TY  - JOUR
AU  - Borović, Teona Teodora
AU  - Panić, Jovana
AU  - Radović, Ivona
AU  - Grozdanić, Nikola
AU  - Vraneš, Milan
PY  - 2024-03
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7188
AB  - In this study, a detailed physicochemical characterization of caffeine in 0.1 mol∙kg−1 of 1-butyl-3-methylimidazolium salicylate (abbreviation [Bmim][Sal]) aqueous solutions is performed based on density, speed of sound, refractive index and viscosity measurements in the temperature range from T = (293.15–313.15) K. [Bmim][Sal] slightly increases the solubility of caffeine in water. Data obtained from the volumetric and viscosimetric measurements indicate that [Bmim][Sal] promotes the self-aggregation of caffeine in water. Molecular dynamic simulations provided insight into how [Bmim][Sal] increases caffeine solubility in water. At higher temperatures, the salicylate anion has stronger interactions with caffeine through π–π interactions than at lower temperatures.
PB  - Elsevier B.V.
T2  - Journal of Molecular Liquids
T1  - Interactions of caffeine and 1-butyl-3-methylimidazolium salicylate ionic liquid in water – Solubility, volumetric, acoustic, viscometric and refractometric studies supported by MD simulation
SP  - 124058
VL  - 397
DO  - 10.1016/j.molliq.2024.124058
ER  - 

@article{
author = "Borović, Teona Teodora and Panić, Jovana and Radović, Ivona and Grozdanić, Nikola and Vraneš, Milan",
year = "2024-03",
abstract = "In this study, a detailed physicochemical characterization of caffeine in 0.1 mol∙kg−1 of 1-butyl-3-methylimidazolium salicylate (abbreviation [Bmim][Sal]) aqueous solutions is performed based on density, speed of sound, refractive index and viscosity measurements in the temperature range from T = (293.15–313.15) K. [Bmim][Sal] slightly increases the solubility of caffeine in water. Data obtained from the volumetric and viscosimetric measurements indicate that [Bmim][Sal] promotes the self-aggregation of caffeine in water. Molecular dynamic simulations provided insight into how [Bmim][Sal] increases caffeine solubility in water. At higher temperatures, the salicylate anion has stronger interactions with caffeine through π–π interactions than at lower temperatures.",
publisher = "Elsevier B.V.",
journal = "Journal of Molecular Liquids",
title = "Interactions of caffeine and 1-butyl-3-methylimidazolium salicylate ionic liquid in water – Solubility, volumetric, acoustic, viscometric and refractometric studies supported by MD simulation",
pages = "124058",
volume = "397",
doi = "10.1016/j.molliq.2024.124058"
}

Borović, T. T., Panić, J., Radović, I., Grozdanić, N.,& Vraneš, M.. (2024-03). Interactions of caffeine and 1-butyl-3-methylimidazolium salicylate ionic liquid in water – Solubility, volumetric, acoustic, viscometric and refractometric studies supported by MD simulation. in Journal of Molecular Liquids
Elsevier B.V.., 397, 124058.
https://doi.org/10.1016/j.molliq.2024.124058

Borović TT, Panić J, Radović I, Grozdanić N, Vraneš M. Interactions of caffeine and 1-butyl-3-methylimidazolium salicylate ionic liquid in water – Solubility, volumetric, acoustic, viscometric and refractometric studies supported by MD simulation. in Journal of Molecular Liquids. 2024;397:124058.
doi:10.1016/j.molliq.2024.124058 .

Borović, Teona Teodora, Panić, Jovana, Radović, Ivona, Grozdanić, Nikola, Vraneš, Milan, "Interactions of caffeine and 1-butyl-3-methylimidazolium salicylate ionic liquid in water – Solubility, volumetric, acoustic, viscometric and refractometric studies supported by MD simulation" in Journal of Molecular Liquids, 397 (2024-03):124058,
https://doi.org/10.1016/j.molliq.2024.124058 . .

TY  - JOUR
AU  - Grozdanić, Nikola
AU  - Simić, Zoran
AU  - Kijevčanin, Mirjana
AU  - Radović, Ivona
PY  - 2024
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7150
AB  - Terpenes usually found in plants have a wide range of applications, especially as additives in various types of fuels, and most recently in the aviation industry, where they can be blended with jet fuels or kerosene. In this work, the densities of pure terpenes (1R)-(+)-α-pinene, (1S)-(−)-β-pinene, and linalool were measured over the temperature range T = (293.15 to 413.15) K and at high pressures p = (0.1 to 60) MPa. The experimental density data were fitted by the modified Tammann-Tait equation where the absolute average percentage deviation between measured and calculated densities was less than 0.02%, the percentage maximum deviation was less than 0.2%, and the average percentage deviation was less than 0.02% for all three measured terpenes. The obtained parameters were used to determine isothermal compressibility (κT), isobaric thermal expansivity (αp), internal pressure (pint), and the difference between specific heat capacity at constant pressure (cp) and constant volume (cv). Furthermore, the PC-SAFT model was applied for liquid density prediction at high pressures. Derived thermodynamic properties such as isothermal compressibility and isobaric thermal expansivity increase as temperature increases and decrease with pressure for all of the studied compounds.
PB  - American Chemical Society
T2  - Journal of Chemical and Engineering Data
T1  - High Pressure Densities and Derived Thermodynamic Properties of Pure (1R)-(+)-α-Pinene, (1S)-(−)-β-Pinene, and Linalool: Experiment and Modeling
EP  - 863
IS  - 3
SP  - 854
VL  - 69
DO  - 10.1021/acs.jced.3c00582
ER  - 

@article{
author = "Grozdanić, Nikola and Simić, Zoran and Kijevčanin, Mirjana and Radović, Ivona",
year = "2024",
abstract = "Terpenes usually found in plants have a wide range of applications, especially as additives in various types of fuels, and most recently in the aviation industry, where they can be blended with jet fuels or kerosene. In this work, the densities of pure terpenes (1R)-(+)-α-pinene, (1S)-(−)-β-pinene, and linalool were measured over the temperature range T = (293.15 to 413.15) K and at high pressures p = (0.1 to 60) MPa. The experimental density data were fitted by the modified Tammann-Tait equation where the absolute average percentage deviation between measured and calculated densities was less than 0.02%, the percentage maximum deviation was less than 0.2%, and the average percentage deviation was less than 0.02% for all three measured terpenes. The obtained parameters were used to determine isothermal compressibility (κT), isobaric thermal expansivity (αp), internal pressure (pint), and the difference between specific heat capacity at constant pressure (cp) and constant volume (cv). Furthermore, the PC-SAFT model was applied for liquid density prediction at high pressures. Derived thermodynamic properties such as isothermal compressibility and isobaric thermal expansivity increase as temperature increases and decrease with pressure for all of the studied compounds.",
publisher = "American Chemical Society",
journal = "Journal of Chemical and Engineering Data",
title = "High Pressure Densities and Derived Thermodynamic Properties of Pure (1R)-(+)-α-Pinene, (1S)-(−)-β-Pinene, and Linalool: Experiment and Modeling",
pages = "863-854",
number = "3",
volume = "69",
doi = "10.1021/acs.jced.3c00582"
}

Grozdanić, N., Simić, Z., Kijevčanin, M.,& Radović, I.. (2024). High Pressure Densities and Derived Thermodynamic Properties of Pure (1R)-(+)-α-Pinene, (1S)-(−)-β-Pinene, and Linalool: Experiment and Modeling. in Journal of Chemical and Engineering Data
American Chemical Society., 69(3), 854-863.
https://doi.org/10.1021/acs.jced.3c00582

Grozdanić N, Simić Z, Kijevčanin M, Radović I. High Pressure Densities and Derived Thermodynamic Properties of Pure (1R)-(+)-α-Pinene, (1S)-(−)-β-Pinene, and Linalool: Experiment and Modeling. in Journal of Chemical and Engineering Data. 2024;69(3):854-863.
doi:10.1021/acs.jced.3c00582 .

Grozdanić, Nikola, Simić, Zoran, Kijevčanin, Mirjana, Radović, Ivona, "High Pressure Densities and Derived Thermodynamic Properties of Pure (1R)-(+)-α-Pinene, (1S)-(−)-β-Pinene, and Linalool: Experiment and Modeling" in Journal of Chemical and Engineering Data, 69, no. 3 (2024):854-863,
https://doi.org/10.1021/acs.jced.3c00582 . .

TY  - JOUR
AU  - Simić, Zoran V.
AU  - Radović, Ivona R.
AU  - Kijevčanin, Mirjana Lj.
PY  - 2024
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7342
AB  - This paper investigates the feasibility of using diethyl adipate (DEA), a green organic solvent, as a separation agent for extracting various alcohols from aqueous solutions. In order to achieve this, liquid-liquid equilibria (LLE) experiments were carried out for four ternary systems: {water + methanol + DEA}, {water + ethanol + DEA}, {water + 1-propanol + DEA}, and {water + 2-propanol + DEA} at 298.15 K and atmospheric pressure. LLE experiments involve determination of certain thermodynamic data such as binodal curves and cloud-point data. Binodal curve data were determined by the cloud-point method using the titration technique, while the tie-line data were determined by optimizing the parameters based on the experimental measurements of the refractive index. Additionally, the distribution coefficients and the separation factors were calculated within the immiscibility region. Hand and Othmer-Tobias correlations were used to examine the reliability of the tie-line data. Also, the experimental ternary LLE data were correlated using the UNIversal QUAsiChemical (UNIQUAC) activity coefficient models. The results confirm that that DEA is a suitable choice for extracting methanol, ethanol, 1-propanol, and 2-propanol from water. The potential of DEA as a separation agent followed the sequence methanol < ethanol < 2-propanol < 1-propanol. UNIQUAC model proved to be effective in correlating the LLE data.
PB  - American Chemical Society
T2  - Journal of Chemical and Engineering Data
T1  - Measurement and Correlation of Liquid–Liquid Equilibrium Data for Ternary Systems Water + C1–C3 Alcohols + Diethyl Adipate at 298.15 K and Atmospheric Pressure
DO  - 10.1021/acs.jced.3c00708
ER  - 

@article{
author = "Simić, Zoran V. and Radović, Ivona R. and Kijevčanin, Mirjana Lj.",
year = "2024",
abstract = "This paper investigates the feasibility of using diethyl adipate (DEA), a green organic solvent, as a separation agent for extracting various alcohols from aqueous solutions. In order to achieve this, liquid-liquid equilibria (LLE) experiments were carried out for four ternary systems: {water + methanol + DEA}, {water + ethanol + DEA}, {water + 1-propanol + DEA}, and {water + 2-propanol + DEA} at 298.15 K and atmospheric pressure. LLE experiments involve determination of certain thermodynamic data such as binodal curves and cloud-point data. Binodal curve data were determined by the cloud-point method using the titration technique, while the tie-line data were determined by optimizing the parameters based on the experimental measurements of the refractive index. Additionally, the distribution coefficients and the separation factors were calculated within the immiscibility region. Hand and Othmer-Tobias correlations were used to examine the reliability of the tie-line data. Also, the experimental ternary LLE data were correlated using the UNIversal QUAsiChemical (UNIQUAC) activity coefficient models. The results confirm that that DEA is a suitable choice for extracting methanol, ethanol, 1-propanol, and 2-propanol from water. The potential of DEA as a separation agent followed the sequence methanol < ethanol < 2-propanol < 1-propanol. UNIQUAC model proved to be effective in correlating the LLE data.",
publisher = "American Chemical Society",
journal = "Journal of Chemical and Engineering Data",
title = "Measurement and Correlation of Liquid–Liquid Equilibrium Data for Ternary Systems Water + C1–C3 Alcohols + Diethyl Adipate at 298.15 K and Atmospheric Pressure",
doi = "10.1021/acs.jced.3c00708"
}

Simić, Z. V., Radović, I. R.,& Kijevčanin, M. Lj.. (2024). Measurement and Correlation of Liquid–Liquid Equilibrium Data for Ternary Systems Water + C1–C3 Alcohols + Diethyl Adipate at 298.15 K and Atmospheric Pressure. in Journal of Chemical and Engineering Data
American Chemical Society..
https://doi.org/10.1021/acs.jced.3c00708

Simić ZV, Radović IR, Kijevčanin ML. Measurement and Correlation of Liquid–Liquid Equilibrium Data for Ternary Systems Water + C1–C3 Alcohols + Diethyl Adipate at 298.15 K and Atmospheric Pressure. in Journal of Chemical and Engineering Data. 2024;.
doi:10.1021/acs.jced.3c00708 .

Simić, Zoran V., Radović, Ivona R., Kijevčanin, Mirjana Lj., "Measurement and Correlation of Liquid–Liquid Equilibrium Data for Ternary Systems Water + C1–C3 Alcohols + Diethyl Adipate at 298.15 K and Atmospheric Pressure" in Journal of Chemical and Engineering Data (2024),
https://doi.org/10.1021/acs.jced.3c00708 . .

