Petrović, Rada

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Authority KeyName Variants
orcid::0000-0001-9511-5633
  • Petrović, Rada (128)
  • Petrović, Rada D. (2)
  • Petrović, Rada P. (1)
Projects
Synthesis, processing and applications of nanostructured multifunctional materials with defined properties Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200135 (University of Belgrade, Faculty of Technology and Metallurgy)
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200287 (Innovation Center of the Faculty of Technology and Metallurgy) Sinteza, struktura, svojstva i primena funkcionalnih nanostrukturnih keramičkih i biokeramičkih materijala
Reinforcing of Nanotechnology and Functional Materials Centre UEFISCDI [304/2011]
EUREKA E!4141 EUREKA E!3033 Bionanocomposite
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) Geopolymers - technology for converting the industrial waste into functional materials
Development and Application of Methods and Materials for Monitoring New Organic Contaminants, Toxic Compounds and Heavy Metals Functional, Functionalized and Advanced Nanomaterials
Synthesis, processing and characterization of nanostructured materials for application in the field of energy, mechanical engineering, environmental protection and biomedicine Industry production of lead and zinc, consequences for population and protection and regulation of ecosystems
CERIC-ERIC [20177018] COST ActionEuropean Cooperation in Science and Technology (COST) [TU 1301]
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200129 (University of Belgrade, Faculty of Dental Medicine) Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200175 (Institute of Technical Sciences of SASA, Belgrade)
Ministry of Education and Science of the Republic of Latvia [EUREKA E! 3033] Office of Science, Office of Basic Energy Sciences, of the U.S. Department of EnergyUnited States Department of Energy (DOE) [DE-AC02-05CH11231]
Structure Fund Project [CZ.02.1.01/0.0/0.0/16_013/0001788] U.S. Department of EnergyUnited States Department of Energy (DOE) [DE-AC02-05CH11231]
CERIC-ERIC Consortium [20152050] Core ProgrammeLuxembourg National Research Fund [PN09-45010]
Czech Ministry of EducationMinistry of Education, Youth & Sports - Czech Republic [LM2015057] Czech Ministry of Education, Youth and SportsMinistry of Education, Youth & Sports - Czech Republic [LG15050]
EUREKA E! 13305-INSOLT-CHR EUREKA E [3033]
EUREKA Project [4141] European Union’s Horizon 2020 research and innovation program under the grant agreement no. 952033 (“Twinning to excel materials engineering for medical devices – ExcellMater”)

Author's Bibliography

The current trend in innovative bioactive materials for dental and orthopedic applications

Veljović, Đorđe; Janaćković, Đorđe; Petrović, Rada; Radovanović, Željko; Ugrinović, Vukašin; Matić, Tamara; Milivojević, Marija

(Savez hemijskih inženjera Srbije, 2024)

