DO  - 10.2298/HEMIND120427077S
ER  - 
@article{
author = "Mihajlović, Marina and Stevanović, Dimitrije and Jovanović, Jovan M. and Jovanović, Mića B.",
year = "2013",
abstract = "As a consequence of environmental legislation improvement in Serbia for industrial producers, especially future holders of Integrated Pollution Prevention Control (IPPC) license, it is necessary to report annually on emissions of pollutants emitted into the environment and pay certain environmental fees. Wastewater treatment plants can be significant sources of volatile organic compounds (VOCs) diffuse emissions, which are difficult to measure directly. Reporting obligations may also expand to benzene and other VOCs in the near future. This paper deals with gaseous emissions calculations from an API separator, based on emission factors and adequate software applications. The analyses results show that the estimated emission values are significantly different, depending on the applied method. VOC emissions have been estimated using US EPA and CONCAWE emissions factors. Calculated emissions range from 40 to 4500 tons/year for oil refinery WWTP of 2,000,000 m3/year. The calculations of benzene and toluene emissions have been performed using three methods: U.S. EPA emission factors, and WATER9 and Toxchem+ software. The calculated benzene and toluene emissions range from 5.5-60 and 0.7-20 tons/year, respectively. U.S. EPA emission factors give the highest values and Toxchem+ the lowest estimation values. Sensitivity analysis of obtained results included the following parameters: flow, temperature, oil content and the concentration of benzene and toluene in the effluent. The wide range of results indicates the need for their official interpretation for the conditions that are typical for Serbia if, in the future, the "polluter pays" principle should be applied to VOC and benzene emissions. The proposal is that adequate national emission factors should be established., Stupanjem na snagu novih zakonskih akata, industrijski zagađivači u Srbiji - budući nosioci integrisane dozvole, dužni su da na godišnjem nivou izveštavaju o emisijama štetnih gasova koji se ispuštaju u životnu sredinu i da u skladu sa time plaćaju određene ekološke naknade. Obaveza izveštavanja u skorijoj budućnosti može se proširiti na benzen i druge lako isparljive ugljovodonike. Predmet analize ovog rada su primena emisionih faktora i softverske simulacije za proračun gasovitih emisija iz postrojenja za tretman otpadnih voda. Rezultati pokazuju da se izračunate vrednosti emisija značajno razlikuju od metode do metode, a u diskusiji se posebna pažnja obraća na procenu pouzdanosti svake od njih.",
publisher = "Association of Chemical Engineers of Serbia",
journal = "Hemijska industrija",
title = "VOC emission from oil refinery and petrochemical wastewater treatment plant estimation, Procena emisija lakoisparljivih organskih jedinjenja iz postrojenja za primarni tretman otpadnih voda rafinerijskih i petrohemijskih postrojenja",
pages = "373-365",
number = "2",
volume = "67",
doi = "10.2298/HEMIND120427077S"
}
Mihajlović, M., Stevanović, D., Jovanović, J. M.,& Jovanović, M. B.. (2013). VOC emission from oil refinery and petrochemical wastewater treatment plant estimation. in Hemijska industrija
Association of Chemical Engineers of Serbia., 67(2), 365-373.
https://doi.org/10.2298/HEMIND120427077S
Mihajlović M, Stevanović D, Jovanović JM, Jovanović MB. VOC emission from oil refinery and petrochemical wastewater treatment plant estimation. in Hemijska industrija. 2013;67(2):365-373.
doi:10.2298/HEMIND120427077S .
Mihajlović, Marina, Stevanović, Dimitrije, Jovanović, Jovan M., Jovanović, Mića B., "VOC emission from oil refinery and petrochemical wastewater treatment plant estimation" in Hemijska industrija, 67, no. 2 (2013):365-373,
https://doi.org/10.2298/HEMIND120427077S . .

Estimation of evaporative losses during storage of crude oil and petroleum products

Mihajlović, Marina; Veljašević, Ana S.; Jovanović, Jovan M.; Jovanović, Mića B.