TY  - DATA
AU  - Simić, Zoran V.
AU  - Radović, Ivona R.
AU  - Kijevčanin, Mirjana Lj.
PY  - 2024
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7343
AB  - This paper investigates the feasibility of using diethyl adipate (DEA), a green organic solvent, as a separation agent for extracting various alcohols from aqueous solutions. In order to achieve this, liquid-liquid equilibria (LLE) experiments were carried out for four ternary systems: {water + methanol + DEA}, {water + ethanol + DEA}, {water + 1-propanol + DEA}, and {water + 2-propanol + DEA} at 298.15 K and atmospheric pressure. LLE experiments involve determination of certain thermodynamic data such as binodal curves and cloud-point data. Binodal curve data were determined by the cloud-point method using the titration technique, while the tie-line data were determined by optimizing the parameters based on the experimental measurements of the refractive index. Additionally, the distribution coefficients and the separation factors were calculated within the immiscibility region. Hand and Othmer-Tobias correlations were used to examine the reliability of the tie-line data. Also, the experimental ternary LLE data were correlated using the UNIversal QUAsiChemical (UNIQUAC) activity coefficient models. The results confirm that that DEA is a suitable choice for extracting methanol, ethanol, 1-propanol, and 2-propanol from water. The potential of DEA as a separation agent followed the sequence methanol < ethanol < 2-propanol < 1-propanol. UNIQUAC model proved to be effective in correlating the LLE data.
PB  - American Chemical Society
T2  - Journal of Chemical and Engineering Data
T1  - Supplementary material for the article: Simić, Z. V.; Radović, I. R.; Kijevčanin, M. Lj. Measurement and Correlation of Liquid–Liquid Equilibrium Data for Ternary Systems Water + C1–C3 Alcohols + Diethyl Adipate at 298.15 K and Atmospheric Pressure. Journal of Chemical and Engineering Data 2024. https://doi.org/10.1021/acs.jced.3c00708
UR  - https://hdl.handle.net/21.15107/rcub_technorep_7343
ER  - 

@misc{
author = "Simić, Zoran V. and Radović, Ivona R. and Kijevčanin, Mirjana Lj.",
year = "2024",
abstract = "This paper investigates the feasibility of using diethyl adipate (DEA), a green organic solvent, as a separation agent for extracting various alcohols from aqueous solutions. In order to achieve this, liquid-liquid equilibria (LLE) experiments were carried out for four ternary systems: {water + methanol + DEA}, {water + ethanol + DEA}, {water + 1-propanol + DEA}, and {water + 2-propanol + DEA} at 298.15 K and atmospheric pressure. LLE experiments involve determination of certain thermodynamic data such as binodal curves and cloud-point data. Binodal curve data were determined by the cloud-point method using the titration technique, while the tie-line data were determined by optimizing the parameters based on the experimental measurements of the refractive index. Additionally, the distribution coefficients and the separation factors were calculated within the immiscibility region. Hand and Othmer-Tobias correlations were used to examine the reliability of the tie-line data. Also, the experimental ternary LLE data were correlated using the UNIversal QUAsiChemical (UNIQUAC) activity coefficient models. The results confirm that that DEA is a suitable choice for extracting methanol, ethanol, 1-propanol, and 2-propanol from water. The potential of DEA as a separation agent followed the sequence methanol < ethanol < 2-propanol < 1-propanol. UNIQUAC model proved to be effective in correlating the LLE data.",
publisher = "American Chemical Society",
journal = "Journal of Chemical and Engineering Data",
title = "Supplementary material for the article: Simić, Z. V.; Radović, I. R.; Kijevčanin, M. Lj. Measurement and Correlation of Liquid–Liquid Equilibrium Data for Ternary Systems Water + C1–C3 Alcohols + Diethyl Adipate at 298.15 K and Atmospheric Pressure. Journal of Chemical and Engineering Data 2024. https://doi.org/10.1021/acs.jced.3c00708",
url = "https://hdl.handle.net/21.15107/rcub_technorep_7343"
}

Simić, Z. V., Radović, I. R.,& Kijevčanin, M. Lj.. (2024). Supplementary material for the article: Simić, Z. V.; Radović, I. R.; Kijevčanin, M. Lj. Measurement and Correlation of Liquid–Liquid Equilibrium Data for Ternary Systems Water + C1–C3 Alcohols + Diethyl Adipate at 298.15 K and Atmospheric Pressure. Journal of Chemical and Engineering Data 2024. https://doi.org/10.1021/acs.jced.3c00708. in Journal of Chemical and Engineering Data
American Chemical Society..
https://hdl.handle.net/21.15107/rcub_technorep_7343

Simić ZV, Radović IR, Kijevčanin ML. Supplementary material for the article: Simić, Z. V.; Radović, I. R.; Kijevčanin, M. Lj. Measurement and Correlation of Liquid–Liquid Equilibrium Data for Ternary Systems Water + C1–C3 Alcohols + Diethyl Adipate at 298.15 K and Atmospheric Pressure. Journal of Chemical and Engineering Data 2024. https://doi.org/10.1021/acs.jced.3c00708. in Journal of Chemical and Engineering Data. 2024;.
https://hdl.handle.net/21.15107/rcub_technorep_7343 .

Simić, Zoran V., Radović, Ivona R., Kijevčanin, Mirjana Lj., "Supplementary material for the article: Simić, Z. V.; Radović, I. R.; Kijevčanin, M. Lj. Measurement and Correlation of Liquid–Liquid Equilibrium Data for Ternary Systems Water + C1–C3 Alcohols + Diethyl Adipate at 298.15 K and Atmospheric Pressure. Journal of Chemical and Engineering Data 2024. https://doi.org/10.1021/acs.jced.3c00708" in Journal of Chemical and Engineering Data (2024),
https://hdl.handle.net/21.15107/rcub_technorep_7343 .

TY  - CONF
AU  - Ivaniš, Gorica R.
AU  - Simić, Zoran V.
AU  - Miškov Panić, Sofija P.
AU  - Kijevčanin, Mirjana Lj.
AU  - Radović, Ivona R.
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7396
AB  - The uncontrolled and excessive use of fossil fuels is one of the main culprits for global warming due to the emission of greenhouse gases. Therefore, intensive work has been done to reduce the use of such fuels by replacing/adding biodiesel in transport sector since the use of biodiesel decreases the net emission of greenhouse gases by about 76 % than when using petroleum diesel (Ivaniš et al., 2016). On the other hand, the modern consumer lifestyle has led to the accumulation of large amounts of waste that additionally pollutes the soil and water, which indicates the necessity of a global transition from a linear to a circular economy where waste represents raw material. The disposal of used cooking oil is a huge problem because it is usually poured down drains, which leads to clogging of kitchen pipes and local sewage. Consequently, waste cooking oil drastically reduces the efficiency of wastewater treatment plants and is extremely harmful to the aquatic ecosystem. The reuse of used cooking oil in food is not recommended so other forms of recycling such as biodiesel production are preferred. Biodiesel is obtained by the transesterification reaction of vegetable oils with short-chain alcohol in the presence of a catalyst, and glycerine is produced as a side product. By applying heterogeneously catalysed transesterification reaction, such as the use of CaO as catalyst, the generation of waste during the purification of products is avoided. Eggshells are solid organic waste that is generally discarded without prior treatment, making it a hazardous waste. It is considered that the eggshell mainly (about 96 %) consists of CaCO₃, which offers the possibility of its revalorisation through CaO production (Waheed et al., 2020). As part of our research, waste hen’s eggshell was collected and annealed at 830 ̊C producing CaO, which was used as a catalyst in the biodiesel synthesis from used cooking oil. The thermodynamic and transport properties of the obtained biodiesel and crude glycerine were determined at wide ranges of temperature and pressure, which is relevant for their further use [1]. The measured properties of the obtained biodiesel meet the limits prescribed by the standard for biodiesel EN14214 which confirms that it can be used in diesel engines and heating applications. The obtained raw glycerine can be mixed with biomass residues and used in the production of pellets. In this way, the problem of accumulation of waste in the form of eggshells, used cooking oil and crude glycerine is solved and their revalorisation is carried out, which is fully in accordance with the postulates of the circular economy. Furthermore, biodiesel, as an environmentally friendly alternative to petroleum diesel, was obtained.
PB  - Ca'Foscari University of Venice
C3  - Book of abstracts / 18th International Conference on Chemistry and the Environment – ICCE 2023, June 11-15, 2023, Venice, Italy
T1  - Waste to Energy: Food Waste Valorisation toward Biofuel Production
SP  - 315
UR  - https://hdl.handle.net/21.15107/rcub_technorep_7396
ER  - 

@conference{
author = "Ivaniš, Gorica R. and Simić, Zoran V. and Miškov Panić, Sofija P. and Kijevčanin, Mirjana Lj. and Radović, Ivona R.",
year = "2023",
abstract = "The uncontrolled and excessive use of fossil fuels is one of the main culprits for global warming due to the emission of greenhouse gases. Therefore, intensive work has been done to reduce the use of such fuels by replacing/adding biodiesel in transport sector since the use of biodiesel decreases the net emission of greenhouse gases by about 76 % than when using petroleum diesel (Ivaniš et al., 2016). On the other hand, the modern consumer lifestyle has led to the accumulation of large amounts of waste that additionally pollutes the soil and water, which indicates the necessity of a global transition from a linear to a circular economy where waste represents raw material. The disposal of used cooking oil is a huge problem because it is usually poured down drains, which leads to clogging of kitchen pipes and local sewage. Consequently, waste cooking oil drastically reduces the efficiency of wastewater treatment plants and is extremely harmful to the aquatic ecosystem. The reuse of used cooking oil in food is not recommended so other forms of recycling such as biodiesel production are preferred. Biodiesel is obtained by the transesterification reaction of vegetable oils with short-chain alcohol in the presence of a catalyst, and glycerine is produced as a side product. By applying heterogeneously catalysed transesterification reaction, such as the use of CaO as catalyst, the generation of waste during the purification of products is avoided. Eggshells are solid organic waste that is generally discarded without prior treatment, making it a hazardous waste. It is considered that the eggshell mainly (about 96 %) consists of CaCO₃, which offers the possibility of its revalorisation through CaO production (Waheed et al., 2020). As part of our research, waste hen’s eggshell was collected and annealed at 830 ̊C producing CaO, which was used as a catalyst in the biodiesel synthesis from used cooking oil. The thermodynamic and transport properties of the obtained biodiesel and crude glycerine were determined at wide ranges of temperature and pressure, which is relevant for their further use [1]. The measured properties of the obtained biodiesel meet the limits prescribed by the standard for biodiesel EN14214 which confirms that it can be used in diesel engines and heating applications. The obtained raw glycerine can be mixed with biomass residues and used in the production of pellets. In this way, the problem of accumulation of waste in the form of eggshells, used cooking oil and crude glycerine is solved and their revalorisation is carried out, which is fully in accordance with the postulates of the circular economy. Furthermore, biodiesel, as an environmentally friendly alternative to petroleum diesel, was obtained.",
publisher = "Ca'Foscari University of Venice",
journal = "Book of abstracts / 18th International Conference on Chemistry and the Environment – ICCE 2023, June 11-15, 2023, Venice, Italy",
title = "Waste to Energy: Food Waste Valorisation toward Biofuel Production",
pages = "315",
url = "https://hdl.handle.net/21.15107/rcub_technorep_7396"
}

Ivaniš, G. R., Simić, Z. V., Miškov Panić, S. P., Kijevčanin, M. Lj.,& Radović, I. R.. (2023). Waste to Energy: Food Waste Valorisation toward Biofuel Production. in Book of abstracts / 18th International Conference on Chemistry and the Environment – ICCE 2023, June 11-15, 2023, Venice, Italy
Ca'Foscari University of Venice., 315.
https://hdl.handle.net/21.15107/rcub_technorep_7396

Ivaniš GR, Simić ZV, Miškov Panić SP, Kijevčanin ML, Radović IR. Waste to Energy: Food Waste Valorisation toward Biofuel Production. in Book of abstracts / 18th International Conference on Chemistry and the Environment – ICCE 2023, June 11-15, 2023, Venice, Italy. 2023;:315.
https://hdl.handle.net/21.15107/rcub_technorep_7396 .

Ivaniš, Gorica R., Simić, Zoran V., Miškov Panić, Sofija P., Kijevčanin, Mirjana Lj., Radović, Ivona R., "Waste to Energy: Food Waste Valorisation toward Biofuel Production" in Book of abstracts / 18th International Conference on Chemistry and the Environment – ICCE 2023, June 11-15, 2023, Venice, Italy (2023):315,
https://hdl.handle.net/21.15107/rcub_technorep_7396 .

TY  - CONF
AU  - Simić, Zoran V.
AU  - Ivaniš, Gorica R.
AU  - Miškov Panić, Sofija P.
AU  - Kijevčanin, Mirjana Lj.
AU  - Radović, Ivona R.
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7395
AB  - The negative impact of the use of fossil fuels on the environment has led to an increase in research in the field of renewable energy sources and intensified the production of biodiesel. The latter has caused the accumulation of a large amount of waste glycerol, since about 1 kg of crude glycerol is obtained for 10 kg of biodiesel. Crude glycerol is traditionally considered a low-value waste because of impurities and variable composition and its disposal was limited due to the harmful effects on the environment. To reuse this by-product of the transesterification reaction, in most cases it needs to be refined. However, crude glycerol purification requires additional costs while at the same time the glycerol market is already saturated and, consequently, the price of crude glycerol continues to decline. To avoid the accumulation of waste glycerol and pollution of the environment, it is necessary to find some applications for the raw glycerol obtained from the industrial production of biodiesel (Groesbeck et al., 2008).
Crude glycerol can be integrated with waste biomass, such as agricultural waste and wood residues, to improve its properties as a fuel. During the production of pellets, raw glycerol serves as a binder, which increases the yield and durability of pellets during storage and transportation. Additionally, it serves as a lubricant reducing the energy required for palletisation. It has been shown that when burning pellets with additional raw glycerol, a significantly lower amount of NOx is released than in the case of classic wood pellets (Zhang et al., 2022).
In this study, we investigated the possibility of adding waste crude glycerol to waste agro-industrial biomass in the production of enriched pellets. By applying the basic principles of the circular economy, the glycerol used for the purposes of this research was obtained from the transesterification reaction between used edible oil and short-chain alcohol, with the presence of a catalyst obtained from the waste shell of chicken egg. The characterization of the mixtures of different agricultural biomass and agro-industrial waste with different mass fraction of crude glycerol was performed. Standard analyses for determining the quality of pellets (such as calorific value, ash content, etc.) were performed to examine the possibility of using the enriched pellets obtained in this way in existing boilers designed for the use of commercial pellets.
PB  - Ca'Foscari University of Venice
C3  - Book of abstracts / 18th International Conference on Chemistry and the Environment – ICCE 2023, June 11-15, 2023, Venice, Italy
T1  - Waste to Energy: Agro-industrial Waste Valorisation Toward Enriched Pellet Production
SP  - 327
UR  - https://hdl.handle.net/21.15107/rcub_technorep_7395
ER  - 

@conference{
author = "Simić, Zoran V. and Ivaniš, Gorica R. and Miškov Panić, Sofija P. and Kijevčanin, Mirjana Lj. and Radović, Ivona R.",
year = "2023",
abstract = "The negative impact of the use of fossil fuels on the environment has led to an increase in research in the field of renewable energy sources and intensified the production of biodiesel. The latter has caused the accumulation of a large amount of waste glycerol, since about 1 kg of crude glycerol is obtained for 10 kg of biodiesel. Crude glycerol is traditionally considered a low-value waste because of impurities and variable composition and its disposal was limited due to the harmful effects on the environment. To reuse this by-product of the transesterification reaction, in most cases it needs to be refined. However, crude glycerol purification requires additional costs while at the same time the glycerol market is already saturated and, consequently, the price of crude glycerol continues to decline. To avoid the accumulation of waste glycerol and pollution of the environment, it is necessary to find some applications for the raw glycerol obtained from the industrial production of biodiesel (Groesbeck et al., 2008).
Crude glycerol can be integrated with waste biomass, such as agricultural waste and wood residues, to improve its properties as a fuel. During the production of pellets, raw glycerol serves as a binder, which increases the yield and durability of pellets during storage and transportation. Additionally, it serves as a lubricant reducing the energy required for palletisation. It has been shown that when burning pellets with additional raw glycerol, a significantly lower amount of NOx is released than in the case of classic wood pellets (Zhang et al., 2022).
In this study, we investigated the possibility of adding waste crude glycerol to waste agro-industrial biomass in the production of enriched pellets. By applying the basic principles of the circular economy, the glycerol used for the purposes of this research was obtained from the transesterification reaction between used edible oil and short-chain alcohol, with the presence of a catalyst obtained from the waste shell of chicken egg. The characterization of the mixtures of different agricultural biomass and agro-industrial waste with different mass fraction of crude glycerol was performed. Standard analyses for determining the quality of pellets (such as calorific value, ash content, etc.) were performed to examine the possibility of using the enriched pellets obtained in this way in existing boilers designed for the use of commercial pellets.",
publisher = "Ca'Foscari University of Venice",
journal = "Book of abstracts / 18th International Conference on Chemistry and the Environment – ICCE 2023, June 11-15, 2023, Venice, Italy",
title = "Waste to Energy: Agro-industrial Waste Valorisation Toward Enriched Pellet Production",
pages = "327",
url = "https://hdl.handle.net/21.15107/rcub_technorep_7395"
}

Simić, Z. V., Ivaniš, G. R., Miškov Panić, S. P., Kijevčanin, M. Lj.,& Radović, I. R.. (2023). Waste to Energy: Agro-industrial Waste Valorisation Toward Enriched Pellet Production. in Book of abstracts / 18th International Conference on Chemistry and the Environment – ICCE 2023, June 11-15, 2023, Venice, Italy
Ca'Foscari University of Venice., 327.
https://hdl.handle.net/21.15107/rcub_technorep_7395

Simić ZV, Ivaniš GR, Miškov Panić SP, Kijevčanin ML, Radović IR. Waste to Energy: Agro-industrial Waste Valorisation Toward Enriched Pellet Production. in Book of abstracts / 18th International Conference on Chemistry and the Environment – ICCE 2023, June 11-15, 2023, Venice, Italy. 2023;:327.
https://hdl.handle.net/21.15107/rcub_technorep_7395 .

