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The alcoholysis of 1,2,2-trimethylpropyl-methylfluorophosphonate
Alkoholiza 1,2,2-trimetilpropil-metilfluorofosfata
dc.creator | Mićević, Mlađen L. | |
dc.creator | Petrović, Slobodan | |
dc.date.accessioned | 2021-03-10T09:54:27Z | |
dc.date.available | 2021-03-10T09:54:27Z | |
dc.date.issued | 2000 | |
dc.identifier.issn | 0352-5139 | |
dc.identifier.uri | http://TechnoRep.tmf.bg.ac.rs/handle/123456789/337 | |
dc.description.abstract | The alcoholysis of 1,2,2-trimethylpropyl-methylfluorophosphonate (soman) was examined with a series of alkoxides and in corresponding alcohols: methanol, ethanol, 1-propanol, 2-propanol, 2-methoxyethanol and 2-ethoxyethanol. Soman reacts with the used alkoxides in a second order reaction, first order in each reactant. The kinetics of the reaction between 1,2,2-trimethylpropyl-methylfluorophosphonate and ethanol in the presence of diethylenetriamine was also examined. A third order reaction rate constant was calculated, first order in each reactant. The activation energy, frequency factor and activation entropy were determined on the basis of the kinetic data. . | en |
dc.description.abstract | Ispitana je alkoholiza 1,2,2-trimetilpropil-metilfluorofosfonata (soman) sa nizom alkoksida u odgovarajućim alkoholima: metanol, etanol, 1-propanol, 2-propanol, 2-metoksietanol i 2-etoksietanol. Soman reaguje sa ispitivanim alkoksidima u reakciji drugog reda, prvog reda prema svakom reaktantu. Ispitana je i kinetika reakcije između 1,2,2-trimetilpropil-metilfluorofosfonata i dietilentriamina u etanolu. Reakcija je ukupno trećeg reda, prvog prema svakom reaktantu. Za ispitivane reakcije su izračunate: energije aktivacije, faktori frekvencije i entropije aktivacije. . | sr |
dc.publisher | Serbian Chemical Society, Belgrade | |
dc.rights | openAccess | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.source | Journal of the Serbian Chemical Society | |
dc.subject | decontamination | en |
dc.subject | alcoholysis | en |
dc.subject | 1,2,2-trimethylpropyl-methylfluorophosphonate | en |
dc.subject | soman | en |
dc.subject | alkoxides and diethylenetriamine | en |
dc.title | The alcoholysis of 1,2,2-trimethylpropyl-methylfluorophosphonate | en |
dc.title | Alkoholiza 1,2,2-trimetilpropil-metilfluorofosfata | sr |
dc.type | article | |
dc.rights.license | BY-NC-ND | |
dc.citation.epage | 866 | |
dc.citation.issue | 12 | |
dc.citation.other | 65(12): 857-866 | |
dc.citation.rank | M23 | |
dc.citation.spage | 857 | |
dc.citation.volume | 65 | |
dc.identifier.fulltext | http://TechnoRep.tmf.bg.ac.rs/bitstream/id/11451/0352-51390012857M.pdf | |
dc.identifier.rcub | https://hdl.handle.net/21.15107/rcub_technorep_337 | |
dc.identifier.scopus | 2-s2.0-0034562153 | |
dc.identifier.wos | 000166372700003 | |
dc.type.version | publishedVersion |