(Association of Chemical Engineers of Serbia, 2013)

TY  - JOUR
AU  - Mihajlović, Marina
AU  - Veljašević, Ana S.
AU  - Jovanović, Jovan M.
AU  - Jovanović, Mića B.
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2374
AB  - Storage of crude oil and petroleum products inevitably leads to evaporative losses. Those losses are important for the industrial plants mass balances, as well as for the environmental protection. In this paper, estimation of evaporative losses was performed using software program TANKS 409d which was developed by the Agency for Environmental Protection of the United States US EPA. Emissions were estimated for the following types of storage tanks: fixed conical roof tank, fixed dome roof tank, external floating roof tank, internal floating roof tank and domed external floating roof tank. Obtained results show quantities of evaporated losses per tone of stored liquid. Crude oil fixed roof storage tank losses are cca. 0.5 kg per tone of crude oil. For floating roof, crude oil losses are 0.001 kg/t. Fuel oil (diesel fuel and heating oil) have the smallest evaporation losses, which are in order of magnitude 10-3 kg/tone. Liquids with higher Reid Vapor Pressure have very high evaporative losses for tanks with fixed roof, up to 2.07 kg/tone. In case of external floating roof tank, losses are 0.32 kg/tone. The smallest losses are for internal floating roof tank and domed external floating roof tank: 0.072 and 0.044, respectively. Finally, it can be concluded that the liquid with low volatility of low BTEX amount can be stored in tanks with fixed roof. In this case, the prevailing economic aspect, because the total amount of evaporative loss does not significantly affect the environment. On the other hand, storage of volatile derivatives with high levels of BTEX is not justified from the economic point of view or from the standpoint of the environment protection.
AB  - Skladištenje nafte i naftnih derivata neizbežno dovodi do pojave evaporativnih gubitaka, koji su važni sa stanovišta odgovarajućeg bilansa i sa stanovišta zaštite životne sredine. U radu je izvršena kvantifikacija evaporativnih gubitaka za različite tipove komercijalnih rezervoara sa fiksnim i plivajućim krovovima korišćenjem softverskog programa TANKS 409d. Na osnovu rezultata procenjene su mase evaporativnih gubitaka po toni uskladištene tečnosti. Gubici sirove nafte za rezervaore sa fiksnim krovom iznose oko 0,5 kg/t sirove nafte, a za rezervoare sa plutajućim krovom oko 0,001 kg/t. Gubici dizela i mazuta su zanemarljivo mali, iznose do 10-3 kg/t. Najznačajniji gubici isparljivih tečnosti su u rezervoarima sa fiksnim krovom (do 2,07 kg/t), a najmanji gubici su kod rezervoara sa kupolastim krovom (oko 0,004 kg/t). Predmetni rezultati predstavljaju osnovu za analizu problema sa tehnoekonomskog stanovišta i sa stanovišta zaštite životne sredine, u funkciji projektovanja.
PB  - Association of Chemical Engineers of Serbia
T2  - Hemijska industrija
T1  - Estimation of evaporative losses during storage of crude oil and petroleum products
T1  - Kvantifikacija evaporativnih gubitaka nafte i naftnih derivata tokom skladištenja
EP  - 174
IS  - 1
SP  - 165
VL  - 67
DO  - 10.2298/HEMIND120301050S
ER  - 
@article{
author = "Mihajlović, Marina and Veljašević, Ana S. and Jovanović, Jovan M. and Jovanović, Mića B.",
year = "2013",