Simić, Zoran V., Ivaniš, Gorica R., Miškov Panić, Sofija P., Kijevčanin, Mirjana Lj., Radović, Ivona R., "Waste to Energy: Agro-industrial Waste Valorisation Toward Enriched Pellet Production" in Book of abstracts / 18th International Conference on Chemistry and the Environment – ICCE 2023, June 11-15, 2023, Venice, Italy (2023):327,
https://hdl.handle.net/21.15107/rcub_technorep_7395 .

TY  - JOUR
AU  - Simić, Zoran V.
AU  - Radović, Ivona R.
AU  - Stijepović, Mirko Z.
AU  - Kijevčanin, Mirjana Lj.
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6030
AB  - The aim of this study was to examine the possibility of using a green organic solvent, dimethyl adipate (DMA), as a separation agent in the extraction of different alcohols from aqueous solutions. For that purpose, the liquid–liquid equilibria (LLE) of four ternary systems were analytically determined at 298.15 K and atmospheric pressure using stirred and thermo-regulated cells: {water + methanol + dimethyl adipate (DMA)}, {water + ethanol + DMA}, {water + 1-propanol + DMA}, {water + 2-propanol + DMA}. Phase diagrams for these four ternary systems were obtained by determining a binodal curve and tie-lines data using a visual cloud-point method, but also gas chromatography. Distribution coefficients and separation factors were calculated for the immiscibility region. Hand and Othmer-Tobias correlations were used to examine the reliability of the tie-line data. In addition, the experimental ternary LLE data were correlated with the UNIversal QUAsiChemical (UNIQUAC) activity coefficient models. The obtained results showed that DMA is a suitable candidate for the extraction of methanol, ethanol, 1-propanol, and 2-propanol from water. With some alcohols, this potential is more noticeable than with others. The potential of DMA as a separation agent is increasing in the following sequence: methanol < ethanol < 2-propanol < 1-propanol, and that also could be noticed from the selectivity values that also increase in this sequence. The UNIQUAC model proved as successful in correlating the LLE data.
PB  - Elsevier B.V.
T2  - Journal of Molecular Liquids
T1  - Liquid-liquid equilibria of the ternary systems water + C1 – C3 alcohols + dimethyl adipate at 298.15 K and atmospheric pressure: Experimental data and modeling
SP  - 121542
VL  - 377
DO  - 10.1016/j.molliq.2023.121542
ER  - 

@article{
author = "Simić, Zoran V. and Radović, Ivona R. and Stijepović, Mirko Z. and Kijevčanin, Mirjana Lj.",
year = "2023",
abstract = "The aim of this study was to examine the possibility of using a green organic solvent, dimethyl adipate (DMA), as a separation agent in the extraction of different alcohols from aqueous solutions. For that purpose, the liquid–liquid equilibria (LLE) of four ternary systems were analytically determined at 298.15 K and atmospheric pressure using stirred and thermo-regulated cells: {water + methanol + dimethyl adipate (DMA)}, {water + ethanol + DMA}, {water + 1-propanol + DMA}, {water + 2-propanol + DMA}. Phase diagrams for these four ternary systems were obtained by determining a binodal curve and tie-lines data using a visual cloud-point method, but also gas chromatography. Distribution coefficients and separation factors were calculated for the immiscibility region. Hand and Othmer-Tobias correlations were used to examine the reliability of the tie-line data. In addition, the experimental ternary LLE data were correlated with the UNIversal QUAsiChemical (UNIQUAC) activity coefficient models. The obtained results showed that DMA is a suitable candidate for the extraction of methanol, ethanol, 1-propanol, and 2-propanol from water. With some alcohols, this potential is more noticeable than with others. The potential of DMA as a separation agent is increasing in the following sequence: methanol < ethanol < 2-propanol < 1-propanol, and that also could be noticed from the selectivity values that also increase in this sequence. The UNIQUAC model proved as successful in correlating the LLE data.",
publisher = "Elsevier B.V.",
journal = "Journal of Molecular Liquids",
title = "Liquid-liquid equilibria of the ternary systems water + C1 – C3 alcohols + dimethyl adipate at 298.15 K and atmospheric pressure: Experimental data and modeling",
pages = "121542",
volume = "377",
doi = "10.1016/j.molliq.2023.121542"
}

Simić, Z. V., Radović, I. R., Stijepović, M. Z.,& Kijevčanin, M. Lj.. (2023). Liquid-liquid equilibria of the ternary systems water + C1 – C3 alcohols + dimethyl adipate at 298.15 K and atmospheric pressure: Experimental data and modeling. in Journal of Molecular Liquids
Elsevier B.V.., 377, 121542.
https://doi.org/10.1016/j.molliq.2023.121542

Simić ZV, Radović IR, Stijepović MZ, Kijevčanin ML. Liquid-liquid equilibria of the ternary systems water + C1 – C3 alcohols + dimethyl adipate at 298.15 K and atmospheric pressure: Experimental data and modeling. in Journal of Molecular Liquids. 2023;377:121542.
doi:10.1016/j.molliq.2023.121542 .

Simić, Zoran V., Radović, Ivona R., Stijepović, Mirko Z., Kijevčanin, Mirjana Lj., "Liquid-liquid equilibria of the ternary systems water + C1 – C3 alcohols + dimethyl adipate at 298.15 K and atmospheric pressure: Experimental data and modeling" in Journal of Molecular Liquids, 377 (2023):121542,
https://doi.org/10.1016/j.molliq.2023.121542 . .

TY  - CONF
AU  - Simić, Zoran
AU  - Radović, Ivona
AU  - Kijevčanin, Mirjana
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6940
AB  - U ovom radu su prikazani podaci o ravnoteži tečnost-tečnost za trokomponentnu smešu voda
+ aceton + dimetil ftalat na T = 298 K i atmosferskom pritisku. Zbog povećanja potrošnje energije
na globalnom nivou, potrebno je ispitati nove mogućnosti zamene klasičnih energetski intenzivnih
procesa separacije koji bi bili zasnovani na ravnoteži tečnost-tečnost. Ekstrakcija tečnost-tečnost je
isplativa, efikasna i iznad svega, metoda separacije koja je prihvatljiva za prirodu u industrijskim
procesima Ovaj postupak bi takođe uključivao zamenu standardnih industrijskih rastvarača sa
ekološki štetnim karakteristikama novim, zelenim rastvaračima. Dimetil ftalat je dobar kandidat
kao zeleni rastvarač jer je relativno netoksičan, dobijen iz obnovljivih izvora i biorazgradiv. Termodinamički
podaci o ravnoteži tečnost-tečnost kako što su binodalna kriva i ravnotežne linije za
odgovarajući sistem su neophodni za projektovanje procesa separacije kao i za bolju percepciju
ponašanja višekomponentnih sistema i poboljšanje termodinamičkog modelovanja i predviđanja
fazne ravnoteže.
AB  - This paper presents liquid-liquid equilibrium data for the ternary mixture of water + acetone + dimethyl phthalate at T = 298 K and atmospheric pressure. Due to the increase in energy consumption on a global level, it is necessary to examine new possibilities of replacing the classic energy-intensive separation processes that would be based on liquid-liquid extraction. Liquid-liquid
extraction is a cost-effective, efficient and, above all, environmentally friendly separation method in
industrial processes. This procedure would also involve the replacement of standard industrial solvents with environmentally harmful characteristics with new, green solvents. Dimethyl phthalate is a good candidate as a green solvent because it is relatively non-toxic, renewable and biodegradable.
Thermodynamic liquid-liquid equilibrium data such as the binodal curve and tie lines for the
corresponding system are necessary for the design of the separation process as well as for a better perception of the behaviour of multicomponent systems and the improvement of thermodynamic modelling and prediction of phase equilibrium.
PB  - Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), Društvo za procesnu tehniku
C3  - Zbornik radova pisanih za 36. Međunarodni kongres o procesnoj industriji, PROCESING '23, 1 i 2. jun 2023, Šabac = Proceedings
T1  - Određivanje podataka za ravnotežu tečnost-tečnost trokomonentnih sistema u cilju tretmana industrijskih otpadnih vodenih tokova
T1  - Determination of liquid-liquid equilibrium data of ternary systems for the treatment of industrial wastewater streams
SP  - 91
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6940
ER  - 

@conference{
author = "Simić, Zoran and Radović, Ivona and Kijevčanin, Mirjana",
year = "2023",
abstract = "U ovom radu su prikazani podaci o ravnoteži tečnost-tečnost za trokomponentnu smešu voda
+ aceton + dimetil ftalat na T = 298 K i atmosferskom pritisku. Zbog povećanja potrošnje energije
na globalnom nivou, potrebno je ispitati nove mogućnosti zamene klasičnih energetski intenzivnih
procesa separacije koji bi bili zasnovani na ravnoteži tečnost-tečnost. Ekstrakcija tečnost-tečnost je
isplativa, efikasna i iznad svega, metoda separacije koja je prihvatljiva za prirodu u industrijskim
procesima Ovaj postupak bi takođe uključivao zamenu standardnih industrijskih rastvarača sa
ekološki štetnim karakteristikama novim, zelenim rastvaračima. Dimetil ftalat je dobar kandidat
kao zeleni rastvarač jer je relativno netoksičan, dobijen iz obnovljivih izvora i biorazgradiv. Termodinamički
podaci o ravnoteži tečnost-tečnost kako što su binodalna kriva i ravnotežne linije za
odgovarajući sistem su neophodni za projektovanje procesa separacije kao i za bolju percepciju
ponašanja višekomponentnih sistema i poboljšanje termodinamičkog modelovanja i predviđanja
fazne ravnoteže., This paper presents liquid-liquid equilibrium data for the ternary mixture of water + acetone + dimethyl phthalate at T = 298 K and atmospheric pressure. Due to the increase in energy consumption on a global level, it is necessary to examine new possibilities of replacing the classic energy-intensive separation processes that would be based on liquid-liquid extraction. Liquid-liquid
extraction is a cost-effective, efficient and, above all, environmentally friendly separation method in
industrial processes. This procedure would also involve the replacement of standard industrial solvents with environmentally harmful characteristics with new, green solvents. Dimethyl phthalate is a good candidate as a green solvent because it is relatively non-toxic, renewable and biodegradable.
Thermodynamic liquid-liquid equilibrium data such as the binodal curve and tie lines for the
corresponding system are necessary for the design of the separation process as well as for a better perception of the behaviour of multicomponent systems and the improvement of thermodynamic modelling and prediction of phase equilibrium.",
publisher = "Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), Društvo za procesnu tehniku",
journal = "Zbornik radova pisanih za 36. Međunarodni kongres o procesnoj industriji, PROCESING '23, 1 i 2. jun 2023, Šabac = Proceedings",
title = "Određivanje podataka za ravnotežu tečnost-tečnost trokomonentnih sistema u cilju tretmana industrijskih otpadnih vodenih tokova, Determination of liquid-liquid equilibrium data of ternary systems for the treatment of industrial wastewater streams",
pages = "91",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6940"
}

Simić, Z., Radović, I.,& Kijevčanin, M.. (2023). Određivanje podataka za ravnotežu tečnost-tečnost trokomonentnih sistema u cilju tretmana industrijskih otpadnih vodenih tokova. in Zbornik radova pisanih za 36. Međunarodni kongres o procesnoj industriji, PROCESING '23, 1 i 2. jun 2023, Šabac = Proceedings
Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), Društvo za procesnu tehniku., 91.
https://hdl.handle.net/21.15107/rcub_technorep_6940

Simić Z, Radović I, Kijevčanin M. Određivanje podataka za ravnotežu tečnost-tečnost trokomonentnih sistema u cilju tretmana industrijskih otpadnih vodenih tokova. in Zbornik radova pisanih za 36. Međunarodni kongres o procesnoj industriji, PROCESING '23, 1 i 2. jun 2023, Šabac = Proceedings. 2023;:91.
https://hdl.handle.net/21.15107/rcub_technorep_6940 .

Simić, Zoran, Radović, Ivona, Kijevčanin, Mirjana, "Određivanje podataka za ravnotežu tečnost-tečnost trokomonentnih sistema u cilju tretmana industrijskih otpadnih vodenih tokova" in Zbornik radova pisanih za 36. Međunarodni kongres o procesnoj industriji, PROCESING '23, 1 i 2. jun 2023, Šabac = Proceedings (2023):91,
https://hdl.handle.net/21.15107/rcub_technorep_6940 .