TY  - CONF
AU  - Veljović, Đorđe
AU  - Janaćković, Đorđe
AU  - Petrović, Rada
AU  - Radovanović, Željko
AU  - Ugrinović, Vukašin
AU  - Matić, Tamara
AU  - Milivojević, Marija
PY  - 2024
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7439
AB  - Bioactive  materials  for  the repairand  regeneration  of human bone  tissue,  as  well  as  for  the restoration  of  teeth,  are  the focus of  numerous  studies  in  the  field  of  biomaterials.Orthopaedic  surgeons  anticipate that  bioactive materialshave  the  potential  to  facilitate  the  formation  of  new  apatite-like  crystals  upon  contact  with body fluids, promoting the development of new bone tissue under in vivoconditions. On the other hand, dentists expect that bioactive  materials  have  the  potential  for  remineralization  of  partially  demineralized  enamel  and  dentin. In  the preceding years, the Bioceramic Materials Group, founded within the Department of Inorganic Chemical Technology at the  Faculty  of  Technology  and  Metallurgy,  University  of  Belgrade (FTM-UB),  conducted  extensive  research  on  the advancement of bioactive and biocompatible materials with adequate mechanical properties, designed for applicationin dentistry, orthopaedics, maxillofacial surgery, and also bone tissue engineering(BTE).
PB  - Savez hemijskih inženjera Srbije
C3  - Hemijska industrija
T1  - The current trend in innovative bioactive materials for dental and orthopedic applications
IS  - 1S
SP  - 37
VL  - 78
UR  - https://hdl.handle.net/21.15107/rcub_technorep_7439
ER  - 
@conference{
author = "Veljović, Đorđe and Janaćković, Đorđe and Petrović, Rada and Radovanović, Željko and Ugrinović, Vukašin and Matić, Tamara and Milivojević, Marija",
year = "2024",
abstract = "Bioactive  materials  for  the repairand  regeneration  of human bone  tissue,  as  well  as  for  the restoration  of  teeth,  are  the focus of  numerous  studies  in  the  field  of  biomaterials.Orthopaedic  surgeons  anticipate that  bioactive materialshave  the  potential  to  facilitate  the  formation  of  new  apatite-like  crystals  upon  contact  with body fluids, promoting the development of new bone tissue under in vivoconditions. On the other hand, dentists expect that bioactive  materials  have  the  potential  for  remineralization  of  partially  demineralized  enamel  and  dentin. In  the preceding years, the Bioceramic Materials Group, founded within the Department of Inorganic Chemical Technology at the  Faculty  of  Technology  and  Metallurgy,  University  of  Belgrade (FTM-UB),  conducted  extensive  research  on  the advancement of bioactive and biocompatible materials with adequate mechanical properties, designed for applicationin dentistry, orthopaedics, maxillofacial surgery, and also bone tissue engineering(BTE).",
publisher = "Savez hemijskih inženjera Srbije",
journal = "Hemijska industrija",
title = "The current trend in innovative bioactive materials for dental and orthopedic applications",
number = "1S",
pages = "37",
volume = "78",
url = "https://hdl.handle.net/21.15107/rcub_technorep_7439"
}
Veljović, Đ., Janaćković, Đ., Petrović, R., Radovanović, Ž., Ugrinović, V., Matić, T.,& Milivojević, M.. (2024). The current trend in innovative bioactive materials for dental and orthopedic applications. in Hemijska industrija
Savez hemijskih inženjera Srbije., 78(1S), 37.
https://hdl.handle.net/21.15107/rcub_technorep_7439
Veljović Đ, Janaćković Đ, Petrović R, Radovanović Ž, Ugrinović V, Matić T, Milivojević M. The current trend in innovative bioactive materials for dental and orthopedic applications. in Hemijska industrija. 2024;78(1S):37.
https://hdl.handle.net/21.15107/rcub_technorep_7439 .
Veljović, Đorđe, Janaćković, Đorđe, Petrović, Rada, Radovanović, Željko, Ugrinović, Vukašin, Matić, Tamara, Milivojević, Marija, "The current trend in innovative bioactive materials for dental and orthopedic applications" in Hemijska industrija, 78, no. 1S (2024):37,
https://hdl.handle.net/21.15107/rcub_technorep_7439 .

An inverse gas chromatography study of the adsorption of organics on zeolite and zeolite/iron oxyhydroxide composite at the infinite and finite surface coverage

Lazarević, Slavica S.; Mihajlović-Kostić, Marija T.; Janković-Častvan, Ivona M.; Janaćković, Đorđe T.; Petrović, Rada D.

(Serbian Chemical Society, 2024)