abstract = "Storage of crude oil and petroleum products inevitably leads to evaporative losses. Those losses are important for the industrial plants mass balances, as well as for the environmental protection. In this paper, estimation of evaporative losses was performed using software program TANKS 409d which was developed by the Agency for Environmental Protection of the United States US EPA. Emissions were estimated for the following types of storage tanks: fixed conical roof tank, fixed dome roof tank, external floating roof tank, internal floating roof tank and domed external floating roof tank. Obtained results show quantities of evaporated losses per tone of stored liquid. Crude oil fixed roof storage tank losses are cca. 0.5 kg per tone of crude oil. For floating roof, crude oil losses are 0.001 kg/t. Fuel oil (diesel fuel and heating oil) have the smallest evaporation losses, which are in order of magnitude 10-3 kg/tone. Liquids with higher Reid Vapor Pressure have very high evaporative losses for tanks with fixed roof, up to 2.07 kg/tone. In case of external floating roof tank, losses are 0.32 kg/tone. The smallest losses are for internal floating roof tank and domed external floating roof tank: 0.072 and 0.044, respectively. Finally, it can be concluded that the liquid with low volatility of low BTEX amount can be stored in tanks with fixed roof. In this case, the prevailing economic aspect, because the total amount of evaporative loss does not significantly affect the environment. On the other hand, storage of volatile derivatives with high levels of BTEX is not justified from the economic point of view or from the standpoint of the environment protection., Skladištenje nafte i naftnih derivata neizbežno dovodi do pojave evaporativnih gubitaka, koji su važni sa stanovišta odgovarajućeg bilansa i sa stanovišta zaštite životne sredine. U radu je izvršena kvantifikacija evaporativnih gubitaka za različite tipove komercijalnih rezervoara sa fiksnim i plivajućim krovovima korišćenjem softverskog programa TANKS 409d. Na osnovu rezultata procenjene su mase evaporativnih gubitaka po toni uskladištene tečnosti. Gubici sirove nafte za rezervaore sa fiksnim krovom iznose oko 0,5 kg/t sirove nafte, a za rezervoare sa plutajućim krovom oko 0,001 kg/t. Gubici dizela i mazuta su zanemarljivo mali, iznose do 10-3 kg/t. Najznačajniji gubici isparljivih tečnosti su u rezervoarima sa fiksnim krovom (do 2,07 kg/t), a najmanji gubici su kod rezervoara sa kupolastim krovom (oko 0,004 kg/t). Predmetni rezultati predstavljaju osnovu za analizu problema sa tehnoekonomskog stanovišta i sa stanovišta zaštite životne sredine, u funkciji projektovanja.",
publisher = "Association of Chemical Engineers of Serbia",
journal = "Hemijska industrija",
title = "Estimation of evaporative losses during storage of crude oil and petroleum products, Kvantifikacija evaporativnih gubitaka nafte i naftnih derivata tokom skladištenja",
pages = "174-165",
number = "1",
volume = "67",
doi = "10.2298/HEMIND120301050S"
}
Mihajlović, M., Veljašević, A. S., Jovanović, J. M.,& Jovanović, M. B.. (2013). Estimation of evaporative losses during storage of crude oil and petroleum products. in Hemijska industrija
Association of Chemical Engineers of Serbia., 67(1), 165-174.
https://doi.org/10.2298/HEMIND120301050S
Mihajlović M, Veljašević AS, Jovanović JM, Jovanović MB. Estimation of evaporative losses during storage of crude oil and petroleum products. in Hemijska industrija. 2013;67(1):165-174.
doi:10.2298/HEMIND120301050S .
Mihajlović, Marina, Veljašević, Ana S., Jovanović, Jovan M., Jovanović, Mića B., "Estimation of evaporative losses during storage of crude oil and petroleum products" in Hemijska industrija, 67, no. 1 (2013):165-174,
https://doi.org/10.2298/HEMIND120301050S . .
1
2