TY  - JOUR
AU  - Ivanović, Marija
AU  - Knežević, Sanja
AU  - Radović, Ivona
AU  - Kljajević, Ljiljana
AU  - Mirković, Miljana
AU  - Nenadović, Miloš
AU  - Nenadović, Snežana
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6311
AB  - Geopolymers have excellent physical and mechanical properties, so they can be used as a substitute for ordinary polymers. Geopolymers are ceramic materials, which exhibit the property of brittleness, which can be a limitation in some structural applications. To overcome this shortcoming, a new group of materials (organic geopolymers) was developed. The aim of this work is the synthesis of organic (hybrid) geopolymers. A geopolymer based on metakaolin was synthesized as a reference sample, while polyvinyl alcohol was added as an organic phase for synthesizing a hybrid geopolymer. It was concluded that the systems follow the rule of behavior in liquid systems. The chemical composition of the samples was determined by X-ray fluorescence analysis (XRF). Structural and phase characterization of hybrid and reference materials were analyzed using X-ray diffraction (XRD)and Fourier-transform infrared spectroscopy (FTIR), which revealed new phases in the PVA-added samples. The results show that the content of added PVA in the reaction mixture affects the phase composition of the synthesized materials. To examine the possibility of adsorption of the samples, Ultraviolet-visible spectroscopy (UV/VIS) was used. The morphology was analyzed using a scanning electron microscope with energy dispersive spectroscopy (SEM/EDS), where efflorescence was observed and identified. After characterizing the geopolymer with the addition of PVA, we obtained a material that was far more porous than the basic sample, and we can conclude that we have synthesized a material that shows good mechanical properties.
PB  - MDPI
T2  - Sustainability (Switzerland)
T1  - Preparation and Characterization of Geopolymers Based on Metakaolin with the Addition of Organic Phase PVA
IS  - 5
SP  - 4441
VL  - 15
DO  - 10.3390/su15054441
ER  - 

@article{
author = "Ivanović, Marija and Knežević, Sanja and Radović, Ivona and Kljajević, Ljiljana and Mirković, Miljana and Nenadović, Miloš and Nenadović, Snežana",
year = "2023",
abstract = "Geopolymers have excellent physical and mechanical properties, so they can be used as a substitute for ordinary polymers. Geopolymers are ceramic materials, which exhibit the property of brittleness, which can be a limitation in some structural applications. To overcome this shortcoming, a new group of materials (organic geopolymers) was developed. The aim of this work is the synthesis of organic (hybrid) geopolymers. A geopolymer based on metakaolin was synthesized as a reference sample, while polyvinyl alcohol was added as an organic phase for synthesizing a hybrid geopolymer. It was concluded that the systems follow the rule of behavior in liquid systems. The chemical composition of the samples was determined by X-ray fluorescence analysis (XRF). Structural and phase characterization of hybrid and reference materials were analyzed using X-ray diffraction (XRD)and Fourier-transform infrared spectroscopy (FTIR), which revealed new phases in the PVA-added samples. The results show that the content of added PVA in the reaction mixture affects the phase composition of the synthesized materials. To examine the possibility of adsorption of the samples, Ultraviolet-visible spectroscopy (UV/VIS) was used. The morphology was analyzed using a scanning electron microscope with energy dispersive spectroscopy (SEM/EDS), where efflorescence was observed and identified. After characterizing the geopolymer with the addition of PVA, we obtained a material that was far more porous than the basic sample, and we can conclude that we have synthesized a material that shows good mechanical properties.",
publisher = "MDPI",
journal = "Sustainability (Switzerland)",
title = "Preparation and Characterization of Geopolymers Based on Metakaolin with the Addition of Organic Phase PVA",
number = "5",
pages = "4441",
volume = "15",
doi = "10.3390/su15054441"
}

Ivanović, M., Knežević, S., Radović, I., Kljajević, L., Mirković, M., Nenadović, M.,& Nenadović, S.. (2023). Preparation and Characterization of Geopolymers Based on Metakaolin with the Addition of Organic Phase PVA. in Sustainability (Switzerland)
MDPI., 15(5), 4441.
https://doi.org/10.3390/su15054441

Ivanović M, Knežević S, Radović I, Kljajević L, Mirković M, Nenadović M, Nenadović S. Preparation and Characterization of Geopolymers Based on Metakaolin with the Addition of Organic Phase PVA. in Sustainability (Switzerland). 2023;15(5):4441.
doi:10.3390/su15054441 .

Ivanović, Marija, Knežević, Sanja, Radović, Ivona, Kljajević, Ljiljana, Mirković, Miljana, Nenadović, Miloš, Nenadović, Snežana, "Preparation and Characterization of Geopolymers Based on Metakaolin with the Addition of Organic Phase PVA" in Sustainability (Switzerland), 15, no. 5 (2023):4441,
https://doi.org/10.3390/su15054441 . .

TY  - JOUR
AU  - Jovanović, Jovan D.
AU  - Grozdanić, Nikola D.
AU  - Radović, Ivona R.
AU  - Kijevčanin, Mirjana Lj.
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6332
AB  - In this paper a group contribution model for predicting the viscosity values of n-alkanes and iso-alkanes in the liquid phase based on Free-Volume Theory was developed. A database with 2129 experimental data with a temperature range up to 573.15 K and a pressure range up to 4000 bar was used to develop the model. The total weighted average percentage error is 4.894%. The model was tested on the next 472 experimental data with a temperature range up to 564.15 K and a pressure range up to 2019 bar and a mean percentage error that was obtained is 5.155%.
PB  - Elsevier B.V.
T2  - Journal of Molecular Liquids
T1  - A new group contribution model for prediction liquid hydrocarbon viscosity based on free-volume theory
SP  - 121452
VL  - 376
DO  - 10.1016/j.molliq.2023.121452
ER  - 

@article{
author = "Jovanović, Jovan D. and Grozdanić, Nikola D. and Radović, Ivona R. and Kijevčanin, Mirjana Lj.",
year = "2023",
abstract = "In this paper a group contribution model for predicting the viscosity values of n-alkanes and iso-alkanes in the liquid phase based on Free-Volume Theory was developed. A database with 2129 experimental data with a temperature range up to 573.15 K and a pressure range up to 4000 bar was used to develop the model. The total weighted average percentage error is 4.894%. The model was tested on the next 472 experimental data with a temperature range up to 564.15 K and a pressure range up to 2019 bar and a mean percentage error that was obtained is 5.155%.",
publisher = "Elsevier B.V.",
journal = "Journal of Molecular Liquids",
title = "A new group contribution model for prediction liquid hydrocarbon viscosity based on free-volume theory",
pages = "121452",
volume = "376",
doi = "10.1016/j.molliq.2023.121452"
}

Jovanović, J. D., Grozdanić, N. D., Radović, I. R.,& Kijevčanin, M. Lj.. (2023). A new group contribution model for prediction liquid hydrocarbon viscosity based on free-volume theory. in Journal of Molecular Liquids
Elsevier B.V.., 376, 121452.
https://doi.org/10.1016/j.molliq.2023.121452

Jovanović JD, Grozdanić ND, Radović IR, Kijevčanin ML. A new group contribution model for prediction liquid hydrocarbon viscosity based on free-volume theory. in Journal of Molecular Liquids. 2023;376:121452.
doi:10.1016/j.molliq.2023.121452 .

Jovanović, Jovan D., Grozdanić, Nikola D., Radović, Ivona R., Kijevčanin, Mirjana Lj., "A new group contribution model for prediction liquid hydrocarbon viscosity based on free-volume theory" in Journal of Molecular Liquids, 376 (2023):121452,
https://doi.org/10.1016/j.molliq.2023.121452 . .

TY  - CONF
AU  - Simić, Zoran
AU  - Ivaniš, Gorica
AU  - Radović, Ivona
AU  - Kijevčanin, Mirjana
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7394
UR  - https://conference-doctoral.up.lublin.pl/2022-volume/
AB  - Due to the global trend of decreasing fossil energy sources consumption, there is a tendency, among other things, to explore possibilities of using biomass to obtain biofuels and value-added chemicals. In order to design processes as optimally as possible, it is necessary to know the thermodynamic properties of biomass components. One of the components that have been gaining in importance lately are furfural and furfuryl alcohol. The thermodynamic and transport properties such as density, speed of sound, refractive index and viscosity, of the binary system furfural + furfuryl alcohol were studied at various temperatures and pressures. Density of pure components was obtained in the temperature range (293.15–413.15) K for furfural and (293.15–373.15) K for furfuryl alcohol at pressure up to 60.0 MPa. The obtained density values were correlated using the modified Tammann–Tait equation. The thermodynamic properties of these components are of great importance in their further potential application.
PB  - Lublin : Publishing House of The University of Life Sciences
C3  - 1st International PhD Student’s Conference  at the University of Life Sciences in Lublin, Poland: ENVIRONMENT- PLANT-ANIMAL-PRODUCT (ICDSUPL), 26 April 2022
T1  - Thermodynamic properties of pure furfural and furfuryl alcohol and binary mixture at different pressures and temperatures
SP  - T029
DO  - 10.24326/ICDSUPL1.T029
ER  - 

@conference{
author = "Simić, Zoran and Ivaniš, Gorica and Radović, Ivona and Kijevčanin, Mirjana",
year = "2022",
abstract = "Due to the global trend of decreasing fossil energy sources consumption, there is a tendency, among other things, to explore possibilities of using biomass to obtain biofuels and value-added chemicals. In order to design processes as optimally as possible, it is necessary to know the thermodynamic properties of biomass components. One of the components that have been gaining in importance lately are furfural and furfuryl alcohol. The thermodynamic and transport properties such as density, speed of sound, refractive index and viscosity, of the binary system furfural + furfuryl alcohol were studied at various temperatures and pressures. Density of pure components was obtained in the temperature range (293.15–413.15) K for furfural and (293.15–373.15) K for furfuryl alcohol at pressure up to 60.0 MPa. The obtained density values were correlated using the modified Tammann–Tait equation. The thermodynamic properties of these components are of great importance in their further potential application.",
publisher = "Lublin : Publishing House of The University of Life Sciences",
journal = "1st International PhD Student’s Conference  at the University of Life Sciences in Lublin, Poland: ENVIRONMENT- PLANT-ANIMAL-PRODUCT (ICDSUPL), 26 April 2022",
title = "Thermodynamic properties of pure furfural and furfuryl alcohol and binary mixture at different pressures and temperatures",
pages = "T029",
doi = "10.24326/ICDSUPL1.T029"
}

Simić, Z., Ivaniš, G., Radović, I.,& Kijevčanin, M.. (2022). Thermodynamic properties of pure furfural and furfuryl alcohol and binary mixture at different pressures and temperatures. in 1st International PhD Student’s Conference  at the University of Life Sciences in Lublin, Poland: ENVIRONMENT- PLANT-ANIMAL-PRODUCT (ICDSUPL), 26 April 2022
Lublin : Publishing House of The University of Life Sciences., T029.
https://doi.org/10.24326/ICDSUPL1.T029

Simić Z, Ivaniš G, Radović I, Kijevčanin M. Thermodynamic properties of pure furfural and furfuryl alcohol and binary mixture at different pressures and temperatures. in 1st International PhD Student’s Conference  at the University of Life Sciences in Lublin, Poland: ENVIRONMENT- PLANT-ANIMAL-PRODUCT (ICDSUPL), 26 April 2022. 2022;:T029.
doi:10.24326/ICDSUPL1.T029 .

Simić, Zoran, Ivaniš, Gorica, Radović, Ivona, Kijevčanin, Mirjana, "Thermodynamic properties of pure furfural and furfuryl alcohol and binary mixture at different pressures and temperatures" in 1st International PhD Student’s Conference  at the University of Life Sciences in Lublin, Poland: ENVIRONMENT- PLANT-ANIMAL-PRODUCT (ICDSUPL), 26 April 2022 (2022):T029,
https://doi.org/10.24326/ICDSUPL1.T029 . .

TY  - CONF
AU  - Ivaniš, Gorica
AU  - Radović, Ivona
AU  - Kijevčanin, Mirjana
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7397
AB  - The negative consequences of the use of fossil fuels, as well as the unsustainability of meeting ever-increasing energy requirements with limited reserves of fossil fuels, have led to the intensification of research in the field of renewable energy sources. Thermo-chemical conversion of biomass results in bio-oil with low energy density due to high oxygen content which can be upgraded by hydrodeoxygenation process (HDO). HDO consists of a number of reactions that can overlap so the process management requires knowledge on the thermodynamic properties of all compounds present in the biomass valorization process. 
Eugenol is promising biomass-derived platform chemical that, depending on used catalyst and reaction conditions, can be converted into a variety of important products including 4-propylguaiacol. Densities of eugenol and 4-propylguaiacol were measured at temperatures (293.15 – 413.15) K and pressures up to 60 MPa. The obtained results were correlated using the modified Tammann-Tait equation, which enabled the calculation of the valuable derived thermodynamic properties, such as the isothermal compressibility, the isobaric thermal expansivity, the internal pressure and the difference between isobaric and isochoric heat capacity. Densities of the binary mixtures eugenol + 4-propylguaiacol were measured at atmospheric pressure and temperatures (288.15 – 343.15) K to examine the influence of interactions between the studied 
components on the thermodynamic properties of their mixtures.
PB  - Graz : Graz University of Technology
C3  - 32nd European Symposium on Applied Thermodynamics 2022, 17-20. July 2022, Graz, Austria
T1  - Thermodynamic properties of binary system eugenol + 4- propylguaiacol in wide ranges of temperature and pressure
SP  - 184
UR  - https://hdl.handle.net/21.15107/rcub_technorep_7397
ER  - 

@conference{
author = "Ivaniš, Gorica and Radović, Ivona and Kijevčanin, Mirjana",
year = "2022",
abstract = "The negative consequences of the use of fossil fuels, as well as the unsustainability of meeting ever-increasing energy requirements with limited reserves of fossil fuels, have led to the intensification of research in the field of renewable energy sources. Thermo-chemical conversion of biomass results in bio-oil with low energy density due to high oxygen content which can be upgraded by hydrodeoxygenation process (HDO). HDO consists of a number of reactions that can overlap so the process management requires knowledge on the thermodynamic properties of all compounds present in the biomass valorization process. 
Eugenol is promising biomass-derived platform chemical that, depending on used catalyst and reaction conditions, can be converted into a variety of important products including 4-propylguaiacol. Densities of eugenol and 4-propylguaiacol were measured at temperatures (293.15 – 413.15) K and pressures up to 60 MPa. The obtained results were correlated using the modified Tammann-Tait equation, which enabled the calculation of the valuable derived thermodynamic properties, such as the isothermal compressibility, the isobaric thermal expansivity, the internal pressure and the difference between isobaric and isochoric heat capacity. Densities of the binary mixtures eugenol + 4-propylguaiacol were measured at atmospheric pressure and temperatures (288.15 – 343.15) K to examine the influence of interactions between the studied 
components on the thermodynamic properties of their mixtures.",
publisher = "Graz : Graz University of Technology",
journal = "32nd European Symposium on Applied Thermodynamics 2022, 17-20. July 2022, Graz, Austria",
title = "Thermodynamic properties of binary system eugenol + 4- propylguaiacol in wide ranges of temperature and pressure",
pages = "184",
url = "https://hdl.handle.net/21.15107/rcub_technorep_7397"
}

Ivaniš, G., Radović, I.,& Kijevčanin, M.. (2022). Thermodynamic properties of binary system eugenol + 4- propylguaiacol in wide ranges of temperature and pressure. in 32nd European Symposium on Applied Thermodynamics 2022, 17-20. July 2022, Graz, Austria
Graz : Graz University of Technology., 184.
https://hdl.handle.net/21.15107/rcub_technorep_7397

Ivaniš G, Radović I, Kijevčanin M. Thermodynamic properties of binary system eugenol + 4- propylguaiacol in wide ranges of temperature and pressure. in 32nd European Symposium on Applied Thermodynamics 2022, 17-20. July 2022, Graz, Austria. 2022;:184.
https://hdl.handle.net/21.15107/rcub_technorep_7397 .

