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The effect of the electrode surface roughness at low level of coarseness on the polarization characteristics of electrochemical processes
(Pergamon-Elsevier Science Ltd, Oxford, 2010)
In this study, it is considered: (a) the effect of the exchange current density to the limiting diffusion current density ratio (J(0)/J(L)) at low level of surface coarseness on the polarization characteristics of the ...
Oxygen reduction on iron-IV. The reduction of hydrogen peroxide as the intermediate in oxygen reduction reaction in alkaline solutions
(Pergamon-Elsevier Science Ltd, Oxford, 1991)
The kinetics of hydrogen peroxide reduction were studied on iron in borate buffered and unbuffered solutions of pH ranging from 8.6 to 13.8, with and without the presence of chloride ions. A rotating disk electrode was ...
The origin of high activity of Pt-Au surfaces in the formic acid oxidation
(Pergamon-Elsevier Science Ltd, Oxford, 2009)
We have investigated the oxidation of HCOOH on Au-modified Pt (Au"Pt) and Pt-modified Au (Pt")/Au) electrodes to establish the role of the ensemble and the electronic effect in the catalysis of this reaction. The surfaces ...
Ti substrate coated with composite Cr–MoO2 coatings as highly selective cathode materials in hypochlorite production
(Elsevier, 2013)
The aim of this work was to investigate the possibility of preparation of the composite Cr–MoO2 coatings onto steel and titanium substrates as cathode materials with high selective properties which imply the suppression ...
Pt supported on nano-tungsten carbide as a beneficial catalyst for the oxygen reduction reaction in alkaline solution
(Elsevier, 2012)
Platinum nanocatalyst at nano-tungsten carbide was synthesized, characterized and tested for oxygen reduction reaction (ORR) in 0.1 mol dm−3 NaOH, at 25 °C. Tungsten-carbide islands on nano-tungsten particles (WC) was ...
Corrosion protection of mild steel by polypyrrole coatings in acid sulfate solutions
(Pergamon-Elsevier Science Ltd, Oxford, 1997)
The corrosion behaviour of mild steel covered by the electrodeposited polypyrrole films was investigated by electrochemical impedance spectroscopy. Electrodeposition of polypyrrole was performed from aqueous solution of ...
Hydrogen evolution at Zn-Ni alloys
(Pergamon-Elsevier Science Ltd, Oxford, 1998)
Zn-Ni alloys were electrodeposited from a berate-citrate and TEPA bath in potentiostatic and galvanostatic regimes. Potential of electrodeposition or current density were varied and chemical composition and phase structure ...
Study of the kinetics and the influence of Bi-irr, on formic acid oxidation at Pt2RU3/C
(Pergamon-Elsevier Science Ltd, Oxford, 2007)
Electrochemical oxidation of HCOOH in H2SO4 and HCIO4 solutions was examined on thin film Pt2RU3/C electrode. XRD pattern revealed that Pt2RU3 alloy consisted of the solid solution of Ru in Pt and the small amount of Ru ...
Comparative studies of chloride and chloride/citrate based electrolytes for zinc-polyaniline batteries
(Pergamon-Elsevier Science Ltd, Oxford, 2006)
Electrochemical behavior of zinc and thin polyaniline (PANI) polymerized from 0.1 M HCl to 0.1 M aniline on graphite electrode, in 0.2 M ZnCl(2) and 0.50 M NH(4)Cl (chloride electrolyte) and with addition of 0.33 M Na-citrate ...
Electrooxidation of H-2, CO and H-2/CO mixtures on a well-characterized Pt-Re bulk alloy electrode and comparison with other Pt binary alloys
(Pergamon-Elsevier Science Ltd, Oxford, 1998)
We report new results for the electrooxidation of Hz, CO and H-2/CO mixtures on a Pt75Re25 bulk alloy using surface preparation in a UHV chamber and characterization by X-ray photoelectron spectroscopy (XPS). Sputter-cleaned ...