Cleaner production aspects of tablet coating process in pharmaceutical industry: problem of VOCs emission

Boltić, Zorana; Ružić, Nenad Lj.; Jovanović, Mica; Mihajlović, Marina; Jovanović, Jovan; Petrović, Slobodan

(Elsevier Sci Ltd, Oxford, 2013)

TY  - JOUR
AU  - Boltić, Zorana
AU  - Ružić, Nenad Lj.
AU  - Jovanović, Mica
AU  - Mihajlović, Marina
AU  - Jovanović, Jovan
AU  - Petrović, Slobodan
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2519
AB  - The aim of the article is to present a case study related to implementation of cleaner production (CP) process with the concept of minimizing emissions versus the end of pipe (EOP) approach within pharmaceutical industry. The idea is to move beyond simple pollution control by technology improvement and prevention of organic solvents emission into the atmosphere. Furthermore, cost-effectiveness of the suggested approach is evaluated compared to traditional concepts of polluted air treatment, ensuring both environmentally friendly and effective production of film coated tablets. Technological changes to improve the impact on the environment have been applied already in many industries as well as in pharmaceutical manufacturing. However, more effort is to be made in order to further decrease particularly VOCs emission into the atmosphere. An analysis is provided to stimulate a proactive approach in this field towards completely eliminating the use of organic solvents from film-coating systems in the production of the pharmaceutical solid dosage forms. The new way of addressing the costs actually associated with embracing cleaner technologies, which are mostly related to regulatory aspects in pharmaceutical industry, is aimed to promote the change in culture, as well as to be applied in the decision making process for other pharmaceutical facilities still using organic solvents based coatings in the manufacturing of tablets. The significance of the small scale projects is additionally emphasized considering the magnitude of the world generic market.
PB  - Elsevier Sci Ltd, Oxford
T2  - Journal of Cleaner Production
T1  - Cleaner production aspects of tablet coating process in pharmaceutical industry: problem of VOCs emission
EP  - 132
SP  - 123
VL  - 44
DO  - 10.1016/j.jclepro.2013.01.004
ER  - 
@article{
author = "Boltić, Zorana and Ružić, Nenad Lj. and Jovanović, Mica and Mihajlović, Marina and Jovanović, Jovan and Petrović, Slobodan",
year = "2013",
abstract = "The aim of the article is to present a case study related to implementation of cleaner production (CP) process with the concept of minimizing emissions versus the end of pipe (EOP) approach within pharmaceutical industry. The idea is to move beyond simple pollution control by technology improvement and prevention of organic solvents emission into the atmosphere. Furthermore, cost-effectiveness of the suggested approach is evaluated compared to traditional concepts of polluted air treatment, ensuring both environmentally friendly and effective production of film coated tablets. Technological changes to improve the impact on the environment have been applied already in many industries as well as in pharmaceutical manufacturing. However, more effort is to be made in order to further decrease particularly VOCs emission into the atmosphere. An analysis is provided to stimulate a proactive approach in this field towards completely eliminating the use of organic solvents from film-coating systems in the production of the pharmaceutical solid dosage forms. The new way of addressing the costs actually associated with embracing cleaner technologies, which are mostly related to regulatory aspects in pharmaceutical industry, is aimed to promote the change in culture, as well as to be applied in the decision making process for other pharmaceutical facilities still using organic solvents based coatings in the manufacturing of tablets. The significance of the small scale projects is additionally emphasized considering the magnitude of the world generic market.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Journal of Cleaner Production",
title = "Cleaner production aspects of tablet coating process in pharmaceutical industry: problem of VOCs emission",
pages = "132-123",
volume = "44",
doi = "10.1016/j.jclepro.2013.01.004"
}
Boltić, Z., Ružić, N. Lj., Jovanović, M., Mihajlović, M., Jovanović, J.,& Petrović, S.. (2013). Cleaner production aspects of tablet coating process in pharmaceutical industry: problem of VOCs emission. in Journal of Cleaner Production
Elsevier Sci Ltd, Oxford., 44, 123-132.
https://doi.org/10.1016/j.jclepro.2013.01.004
Boltić Z, Ružić NL, Jovanović M, Mihajlović M, Jovanović J, Petrović S. Cleaner production aspects of tablet coating process in pharmaceutical industry: problem of VOCs emission. in Journal of Cleaner Production. 2013;44:123-132.
doi:10.1016/j.jclepro.2013.01.004 .
Boltić, Zorana, Ružić, Nenad Lj., Jovanović, Mica, Mihajlović, Marina, Jovanović, Jovan, Petrović, Slobodan, "Cleaner production aspects of tablet coating process in pharmaceutical industry: problem of VOCs emission" in Journal of Cleaner Production, 44 (2013):123-132,
https://doi.org/10.1016/j.jclepro.2013.01.004 . .
34
26
40