Ivaniš, Gorica, Radović, Ivona, Kijevčanin, Mirjana, "Thermodynamic properties of binary system eugenol + 4- propylguaiacol in wide ranges of temperature and pressure" in 32nd European Symposium on Applied Thermodynamics 2022, 17-20. July 2022, Graz, Austria (2022):184,
https://hdl.handle.net/21.15107/rcub_technorep_7397 .

TY  - CONF
AU  - Simić, Zoran
AU  - Kijevčanin, Mirjana
AU  - Radović, Ivona
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7388
AB  - Zbog globalnog trenda povećanja zagađenosti životne okoline teži se ka tome da se u različitim granama hemijske industrije implementiraju zeleni rastvarači, koji bi zamenili štetne industrijske rastvarače. Kako bi se ispitale mogućnosti upotrebe zelenih rastvarača, mogućnosti adekvatne zamene i projektovanje procesa, neophodno je poznavanje termodinamičkih podataka kao što su podaci za ravnotežu tečnost-tečnost (LLE), odgovarajuću binodalnu krivu i ravnotežne linije. Podaci o rastvorljivosti komponenata su od velikog značaja za procese separacije (naročito ekstrakciju) koji se primenjuju u hemijskoj industriji. Ravnotežne linije predstavljaju veoma bitan termodinamički podatak koji se, u zavisnosti od same prirode komponenti koje ulaze u sastav smeše, u velikom procentu dobijaju hromatografskom analizom. S obzirom da je hromatografska analiza metoda koju ne može svaka laboratorija da priušti, kako zbog visoke cene aparata tako i zbog visokih troškova korišćenja, u ovom radu biće prikazane neke od alternativnih mogućnosti za određivanje ravnotežnih linija kod ravnoteže tečnost-tečnost. Na primeru ternarnog sistema voda+dimetil adipat+2-propanol biće prikazano određivanje ravnotežnih linija preko indeksa refrakcije i preko gustine smeše. Ove analitičke metode često se koriste u različitim granama industrije. Na osnovu dobijenih rezultata izvršeno je medjusobno poredjenje rezultata dobijenih preko ove tri metode.
AB  - Due to the global trend of increasing environmental pollution, green solvents are being implemented in various branches of the chemical industry to, which would replace standard industrial solvents with harmful characteristics. In order to examine the possibilities of using green solvents, the possibility of appropriate replacement and process design, it is necessary to determine thermodynamic data such as liquid-liquid equilibria, i.e. tie lines in liquid- liquid extraction (LLE), and the corresponding binodal curve. Solubility of components are of great importance for the separation processes (especially for extraction) applied in the chemical industry. Tie lines are a very important thermodynamic data, which are mostly determined by chromatographic analysis depending on the nature of the components in the mixture. Tie lines are mostly determined by chromatographic analysis. Chromatographic analysis is one of the methods that not every laboratory can afford, due to the high cost of the apparatus and high operational costs. In this paper some of the alternative methods for determining tie lines in liquid-liquid equilibria are presented. On the example of the ternary system water+dimethyl adipate+2-propanol, the determination of tie lines via the refractive index and the density of the mixture are shown. These analytical methods are often used in various branches of industry. Based on the obtained results, a mutual comparison of the results obtained through these three methods is performed.
PB  - Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), Društvo za procesnu tehniku
C3  - Zbornik radova / 35. Međunarodni kongres o procesnoj industriji, PROCESING '22, 1-3. jun 2022, Beograd
T1  - Analiza različitih mogućnosti za određivanje ravnotežnih linija kod ravnoteže tečnost-tečnost
T1  - Analysis of different possibilities for determining tie lines in liquid-liquid equilibria
EP  - 323
SP  - 319
DO  - 10.24094/ptk.022.319
ER  - 

@conference{
author = "Simić, Zoran and Kijevčanin, Mirjana and Radović, Ivona",
year = "2022",
abstract = "Zbog globalnog trenda povećanja zagađenosti životne okoline teži se ka tome da se u različitim granama hemijske industrije implementiraju zeleni rastvarači, koji bi zamenili štetne industrijske rastvarače. Kako bi se ispitale mogućnosti upotrebe zelenih rastvarača, mogućnosti adekvatne zamene i projektovanje procesa, neophodno je poznavanje termodinamičkih podataka kao što su podaci za ravnotežu tečnost-tečnost (LLE), odgovarajuću binodalnu krivu i ravnotežne linije. Podaci o rastvorljivosti komponenata su od velikog značaja za procese separacije (naročito ekstrakciju) koji se primenjuju u hemijskoj industriji. Ravnotežne linije predstavljaju veoma bitan termodinamički podatak koji se, u zavisnosti od same prirode komponenti koje ulaze u sastav smeše, u velikom procentu dobijaju hromatografskom analizom. S obzirom da je hromatografska analiza metoda koju ne može svaka laboratorija da priušti, kako zbog visoke cene aparata tako i zbog visokih troškova korišćenja, u ovom radu biće prikazane neke od alternativnih mogućnosti za određivanje ravnotežnih linija kod ravnoteže tečnost-tečnost. Na primeru ternarnog sistema voda+dimetil adipat+2-propanol biće prikazano određivanje ravnotežnih linija preko indeksa refrakcije i preko gustine smeše. Ove analitičke metode često se koriste u različitim granama industrije. Na osnovu dobijenih rezultata izvršeno je medjusobno poredjenje rezultata dobijenih preko ove tri metode., Due to the global trend of increasing environmental pollution, green solvents are being implemented in various branches of the chemical industry to, which would replace standard industrial solvents with harmful characteristics. In order to examine the possibilities of using green solvents, the possibility of appropriate replacement and process design, it is necessary to determine thermodynamic data such as liquid-liquid equilibria, i.e. tie lines in liquid- liquid extraction (LLE), and the corresponding binodal curve. Solubility of components are of great importance for the separation processes (especially for extraction) applied in the chemical industry. Tie lines are a very important thermodynamic data, which are mostly determined by chromatographic analysis depending on the nature of the components in the mixture. Tie lines are mostly determined by chromatographic analysis. Chromatographic analysis is one of the methods that not every laboratory can afford, due to the high cost of the apparatus and high operational costs. In this paper some of the alternative methods for determining tie lines in liquid-liquid equilibria are presented. On the example of the ternary system water+dimethyl adipate+2-propanol, the determination of tie lines via the refractive index and the density of the mixture are shown. These analytical methods are often used in various branches of industry. Based on the obtained results, a mutual comparison of the results obtained through these three methods is performed.",
publisher = "Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), Društvo za procesnu tehniku",
journal = "Zbornik radova / 35. Međunarodni kongres o procesnoj industriji, PROCESING '22, 1-3. jun 2022, Beograd",
title = "Analiza različitih mogućnosti za određivanje ravnotežnih linija kod ravnoteže tečnost-tečnost, Analysis of different possibilities for determining tie lines in liquid-liquid equilibria",
pages = "323-319",
doi = "10.24094/ptk.022.319"
}

Simić, Z., Kijevčanin, M.,& Radović, I.. (2022). Analiza različitih mogućnosti za određivanje ravnotežnih linija kod ravnoteže tečnost-tečnost. in Zbornik radova / 35. Međunarodni kongres o procesnoj industriji, PROCESING '22, 1-3. jun 2022, Beograd
Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), Društvo za procesnu tehniku., 319-323.
https://doi.org/10.24094/ptk.022.319

Simić Z, Kijevčanin M, Radović I. Analiza različitih mogućnosti za određivanje ravnotežnih linija kod ravnoteže tečnost-tečnost. in Zbornik radova / 35. Međunarodni kongres o procesnoj industriji, PROCESING '22, 1-3. jun 2022, Beograd. 2022;:319-323.
doi:10.24094/ptk.022.319 .

Simić, Zoran, Kijevčanin, Mirjana, Radović, Ivona, "Analiza različitih mogućnosti za određivanje ravnotežnih linija kod ravnoteže tečnost-tečnost" in Zbornik radova / 35. Međunarodni kongres o procesnoj industriji, PROCESING '22, 1-3. jun 2022, Beograd (2022):319-323,
https://doi.org/10.24094/ptk.022.319 . .

TY  - JOUR
AU  - Mohammad, Ahmad Hakky
AU  - Radović, Ivona
AU  - Ivanović, Marija
AU  - Kijevčanin, Mirjana
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5224
AB  - Water hyacinth biomass was used for the synthesis of activated carbons in the process of chemical activation with H3PO4, followed by controlled carbonization. The study investigates the effect of various impregnation weight ratios of H3PO4 and dry hyacinth (0.5–3.0), as well as different carbonization temperatures (T = 400–800 °C), on the surface characteristics of the produced activated carbons (AC). The activated carbon obtained with an impregnation ratio of 1.5 and a carbonization temperature of 600 °C (1.5 AC/600) showed the highest values of specific surface area of 1421 m2 g−1, representing a selected adsorbent for metformin removal. The chosen sample was characterized by elemental analysis, adsorption–desorption isotherms of nitrogen at −196 °C, via FTIR spectroscopy and the SEM method. The modeling of the experimental adsorption data showed that metformin adsorption: (i) can be best described by the Langmuir isotherm model, with the value of qmax = 122.47 mg g−1; (ii) led the pseudo-second order kinetic model; and (iii) is a spontaneous (ΔG° = −3.44 kJ mol−1) and endothermic (ΔH° = 8.77 kJ mol−1) process. A desorption study has shown that 92% of metformin was successfully desorbed in the presence of a 0.1 MHCl/ethanol mixture (volume ratio 2:1). The recovery of the adsorbent of 84%, after five successive cycles, indicated that the 1.5 AC/600 has potential to be applied in the real systems for water treatment.
PB  - MDPI
T2  - Sustainability
T1  - Adsorption of Metformin on Activated Carbon Produced from the Water Hyacinth Biowaste Using H3PO4 as a Chemical Activator
IS  - 18
SP  - 11144
VL  - 14
DO  - 10.3390/su141811144
ER  - 

@article{
author = "Mohammad, Ahmad Hakky and Radović, Ivona and Ivanović, Marija and Kijevčanin, Mirjana",
year = "2022",
abstract = "Water hyacinth biomass was used for the synthesis of activated carbons in the process of chemical activation with H3PO4, followed by controlled carbonization. The study investigates the effect of various impregnation weight ratios of H3PO4 and dry hyacinth (0.5–3.0), as well as different carbonization temperatures (T = 400–800 °C), on the surface characteristics of the produced activated carbons (AC). The activated carbon obtained with an impregnation ratio of 1.5 and a carbonization temperature of 600 °C (1.5 AC/600) showed the highest values of specific surface area of 1421 m2 g−1, representing a selected adsorbent for metformin removal. The chosen sample was characterized by elemental analysis, adsorption–desorption isotherms of nitrogen at −196 °C, via FTIR spectroscopy and the SEM method. The modeling of the experimental adsorption data showed that metformin adsorption: (i) can be best described by the Langmuir isotherm model, with the value of qmax = 122.47 mg g−1; (ii) led the pseudo-second order kinetic model; and (iii) is a spontaneous (ΔG° = −3.44 kJ mol−1) and endothermic (ΔH° = 8.77 kJ mol−1) process. A desorption study has shown that 92% of metformin was successfully desorbed in the presence of a 0.1 MHCl/ethanol mixture (volume ratio 2:1). The recovery of the adsorbent of 84%, after five successive cycles, indicated that the 1.5 AC/600 has potential to be applied in the real systems for water treatment.",
publisher = "MDPI",
journal = "Sustainability",
title = "Adsorption of Metformin on Activated Carbon Produced from the Water Hyacinth Biowaste Using H3PO4 as a Chemical Activator",
number = "18",
pages = "11144",
volume = "14",
doi = "10.3390/su141811144"
}

Mohammad, A. H., Radović, I., Ivanović, M.,& Kijevčanin, M.. (2022). Adsorption of Metformin on Activated Carbon Produced from the Water Hyacinth Biowaste Using H3PO4 as a Chemical Activator. in Sustainability
MDPI., 14(18), 11144.
https://doi.org/10.3390/su141811144

Mohammad AH, Radović I, Ivanović M, Kijevčanin M. Adsorption of Metformin on Activated Carbon Produced from the Water Hyacinth Biowaste Using H3PO4 as a Chemical Activator. in Sustainability. 2022;14(18):11144.
doi:10.3390/su141811144 .

Mohammad, Ahmad Hakky, Radović, Ivona, Ivanović, Marija, Kijevčanin, Mirjana, "Adsorption of Metformin on Activated Carbon Produced from the Water Hyacinth Biowaste Using H3PO4 as a Chemical Activator" in Sustainability, 14, no. 18 (2022):11144,
https://doi.org/10.3390/su141811144 . .

TY  - JOUR
AU  - Zarić, Milana M.
AU  - Vraneš, Milan
AU  - Bikić, Siniša
AU  - Tot, Aleksandar
AU  - Papović, Snežana
AU  - Borović, Teona Teodora
AU  - Kijevčanin, Mirjana Lj.
AU  - Radović, Ivona R.
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5246
AB  - Ethylene glycol is recognized as a heat transfer fluid. To improve its performance, caffeine is added to pure ethylene glycol. The experimental measurements of densities at pressures of up to 60 MPa and in the range of temperatures 293.15-413.15 K were performed. Obtained experimental results were fitted by the modified Tammann-Tait equation, and parameters were used to determine some valuable thermodynamic and mechanical properties, the isothermal compressibility, the isobaric thermal expansibility, the internal pressure, and the difference of specific heat capacity at constant pressure and constant volume. The same approach was applied to the equimolar mixture of ethylene glycol and water. The results confirm negligible changes in the investigated thermodynamic properties with the addition of caffeine into pure ethylene glycol and significantly smaller dependence on temperature compared to the mixture of ethylene glycol and water.
PB  - American Chemical Society
T2  - Journal of Chemical and Engineering Data
T1  - Thermodynamic Properties of Caffeine in Ethylene Glycol at High Pressures and High Temperatures
DO  - 10.1021/acs.jced.2c00401
ER  - 

@article{
author = "Zarić, Milana M. and Vraneš, Milan and Bikić, Siniša and Tot, Aleksandar and Papović, Snežana and Borović, Teona Teodora and Kijevčanin, Mirjana Lj. and Radović, Ivona R.",
year = "2022",
abstract = "Ethylene glycol is recognized as a heat transfer fluid. To improve its performance, caffeine is added to pure ethylene glycol. The experimental measurements of densities at pressures of up to 60 MPa and in the range of temperatures 293.15-413.15 K were performed. Obtained experimental results were fitted by the modified Tammann-Tait equation, and parameters were used to determine some valuable thermodynamic and mechanical properties, the isothermal compressibility, the isobaric thermal expansibility, the internal pressure, and the difference of specific heat capacity at constant pressure and constant volume. The same approach was applied to the equimolar mixture of ethylene glycol and water. The results confirm negligible changes in the investigated thermodynamic properties with the addition of caffeine into pure ethylene glycol and significantly smaller dependence on temperature compared to the mixture of ethylene glycol and water.",
publisher = "American Chemical Society",
journal = "Journal of Chemical and Engineering Data",
title = "Thermodynamic Properties of Caffeine in Ethylene Glycol at High Pressures and High Temperatures",
doi = "10.1021/acs.jced.2c00401"
}

Zarić, M. M., Vraneš, M., Bikić, S., Tot, A., Papović, S., Borović, T. T., Kijevčanin, M. Lj.,& Radović, I. R.. (2022). Thermodynamic Properties of Caffeine in Ethylene Glycol at High Pressures and High Temperatures. in Journal of Chemical and Engineering Data
American Chemical Society..
https://doi.org/10.1021/acs.jced.2c00401

Zarić MM, Vraneš M, Bikić S, Tot A, Papović S, Borović TT, Kijevčanin ML, Radović IR. Thermodynamic Properties of Caffeine in Ethylene Glycol at High Pressures and High Temperatures. in Journal of Chemical and Engineering Data. 2022;.
doi:10.1021/acs.jced.2c00401 .

Zarić, Milana M., Vraneš, Milan, Bikić, Siniša, Tot, Aleksandar, Papović, Snežana, Borović, Teona Teodora, Kijevčanin, Mirjana Lj., Radović, Ivona R., "Thermodynamic Properties of Caffeine in Ethylene Glycol at High Pressures and High Temperatures" in Journal of Chemical and Engineering Data (2022),
https://doi.org/10.1021/acs.jced.2c00401 . .

Кијевчанин, М., Стијеповић, М., Радовић, И., Грозданић, Н.,& Иваниш, Г.. (2022). PYROLSIM – Софтвер за симулацију и оптимизацију пиролитичке пећи у фабрици  Етилен. 
Технолошко - металуршки факултет, Универзитет у Београду..
https://hdl.handle.net/21.15107/rcub_technorep_7385

Кијевчанин М, Стијеповић М, Радовић И, Грозданић Н, Иваниш Г. PYROLSIM – Софтвер за симулацију и оптимизацију пиролитичке пећи у фабрици  Етилен. 2022;.
https://hdl.handle.net/21.15107/rcub_technorep_7385 .

Кијевчанин, Мирјана, Стијеповић, Мирко, Радовић, Ивона, Грозданић, Никола, Иваниш, Горица, "PYROLSIM – Софтвер за симулацију и оптимизацију пиролитичке пећи у фабрици  Етилен" (2022),
https://hdl.handle.net/21.15107/rcub_technorep_7385 .

TY  - CONF
AU  - Simić, Zoran
AU  - Miletić, Ksenija
AU  - Grozdanić, Nikola
AU  - Radović, Ivona
AU  - Kijevčanin, Mirjana
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7398
AB  - U cilju smanjenja zagađenja na globalnom nivou poslednjih godina aktuelna je tema zamene fosilnih goriva nekim novim biogorivima. Terpeni, koji su sastavni delovi biljaka, mogu se koristiti u ove svrhe kao dodatak standardnim gorivima. Neke od termodinamičkih svojstva pod uslovima visokog pritiska i određnih temperatura su od velike važnosti za efikasnost motora. U ovom radu su dobijene gustine linalola, alfa-pinena i beta-pinena u temperaturnom intervalu 293.15-413.15 K i na pritiscima do 60 MPa. Na osnovu ovih rezultata utvrđeno je da s porastom temperature pri konstantnom pritisku gustina navedenih terpena opada, dok sa povećanjem pritiska pri konstantnoj temperaturi gustina raste.
AB  - In order to reduce pollution at the global level in recent years, the main topic is replacing fossil fuels with some new biofuels. Terpenes, which are integral parts of plants, can be used for these purposes as an addition to standard petroelum fuels. Some of thermodynamic properties under high pressure conditions and moderate temperatures are of significant importance for engine efficiency. In this work, the densities of linalool, αpinene and β-pinene were obtained in the temperature range 293.15-413.15 K and at pressures up to 60 MPa. Based on these results, it was found that with increasing temperature at constant pressure the density of these terpenes decreases, while with increasing pressure at constant temperature the density increases.
PB  - Beograd : Srpsko hemijsko društvo = Serbian Chemical Society
C3  - Kratki izvodi radova ; Knjiga radova / 57. savetovanje Srpskog hemijskog društva, Kragujevac 18. i 19. juni 2021. = Book of Abstracts ; Proceedings = 57th meeting of the Serbian Chemical Society, Kragujevac, Serbia, June 18-19, 2021
T1  - Eksperimentalno određivanje gustina linalola, alfa-pinena i beta-pinena na visokom pritisku
T1  - Experimental determination of linalool, α-pinene and β-pinene densities at high pressure
EP  - 127
SP  - 121
UR  - https://hdl.handle.net/21.15107/rcub_technorep_7398
ER  - 

@conference{
author = "Simić, Zoran and Miletić, Ksenija and Grozdanić, Nikola and Radović, Ivona and Kijevčanin, Mirjana",
year = "2021",
abstract = "U cilju smanjenja zagađenja na globalnom nivou poslednjih godina aktuelna je tema zamene fosilnih goriva nekim novim biogorivima. Terpeni, koji su sastavni delovi biljaka, mogu se koristiti u ove svrhe kao dodatak standardnim gorivima. Neke od termodinamičkih svojstva pod uslovima visokog pritiska i određnih temperatura su od velike važnosti za efikasnost motora. U ovom radu su dobijene gustine linalola, alfa-pinena i beta-pinena u temperaturnom intervalu 293.15-413.15 K i na pritiscima do 60 MPa. Na osnovu ovih rezultata utvrđeno je da s porastom temperature pri konstantnom pritisku gustina navedenih terpena opada, dok sa povećanjem pritiska pri konstantnoj temperaturi gustina raste., In order to reduce pollution at the global level in recent years, the main topic is replacing fossil fuels with some new biofuels. Terpenes, which are integral parts of plants, can be used for these purposes as an addition to standard petroelum fuels. Some of thermodynamic properties under high pressure conditions and moderate temperatures are of significant importance for engine efficiency. In this work, the densities of linalool, αpinene and β-pinene were obtained in the temperature range 293.15-413.15 K and at pressures up to 60 MPa. Based on these results, it was found that with increasing temperature at constant pressure the density of these terpenes decreases, while with increasing pressure at constant temperature the density increases.",
publisher = "Beograd : Srpsko hemijsko društvo = Serbian Chemical Society",
journal = "Kratki izvodi radova ; Knjiga radova / 57. savetovanje Srpskog hemijskog društva, Kragujevac 18. i 19. juni 2021. = Book of Abstracts ; Proceedings = 57th meeting of the Serbian Chemical Society, Kragujevac, Serbia, June 18-19, 2021",
title = "Eksperimentalno određivanje gustina linalola, alfa-pinena i beta-pinena na visokom pritisku, Experimental determination of linalool, α-pinene and β-pinene densities at high pressure",
pages = "127-121",
url = "https://hdl.handle.net/21.15107/rcub_technorep_7398"
}

Simić, Z., Miletić, K., Grozdanić, N., Radović, I.,& Kijevčanin, M.. (2021). Eksperimentalno određivanje gustina linalola, alfa-pinena i beta-pinena na visokom pritisku. in Kratki izvodi radova ; Knjiga radova / 57. savetovanje Srpskog hemijskog društva, Kragujevac 18. i 19. juni 2021. = Book of Abstracts ; Proceedings = 57th meeting of the Serbian Chemical Society, Kragujevac, Serbia, June 18-19, 2021
Beograd : Srpsko hemijsko društvo = Serbian Chemical Society., 121-127.
https://hdl.handle.net/21.15107/rcub_technorep_7398

Simić Z, Miletić K, Grozdanić N, Radović I, Kijevčanin M. Eksperimentalno određivanje gustina linalola, alfa-pinena i beta-pinena na visokom pritisku. in Kratki izvodi radova ; Knjiga radova / 57. savetovanje Srpskog hemijskog društva, Kragujevac 18. i 19. juni 2021. = Book of Abstracts ; Proceedings = 57th meeting of the Serbian Chemical Society, Kragujevac, Serbia, June 18-19, 2021. 2021;:121-127.
https://hdl.handle.net/21.15107/rcub_technorep_7398 .

Simić, Zoran, Miletić, Ksenija, Grozdanić, Nikola, Radović, Ivona, Kijevčanin, Mirjana, "Eksperimentalno određivanje gustina linalola, alfa-pinena i beta-pinena na visokom pritisku" in Kratki izvodi radova ; Knjiga radova / 57. savetovanje Srpskog hemijskog društva, Kragujevac 18. i 19. juni 2021. = Book of Abstracts ; Proceedings = 57th meeting of the Serbian Chemical Society, Kragujevac, Serbia, June 18-19, 2021 (2021):121-127,
https://hdl.handle.net/21.15107/rcub_technorep_7398 .

TY  - JOUR
AU  - Simić, Zoran V.
AU  - Kijevčanin, Mirjana Lj.
AU  - Radović, Ivona R.
AU  - Grilc, Miha
AU  - Ivaniš, Gorica R.
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5933
AB  - The limited reserves and well-known disadvantages of using fossil energy sources have increased the need for appropriate renewable substitutes in the production of various chemicals and materials. Biomass has been shown to be worthy of attention since it can be converted to biofuels and value-added chemicals relatively easily. The design of biomass valorisation process requires knowledge on the thermodynamic behaviour of the biomass-derived compounds, such as furfural and furfuryl alcohol. The thermodynamic and transport properties of the binary system furfural + furfuryl alcohol were studied at various temperatures and pressures. Density, speed of sound and refractive index were measured in the temperature range T = (288.15–345.15) K and viscosity was measured at temperatures up to 373.15 K, all at atmospheric pressure. Further, the density of pure components was obtained in the temperature range (293.15–413.15) K for furfural and (293.15–373.15) K for furfuryl alcohol at pressures up to 60.0 MPa. The obtained density values were correlated using the modified Tammann–Tait equation with an average absolute deviation lower than 0.009% for furfural and furfuryl alcohol. The optimised parameters were used for the calculation of the isothermal compressibility, the isobaric thermal expansivity, the internal pressure and the isobaric and isochoric specific heat capacities. The reported data are a valuable source of information for the further application of the investigated compounds.
PB  - MDPI
T2  - Energies
T1  - Thermodynamic and transport properties of biomass-derived furfural, furfuryl alcohol and their mixtures
IS  - 22
SP  - 7769
VL  - 14
DO  - 10.3390/en14227769
ER  - 

@article{
author = "Simić, Zoran V. and Kijevčanin, Mirjana Lj. and Radović, Ivona R. and Grilc, Miha and Ivaniš, Gorica R.",
year = "2021",
abstract = "The limited reserves and well-known disadvantages of using fossil energy sources have increased the need for appropriate renewable substitutes in the production of various chemicals and materials. Biomass has been shown to be worthy of attention since it can be converted to biofuels and value-added chemicals relatively easily. The design of biomass valorisation process requires knowledge on the thermodynamic behaviour of the biomass-derived compounds, such as furfural and furfuryl alcohol. The thermodynamic and transport properties of the binary system furfural + furfuryl alcohol were studied at various temperatures and pressures. Density, speed of sound and refractive index were measured in the temperature range T = (288.15–345.15) K and viscosity was measured at temperatures up to 373.15 K, all at atmospheric pressure. Further, the density of pure components was obtained in the temperature range (293.15–413.15) K for furfural and (293.15–373.15) K for furfuryl alcohol at pressures up to 60.0 MPa. The obtained density values were correlated using the modified Tammann–Tait equation with an average absolute deviation lower than 0.009% for furfural and furfuryl alcohol. The optimised parameters were used for the calculation of the isothermal compressibility, the isobaric thermal expansivity, the internal pressure and the isobaric and isochoric specific heat capacities. The reported data are a valuable source of information for the further application of the investigated compounds.",
publisher = "MDPI",
journal = "Energies",
title = "Thermodynamic and transport properties of biomass-derived furfural, furfuryl alcohol and their mixtures",
number = "22",
pages = "7769",
volume = "14",
doi = "10.3390/en14227769"
}

Simić, Z. V., Kijevčanin, M. Lj., Radović, I. R., Grilc, M.,& Ivaniš, G. R.. (2021). Thermodynamic and transport properties of biomass-derived furfural, furfuryl alcohol and their mixtures. in Energies
MDPI., 14(22), 7769.
https://doi.org/10.3390/en14227769

Simić ZV, Kijevčanin ML, Radović IR, Grilc M, Ivaniš GR. Thermodynamic and transport properties of biomass-derived furfural, furfuryl alcohol and their mixtures. in Energies. 2021;14(22):7769.
doi:10.3390/en14227769 .

Simić, Zoran V., Kijevčanin, Mirjana Lj., Radović, Ivona R., Grilc, Miha, Ivaniš, Gorica R., "Thermodynamic and transport properties of biomass-derived furfural, furfuryl alcohol and their mixtures" in Energies, 14, no. 22 (2021):7769,
https://doi.org/10.3390/en14227769 . .

TY  - CONF
AU  - Simić, Zoran
AU  - Kijevčanin, Mirjana
AU  - Radović, Ivona
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7389
AB  - Zbog globalnog trenda povećanja potrošnje energenata, kao i njihove cene, teži se ka tome da
se ispitaju nove mogućnosti zamene klasičnih energetski zahtevnih separacionih procesa zasnovanih
na isparavanju lakše isparljivih komponenata, na procese separacije zasnovanih na ravnoteži tečnost-tečnost (LLE), odnosno na ekstrakciji komponenata iz tečnih rastvora. Pored toga što bi ovaj
postupak podrazumevao smanjenu upotrebu različitih izvora energije, on bi uključio i zamenu standardnih industrijskih rastvarača sa karakteristikama štetnim po životnu sredinu, novim, zelenim
rastvaračima. U ovom radu biće prikazan način korišćenja ravnoteže tečnost-tečnost na separacione
procese, na primeru ternarnog sitema voda + i-propanol + dimetil adipat, a kroz određivanje binodalnih krivih i ravnotežnih linija na atmosferskom pritisku i temperaturi od 298.15K.
AB  - Due to the global trend of increasing energy consumption, as well as their prices, the aim is to examine the possibilities of replacing energy-intensive classical separation processes based on eva-poration of more volatile components, to separation processes based on liquid-liquid equilibria (LLE), i.e. extraction of components from liquid solutions. Beside that this procedure would involve the reduced use of various energy sources, it would also include the replacement of standard indus-trial solvents with harmful characteristics for the environment, new green solvents. This paper will show the method of using liquid-liquid equilibrium on the example of the ternary system water + i-propanol + dimethyl adipate through the determination of binodal curves and tie lines at atmospheric pressure and temperature of 298.15 K.
PB  - Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), Društvo za procesnu tehniku
C3  - Zbornik radova / 34. Međunarodni kongres o procesnoj industriji, PROCESING '21, 3. i 4. jun 2021, Novi Sad
T1  - Primena ravnoteže tečnost-tečnost ternarnih vodenih rastvora u separacionim procesima
T1  - Liquid-liquid equilibrium of the ternary water solutions system in separation processes
EP  - 144
SP  - 141
UR  - https://hdl.handle.net/21.15107/rcub_technorep_7389
ER  - 

@conference{
author = "Simić, Zoran and Kijevčanin, Mirjana and Radović, Ivona",
year = "2021",
abstract = "Zbog globalnog trenda povećanja potrošnje energenata, kao i njihove cene, teži se ka tome da
se ispitaju nove mogućnosti zamene klasičnih energetski zahtevnih separacionih procesa zasnovanih
na isparavanju lakše isparljivih komponenata, na procese separacije zasnovanih na ravnoteži tečnost-tečnost (LLE), odnosno na ekstrakciji komponenata iz tečnih rastvora. Pored toga što bi ovaj
postupak podrazumevao smanjenu upotrebu različitih izvora energije, on bi uključio i zamenu standardnih industrijskih rastvarača sa karakteristikama štetnim po životnu sredinu, novim, zelenim
rastvaračima. U ovom radu biće prikazan način korišćenja ravnoteže tečnost-tečnost na separacione
procese, na primeru ternarnog sitema voda + i-propanol + dimetil adipat, a kroz određivanje binodalnih krivih i ravnotežnih linija na atmosferskom pritisku i temperaturi od 298.15K., Due to the global trend of increasing energy consumption, as well as their prices, the aim is to examine the possibilities of replacing energy-intensive classical separation processes based on eva-poration of more volatile components, to separation processes based on liquid-liquid equilibria (LLE), i.e. extraction of components from liquid solutions. Beside that this procedure would involve the reduced use of various energy sources, it would also include the replacement of standard indus-trial solvents with harmful characteristics for the environment, new green solvents. This paper will show the method of using liquid-liquid equilibrium on the example of the ternary system water + i-propanol + dimethyl adipate through the determination of binodal curves and tie lines at atmospheric pressure and temperature of 298.15 K.",
publisher = "Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), Društvo za procesnu tehniku",
journal = "Zbornik radova / 34. Međunarodni kongres o procesnoj industriji, PROCESING '21, 3. i 4. jun 2021, Novi Sad",
title = "Primena ravnoteže tečnost-tečnost ternarnih vodenih rastvora u separacionim procesima, Liquid-liquid equilibrium of the ternary water solutions system in separation processes",
pages = "144-141",
url = "https://hdl.handle.net/21.15107/rcub_technorep_7389"
}

Simić, Z., Kijevčanin, M.,& Radović, I.. (2021). Primena ravnoteže tečnost-tečnost ternarnih vodenih rastvora u separacionim procesima. in Zbornik radova / 34. Međunarodni kongres o procesnoj industriji, PROCESING '21, 3. i 4. jun 2021, Novi Sad
Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), Društvo za procesnu tehniku., 141-144.
https://hdl.handle.net/21.15107/rcub_technorep_7389

Simić Z, Kijevčanin M, Radović I. Primena ravnoteže tečnost-tečnost ternarnih vodenih rastvora u separacionim procesima. in Zbornik radova / 34. Međunarodni kongres o procesnoj industriji, PROCESING '21, 3. i 4. jun 2021, Novi Sad. 2021;:141-144.
https://hdl.handle.net/21.15107/rcub_technorep_7389 .

Simić, Zoran, Kijevčanin, Mirjana, Radović, Ivona, "Primena ravnoteže tečnost-tečnost ternarnih vodenih rastvora u separacionim procesima" in Zbornik radova / 34. Međunarodni kongres o procesnoj industriji, PROCESING '21, 3. i 4. jun 2021, Novi Sad (2021):141-144,
https://hdl.handle.net/21.15107/rcub_technorep_7389 .

TY  - JOUR
AU  - Ilic-Pajic, Jovana
AU  - Radović, Ivona
AU  - Grozdanić, Nikola
AU  - Stajic-Trosic, Jasna
AU  - Kijevčanin, Mirjana
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4809
AB  - An experimental analysis of density, refractive index, speed of sound and the viscosity at atmospheric pressure and temperatures T = (288.15 to 323.15) K has been carried out for the three binary systems, i.e. (p-cymene + alpha-pinene), (p-cymene + limonene) and (p-cymene + citral). Excess molar volumes, viscosity deviations, deviations in isentropic compressibility and excess Gibbs free energy of activation of viscous flow were calculated from experimental data. The results were fitted employing Redlich-Kister polynomial equation. Also, partial molar volumes, excess partial molar volumes and partial molar volumes at infinite dilutions were calculated to elucidate the non-ideal behavior of investigated mixtures. Furthermore, Prigogine-Flory-Patterson (PFP) model was successfully applied for the correlation of excess molar volumes of examined binary mixtures. The results of excess molar volume correlations show very good agreement with experimental measurement.
T2  - Journal of Molecular Liquids
T1  - Volumetric and thermodynamic properties of binary mixtures of p-cymene with alpha-pinene, limonene and citral at atmospheric pressure and temperatures up to 323.15 K
VL  - 344
DO  - 10.1016/j.molliq.2021.117486
ER  - 

@article{
author = "Ilic-Pajic, Jovana and Radović, Ivona and Grozdanić, Nikola and Stajic-Trosic, Jasna and Kijevčanin, Mirjana",
year = "2021",
abstract = "An experimental analysis of density, refractive index, speed of sound and the viscosity at atmospheric pressure and temperatures T = (288.15 to 323.15) K has been carried out for the three binary systems, i.e. (p-cymene + alpha-pinene), (p-cymene + limonene) and (p-cymene + citral). Excess molar volumes, viscosity deviations, deviations in isentropic compressibility and excess Gibbs free energy of activation of viscous flow were calculated from experimental data. The results were fitted employing Redlich-Kister polynomial equation. Also, partial molar volumes, excess partial molar volumes and partial molar volumes at infinite dilutions were calculated to elucidate the non-ideal behavior of investigated mixtures. Furthermore, Prigogine-Flory-Patterson (PFP) model was successfully applied for the correlation of excess molar volumes of examined binary mixtures. The results of excess molar volume correlations show very good agreement with experimental measurement.",
journal = "Journal of Molecular Liquids",
title = "Volumetric and thermodynamic properties of binary mixtures of p-cymene with alpha-pinene, limonene and citral at atmospheric pressure and temperatures up to 323.15 K",
volume = "344",
doi = "10.1016/j.molliq.2021.117486"
}

Ilic-Pajic, J., Radović, I., Grozdanić, N., Stajic-Trosic, J.,& Kijevčanin, M.. (2021). Volumetric and thermodynamic properties of binary mixtures of p-cymene with alpha-pinene, limonene and citral at atmospheric pressure and temperatures up to 323.15 K. in Journal of Molecular Liquids, 344.
https://doi.org/10.1016/j.molliq.2021.117486

Ilic-Pajic J, Radović I, Grozdanić N, Stajic-Trosic J, Kijevčanin M. Volumetric and thermodynamic properties of binary mixtures of p-cymene with alpha-pinene, limonene and citral at atmospheric pressure and temperatures up to 323.15 K. in Journal of Molecular Liquids. 2021;344.
doi:10.1016/j.molliq.2021.117486 .

Ilic-Pajic, Jovana, Radović, Ivona, Grozdanić, Nikola, Stajic-Trosic, Jasna, Kijevčanin, Mirjana, "Volumetric and thermodynamic properties of binary mixtures of p-cymene with alpha-pinene, limonene and citral at atmospheric pressure and temperatures up to 323.15 K" in Journal of Molecular Liquids, 344 (2021),
https://doi.org/10.1016/j.molliq.2021.117486 . .

TY  - JOUR
AU  - Grozdanić, Nikola
AU  - Radović, Ivona
AU  - Knezevic-Stevanovic, Andjela
AU  - Kijevčanin, Mirjana
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4820
AB  - In this work, experimental densities data of the binary system tetrahydrofuran + 2-butanol have been determined at eight temperatures, T=(288.15-323.15) K and atmospheric pressure and used for excess molar volume calculations. Also, partial molar volumes, excess partial molar volumes and partial molar volumes at infinite dilutions were calculated for further non-ideal behaviour of binary mixture. Excess molar volume, V-E, of experimental determined system tetrahydrofuran + 2-butanol, and four previously published binary systems, tetrahydrofuran + 1-butanol, dimethyl adipate + 1-butanol, dimethyl adipate + 2-butanol and dimethyl adipate + tetrahydrofuran were correlated with two models, Prigogine-Flory-Patterson (PFP) and Extended Real Association Solution (ERAS). In order to apply the proposed models additional data of ultrasonic speed of sounds for pure components, dimethyl adipate, tetrahydrofuran, 1-butanol and 2-butanol, were measured in the temperature range T=(288.15-323.15) K and at atmospheric pressure. Volumetric coefficients, thermal expansion coefficient alpha and isothermal compressibility kappa were calculated from density, ultrasonic speed of sound and isobaric heat capacity data. Isobaric molar heat capacities C-p,C-m at all temperatures for all pure components were obtained by correlation of literature data. Both models, PFP and ERAS were used for analysis of molecular interactions present in the investigated solutions.
T2  - Journal of Molecular Liquids
T1  - Volumetric properties of binary mixtures of tetrahydrofuran, dimethyl adipate, 1-butanol and 2-butanol from (288.15 to 323.15) K and modeling by Prigogine-Flory-Patterson (PFP) and Extended Real Association Solution (ERAS) models
VL  - 340
DO  - 10.1016/j.molliq.2021.117313
ER  - 

@article{
author = "Grozdanić, Nikola and Radović, Ivona and Knezevic-Stevanovic, Andjela and Kijevčanin, Mirjana",
year = "2021",
abstract = "In this work, experimental densities data of the binary system tetrahydrofuran + 2-butanol have been determined at eight temperatures, T=(288.15-323.15) K and atmospheric pressure and used for excess molar volume calculations. Also, partial molar volumes, excess partial molar volumes and partial molar volumes at infinite dilutions were calculated for further non-ideal behaviour of binary mixture. Excess molar volume, V-E, of experimental determined system tetrahydrofuran + 2-butanol, and four previously published binary systems, tetrahydrofuran + 1-butanol, dimethyl adipate + 1-butanol, dimethyl adipate + 2-butanol and dimethyl adipate + tetrahydrofuran were correlated with two models, Prigogine-Flory-Patterson (PFP) and Extended Real Association Solution (ERAS). In order to apply the proposed models additional data of ultrasonic speed of sounds for pure components, dimethyl adipate, tetrahydrofuran, 1-butanol and 2-butanol, were measured in the temperature range T=(288.15-323.15) K and at atmospheric pressure. Volumetric coefficients, thermal expansion coefficient alpha and isothermal compressibility kappa were calculated from density, ultrasonic speed of sound and isobaric heat capacity data. Isobaric molar heat capacities C-p,C-m at all temperatures for all pure components were obtained by correlation of literature data. Both models, PFP and ERAS were used for analysis of molecular interactions present in the investigated solutions.",
journal = "Journal of Molecular Liquids",
title = "Volumetric properties of binary mixtures of tetrahydrofuran, dimethyl adipate, 1-butanol and 2-butanol from (288.15 to 323.15) K and modeling by Prigogine-Flory-Patterson (PFP) and Extended Real Association Solution (ERAS) models",
volume = "340",
doi = "10.1016/j.molliq.2021.117313"
}

Grozdanić, N., Radović, I., Knezevic-Stevanovic, A.,& Kijevčanin, M.. (2021). Volumetric properties of binary mixtures of tetrahydrofuran, dimethyl adipate, 1-butanol and 2-butanol from (288.15 to 323.15) K and modeling by Prigogine-Flory-Patterson (PFP) and Extended Real Association Solution (ERAS) models. in Journal of Molecular Liquids, 340.
https://doi.org/10.1016/j.molliq.2021.117313

Grozdanić N, Radović I, Knezevic-Stevanovic A, Kijevčanin M. Volumetric properties of binary mixtures of tetrahydrofuran, dimethyl adipate, 1-butanol and 2-butanol from (288.15 to 323.15) K and modeling by Prigogine-Flory-Patterson (PFP) and Extended Real Association Solution (ERAS) models. in Journal of Molecular Liquids. 2021;340.
doi:10.1016/j.molliq.2021.117313 .

Grozdanić, Nikola, Radović, Ivona, Knezevic-Stevanovic, Andjela, Kijevčanin, Mirjana, "Volumetric properties of binary mixtures of tetrahydrofuran, dimethyl adipate, 1-butanol and 2-butanol from (288.15 to 323.15) K and modeling by Prigogine-Flory-Patterson (PFP) and Extended Real Association Solution (ERAS) models" in Journal of Molecular Liquids, 340 (2021),
https://doi.org/10.1016/j.molliq.2021.117313 . .

TY  - JOUR
AU  - Sas, Olalla G.
AU  - Ivaniš, Gorica
AU  - Kijevčanin, Mirjana
AU  - Gonzalez, Begona
AU  - Dominguez, Angeles
AU  - Radović, Ivona
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4856
AB  - Densities of four Deep Eutectic Solvents (DESs) based on menthol and organic acids (menthol:octanoic acid (1:1), menthol:decanoic acid (1:1), menthol:dodecanoic acid (2:1) and decanoic acid:octanoic acid (1:3)) were measured at high pressures (0.1 to 60) MPa and several temperatures (293.15 to 413.15) K. Tammann-Tait equation was used to model the experimental density data; the average absolute percentage deviations between calculated and experimental data were less or equal 0.012 %. The influence of the temperature and pressure on the derived volumetric properties: isothermal compressibility (k(T)), isobaric thermal expansivity (alpha(p)), internal pressure (p(int)) and difference between heat capacity at constant pressure (c(p)) and constant volume (c(v)) was analysed. Considering the experimental results, it is possible to observe that deep eutectic solvent formed by linear organic acids presents higher density values than those formed by menthol, being the densest the solvent formed by dodecanoic and octanoic acid. Attending to the derived volumetric properties in general, isothermal compressibility and isobaric thermal expansivity increase as temperature increases and decrease with pressure for all studied systems, being the octanoic acid based DESs slightly more compressible than the other studied DESs.
T2  - Journal of Chemical Thermodynamics
T1  - High pressure densities and derived thermodynamic properties of deep eutectic solvents with menthol and saturated fatty acids
VL  - 162
DO  - 10.1016/j.jct.2021.106578
ER  - 

@article{
author = "Sas, Olalla G. and Ivaniš, Gorica and Kijevčanin, Mirjana and Gonzalez, Begona and Dominguez, Angeles and Radović, Ivona",
year = "2021",
abstract = "Densities of four Deep Eutectic Solvents (DESs) based on menthol and organic acids (menthol:octanoic acid (1:1), menthol:decanoic acid (1:1), menthol:dodecanoic acid (2:1) and decanoic acid:octanoic acid (1:3)) were measured at high pressures (0.1 to 60) MPa and several temperatures (293.15 to 413.15) K. Tammann-Tait equation was used to model the experimental density data; the average absolute percentage deviations between calculated and experimental data were less or equal 0.012 %. The influence of the temperature and pressure on the derived volumetric properties: isothermal compressibility (k(T)), isobaric thermal expansivity (alpha(p)), internal pressure (p(int)) and difference between heat capacity at constant pressure (c(p)) and constant volume (c(v)) was analysed. Considering the experimental results, it is possible to observe that deep eutectic solvent formed by linear organic acids presents higher density values than those formed by menthol, being the densest the solvent formed by dodecanoic and octanoic acid. Attending to the derived volumetric properties in general, isothermal compressibility and isobaric thermal expansivity increase as temperature increases and decrease with pressure for all studied systems, being the octanoic acid based DESs slightly more compressible than the other studied DESs.",
journal = "Journal of Chemical Thermodynamics",
title = "High pressure densities and derived thermodynamic properties of deep eutectic solvents with menthol and saturated fatty acids",
volume = "162",
doi = "10.1016/j.jct.2021.106578"
}

Sas, O. G., Ivaniš, G., Kijevčanin, M., Gonzalez, B., Dominguez, A.,& Radović, I.. (2021). High pressure densities and derived thermodynamic properties of deep eutectic solvents with menthol and saturated fatty acids. in Journal of Chemical Thermodynamics, 162.
https://doi.org/10.1016/j.jct.2021.106578

Sas OG, Ivaniš G, Kijevčanin M, Gonzalez B, Dominguez A, Radović I. High pressure densities and derived thermodynamic properties of deep eutectic solvents with menthol and saturated fatty acids. in Journal of Chemical Thermodynamics. 2021;162.
doi:10.1016/j.jct.2021.106578 .

Sas, Olalla G., Ivaniš, Gorica, Kijevčanin, Mirjana, Gonzalez, Begona, Dominguez, Angeles, Radović, Ivona, "High pressure densities and derived thermodynamic properties of deep eutectic solvents with menthol and saturated fatty acids" in Journal of Chemical Thermodynamics, 162 (2021),
https://doi.org/10.1016/j.jct.2021.106578 . .

TY  - JOUR
AU  - Ivanovic, Marija
AU  - Nenadovic, Snezana
AU  - Pavlovic, Vera P.
AU  - Radović, Ivona
AU  - Kijevčanin, Mirjana
AU  - Pavlović, Vladimir B.
AU  - Kljajevic, Ljiljana
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4869
AB  - Thermodynamic parameters (densities, viscosities, speed of sound, and refractive index) of four series of alkaline activators were determined over the temperature range from 15 to 60 degrees C for the process of geopolymerization. Mixtures of Na2SiO3 and NaOH of different molar concentrations ( from 2M to 8M with step 2) were used as an alkaline activator. The sample with the highest NaOH concentration also shows the highest values of all thermodynamic parameters. Metakaolin, obtained by calcination of kaolin at 750 degrees C, was used as the starting material. The samples were characterized by X-ray diffraction (XRD), FTIR and Raman spectroscopy, Scanning Electron Microscopy (SEM), and Energy-Dispersive X-Ray (EDX) Spectroscopy. Results of FTIR analysis correlated with results of Raman Spectroscopy. Due to the polymerization process, the changes in the phonon spectrum were confirmed. The different concentrations of activators do not notably change the Si/Al ratio.
T2  - Macedonian Journal of Chemistry and Chemical Engineering
T1  - The influence of thermodynamic parameters on alkaline activators of geopolymers and the structure of geopolymers
EP  - 117
IS  - 1
SP  - 107
VL  - 40
DO  - 10.20450/mjcce.2021.2127
ER  - 

@article{
author = "Ivanovic, Marija and Nenadovic, Snezana and Pavlovic, Vera P. and Radović, Ivona and Kijevčanin, Mirjana and Pavlović, Vladimir B. and Kljajevic, Ljiljana",
year = "2021",
abstract = "Thermodynamic parameters (densities, viscosities, speed of sound, and refractive index) of four series of alkaline activators were determined over the temperature range from 15 to 60 degrees C for the process of geopolymerization. Mixtures of Na2SiO3 and NaOH of different molar concentrations ( from 2M to 8M with step 2) were used as an alkaline activator. The sample with the highest NaOH concentration also shows the highest values of all thermodynamic parameters. Metakaolin, obtained by calcination of kaolin at 750 degrees C, was used as the starting material. The samples were characterized by X-ray diffraction (XRD), FTIR and Raman spectroscopy, Scanning Electron Microscopy (SEM), and Energy-Dispersive X-Ray (EDX) Spectroscopy. Results of FTIR analysis correlated with results of Raman Spectroscopy. Due to the polymerization process, the changes in the phonon spectrum were confirmed. The different concentrations of activators do not notably change the Si/Al ratio.",
journal = "Macedonian Journal of Chemistry and Chemical Engineering",
title = "The influence of thermodynamic parameters on alkaline activators of geopolymers and the structure of geopolymers",
pages = "117-107",
number = "1",
volume = "40",
doi = "10.20450/mjcce.2021.2127"
}

Ivanovic, M., Nenadovic, S., Pavlovic, V. P., Radović, I., Kijevčanin, M., Pavlović, V. B.,& Kljajevic, L.. (2021). The influence of thermodynamic parameters on alkaline activators of geopolymers and the structure of geopolymers. in Macedonian Journal of Chemistry and Chemical Engineering, 40(1), 107-117.
https://doi.org/10.20450/mjcce.2021.2127

Ivanovic M, Nenadovic S, Pavlovic VP, Radović I, Kijevčanin M, Pavlović VB, Kljajevic L. The influence of thermodynamic parameters on alkaline activators of geopolymers and the structure of geopolymers. in Macedonian Journal of Chemistry and Chemical Engineering. 2021;40(1):107-117.
doi:10.20450/mjcce.2021.2127 .

Ivanovic, Marija, Nenadovic, Snezana, Pavlovic, Vera P., Radović, Ivona, Kijevčanin, Mirjana, Pavlović, Vladimir B., Kljajevic, Ljiljana, "The influence of thermodynamic parameters on alkaline activators of geopolymers and the structure of geopolymers" in Macedonian Journal of Chemistry and Chemical Engineering, 40, no. 1 (2021):107-117,
https://doi.org/10.20450/mjcce.2021.2127 . .

TY  - JOUR
AU  - Vranes, Milan
AU  - Radović, Ivona
AU  - Bikic, Sinisa
AU  - Tot, Aleksandar
AU  - Kijevčanin, Mirjana
AU  - Zarić, Danica
AU  - Borovic, Teona Teodora
AU  - Papovic, Snezana
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4930
AB  - In this article, detailed physicochemical characterization of ethylene glycol and caffeine + ethylene glycol mixtures is performed based on density, viscosity and refractive indices measurements in temperature range from (288.15 to 343.15) K. The apparent molar volume (V-phi) arent molar volume at infinite dilution (V-phi(o)), Masson's experimental slope (S-nu), limiting apparent molar expansibility, (E-phi(o)), viscosity B-coefficient, thermodynamical parameters of viscous flow and molar refractions (R-m) have been evaluated from experimental measurements and results are additionally proven by molecular dynamic simulations. The addition of caffeine reduces viscosity of ethylene glycol, while caffeine molecules have high tendency to form self-aggregates due to weak interactions with ethylene glycol. Compared to aqueous solution of caffeine, caffeine + ethylene glycol mixtures are characterized with significantly lower solvation number and with more pronounced caffeine self-aggregation.
T2  - Journal of Molecular Liquids
T1  - Improving ethylene glycol transport properties by caffeine - Thermodynamic and computational evidence
VL  - 333
DO  - 10.1016/j.molliq.2021.115918
ER  - 

@article{
author = "Vranes, Milan and Radović, Ivona and Bikic, Sinisa and Tot, Aleksandar and Kijevčanin, Mirjana and Zarić, Danica and Borovic, Teona Teodora and Papovic, Snezana",
year = "2021",
abstract = "In this article, detailed physicochemical characterization of ethylene glycol and caffeine + ethylene glycol mixtures is performed based on density, viscosity and refractive indices measurements in temperature range from (288.15 to 343.15) K. The apparent molar volume (V-phi) arent molar volume at infinite dilution (V-phi(o)), Masson's experimental slope (S-nu), limiting apparent molar expansibility, (E-phi(o)), viscosity B-coefficient, thermodynamical parameters of viscous flow and molar refractions (R-m) have been evaluated from experimental measurements and results are additionally proven by molecular dynamic simulations. The addition of caffeine reduces viscosity of ethylene glycol, while caffeine molecules have high tendency to form self-aggregates due to weak interactions with ethylene glycol. Compared to aqueous solution of caffeine, caffeine + ethylene glycol mixtures are characterized with significantly lower solvation number and with more pronounced caffeine self-aggregation.",
journal = "Journal of Molecular Liquids",
title = "Improving ethylene glycol transport properties by caffeine - Thermodynamic and computational evidence",
volume = "333",
doi = "10.1016/j.molliq.2021.115918"
}

Vranes, M., Radović, I., Bikic, S., Tot, A., Kijevčanin, M., Zarić, D., Borovic, T. T.,& Papovic, S.. (2021). Improving ethylene glycol transport properties by caffeine - Thermodynamic and computational evidence. in Journal of Molecular Liquids, 333.
https://doi.org/10.1016/j.molliq.2021.115918

Vranes M, Radović I, Bikic S, Tot A, Kijevčanin M, Zarić D, Borovic TT, Papovic S. Improving ethylene glycol transport properties by caffeine - Thermodynamic and computational evidence. in Journal of Molecular Liquids. 2021;333.
doi:10.1016/j.molliq.2021.115918 .

Vranes, Milan, Radović, Ivona, Bikic, Sinisa, Tot, Aleksandar, Kijevčanin, Mirjana, Zarić, Danica, Borovic, Teona Teodora, Papovic, Snezana, "Improving ethylene glycol transport properties by caffeine - Thermodynamic and computational evidence" in Journal of Molecular Liquids, 333 (2021),
https://doi.org/10.1016/j.molliq.2021.115918 . .

TY  - JOUR
AU  - Ivanović, Marija
AU  - Nenadović, Snežana S.
AU  - Pavlović, Vera P.
AU  - Radović, Ivona R.
AU  - Kijevčanin, Mirjana Lj.
AU  - Pavlović, Vladimir B.
AU  - Kljajević, Ljiljana M.
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5121
AB  - Thermodynamic parameters (densities, viscosities, speed of sound, and refractive index) of four series of alkaline activators were determined over the temperature range from 15 to 60 °C for the process of geopolymerization. Mixtures of Na2SiO3and NaOH of different molar concentrations (from 2M to 8M with step 2) were used as an alkaline activator. The sample with the highest NaOH concentrationalso shows the highest values of all thermodynamic parameters.Metakaolin, obtained by calcination of kaolin at 750 °C, was used as the starting material.The samples were characterized by X-ray diffraction (XRD),FTIR and Raman spectroscopy, Scanning Electron Microscopy (SEM), and Energy-Dispersive X-Ray (EDX) Spectroscopy. Results of FTIR analysis correlated with results of Raman Spectroscopy. Due to the polymerization process, the changes in the phonon spectrum were confirmed. The different concentra-tions of activators do not notably change the Si/Al ratio.
T2  - Macedonian Journal of Chemistry and Chemical Engineering
T1  - The influence of thermodynamic parameters on alkaline activator of geopolymers and structure of geopolymers
IS  - 1
SP  - 99
VL  - 40
DO  - 10.20450/mjcce.2021.2127
ER  - 

@article{
author = "Ivanović, Marija and Nenadović, Snežana S. and Pavlović, Vera P. and Radović, Ivona R. and Kijevčanin, Mirjana Lj. and Pavlović, Vladimir B. and Kljajević, Ljiljana M.",
year = "2021",
abstract = "Thermodynamic parameters (densities, viscosities, speed of sound, and refractive index) of four series of alkaline activators were determined over the temperature range from 15 to 60 °C for the process of geopolymerization. Mixtures of Na2SiO3and NaOH of different molar concentrations (from 2M to 8M with step 2) were used as an alkaline activator. The sample with the highest NaOH concentrationalso shows the highest values of all thermodynamic parameters.Metakaolin, obtained by calcination of kaolin at 750 °C, was used as the starting material.The samples were characterized by X-ray diffraction (XRD),FTIR and Raman spectroscopy, Scanning Electron Microscopy (SEM), and Energy-Dispersive X-Ray (EDX) Spectroscopy. Results of FTIR analysis correlated with results of Raman Spectroscopy. Due to the polymerization process, the changes in the phonon spectrum were confirmed. The different concentra-tions of activators do not notably change the Si/Al ratio.",
journal = "Macedonian Journal of Chemistry and Chemical Engineering",
title = "The influence of thermodynamic parameters on alkaline activator of geopolymers and structure of geopolymers",
number = "1",
pages = "99",
volume = "40",
doi = "10.20450/mjcce.2021.2127"
}

Ivanović, M., Nenadović, S. S., Pavlović, V. P., Radović, I. R., Kijevčanin, M. Lj., Pavlović, V. B.,& Kljajević, L. M.. (2021). The influence of thermodynamic parameters on alkaline activator of geopolymers and structure of geopolymers. in Macedonian Journal of Chemistry and Chemical Engineering, 40(1), 99.
https://doi.org/10.20450/mjcce.2021.2127

Ivanović M, Nenadović SS, Pavlović VP, Radović IR, Kijevčanin ML, Pavlović VB, Kljajević LM. The influence of thermodynamic parameters on alkaline activator of geopolymers and structure of geopolymers. in Macedonian Journal of Chemistry and Chemical Engineering. 2021;40(1):99.
doi:10.20450/mjcce.2021.2127 .

Ivanović, Marija, Nenadović, Snežana S., Pavlović, Vera P., Radović, Ivona R., Kijevčanin, Mirjana Lj., Pavlović, Vladimir B., Kljajević, Ljiljana M., "The influence of thermodynamic parameters on alkaline activator of geopolymers and structure of geopolymers" in Macedonian Journal of Chemistry and Chemical Engineering, 40, no. 1 (2021):99,
https://doi.org/10.20450/mjcce.2021.2127 . .