TY  - JOUR
AU  - Lazarević, Slavica S.
AU  - Mihajlović-Kostić, Marija T.
AU  - Janković-Častvan, Ivona M.
AU  - Janaćković, Đorđe T.
AU  - Petrović, Rada D.
PY  - 2024
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7434
AB  - The surfaces of natural (NZ) and zeolite/iron oxyhydroxide composite (ZFe) samples were analysed by means of inverse gas chromatography (IGC) using the adsorption data of organic non-polar and polar probes, in the infinite and finite-dilution regimes, in the temperature range 483-513 K. The dispersive components of the free energy of adsorption, γS, determined by the Gray method, decreased with increasing temperature for both zeolites. The specific interactions were characterised by the specific free adsorption energy change, ΔGaS, the specific enthalpy change of adsorption, ΔHaS, as well as the donor and acceptor interaction parameters (KA, KD) and the basic character of the NZ and ZFe was evidenced. The adsorption isotherms of n-hexane, benzene, chloroform and tetrahydrofuran (THF) were determined under finite surface coverage and used to estimate the specific surface area and the adsorption energy distribution. The adsorption capacity of the ZFe was higher than for NZ for all the investigated adsorbates. The specific surface areas and pore size distributions were also determined using nitrogen adsorption-desorption isotherms, i.e., the BET method. It was observed that the nature of the adsorbate and the properties of the solid surface of the initial and modified samples governed the uptake of adsorbates.
AB  - Применом инверзне гасне хроматографије, испитана су површинска својства природног зеолита (NZ) и композита зеолита и гвожђе-оксихидроксида (ZFe), коришћењем поларних и неполарних проба у условима нулте и коначне прекривености у температурном опсегу 483–513 K. Вредности дисперзивне компоненте слободне енергије адсорпције, γS, одређене методом Греја, опадају са порастом температуре за оба зеолита. Одређивањем промене специфичне слободне енергије адсорпције, ΔGa S, и промене специфичне енталпије адсорпције, ΔHa S, које одговарају кисело/базним интеракцијама на чврстој површини, одређени су и акцепторски и донорски параметри (KА и KD) на основу којих је утврђено да су површине узорака NZ и ZFe базног карактера. На основу добијених адсорпционих изотерми за n-хексан, бензен, хлороформ и тетрахидрофуран, применом инверзне гасне хроматографије у условима коначне прекривености, израчунате су вредности специфичне површине као и расподела адсорпционе енергије. Капацитет адсорпције узорка ZFe је био већи у односу на капацитета узорка NZ, за све испитане адсорбенте. Специфична површина узорака као и расподела величине мезопора одређени су применом адсорпионе/десорпционе изотерме за гасовити азот, односно применом BET методе. Закључено је да су природа адсорбата и површинска својства адсорбената главни фактори који одређују капацитет адсорпције.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - An inverse gas chromatography study of the adsorption of organics on zeolite and zeolite/iron oxyhydroxide composite at the infinite and finite surface coverage
T1  - Примена инверзне гасне хроматографије при нултој и коначној прекривености за испитивање адсорпције органских мoлекула на зеолиту и композиту зеолита и гвожђе-оксихидроксида
EP  - 397
IS  - 3
SP  - 383
VL  - 89
DO  - 10.2298/JSC230908093L
ER  - 
@article{
author = "Lazarević, Slavica S. and Mihajlović-Kostić, Marija T. and Janković-Častvan, Ivona M. and Janaćković, Đorđe T. and Petrović, Rada D.",
year = "2024",
abstract = "The surfaces of natural (NZ) and zeolite/iron oxyhydroxide composite (ZFe) samples were analysed by means of inverse gas chromatography (IGC) using the adsorption data of organic non-polar and polar probes, in the infinite and finite-dilution regimes, in the temperature range 483-513 K. The dispersive components of the free energy of adsorption, γS, determined by the Gray method, decreased with increasing temperature for both zeolites. The specific interactions were characterised by the specific free adsorption energy change, ΔGaS, the specific enthalpy change of adsorption, ΔHaS, as well as the donor and acceptor interaction parameters (KA, KD) and the basic character of the NZ and ZFe was evidenced. The adsorption isotherms of n-hexane, benzene, chloroform and tetrahydrofuran (THF) were determined under finite surface coverage and used to estimate the specific surface area and the adsorption energy distribution. The adsorption capacity of the ZFe was higher than for NZ for all the investigated adsorbates. The specific surface areas and pore size distributions were also determined using nitrogen adsorption-desorption isotherms, i.e., the BET method. It was observed that the nature of the adsorbate and the properties of the solid surface of the initial and modified samples governed the uptake of adsorbates., Применом инверзне гасне хроматографије, испитана су површинска својства природног зеолита (NZ) и композита зеолита и гвожђе-оксихидроксида (ZFe), коришћењем поларних и неполарних проба у условима нулте и коначне прекривености у температурном опсегу 483–513 K. Вредности дисперзивне компоненте слободне енергије адсорпције, γS, одређене методом Греја, опадају са порастом температуре за оба зеолита. Одређивањем промене специфичне слободне енергије адсорпције, ΔGa S, и промене специфичне енталпије адсорпције, ΔHa S, које одговарају кисело/базним интеракцијама на чврстој површини, одређени су и акцепторски и донорски параметри (KА и KD) на основу којих је утврђено да су површине узорака NZ и ZFe базног карактера. На основу добијених адсорпционих изотерми за n-хексан, бензен, хлороформ и тетрахидрофуран, применом инверзне гасне хроматографије у условима коначне прекривености, израчунате су вредности специфичне површине као и расподела адсорпционе енергије. Капацитет адсорпције узорка ZFe је био већи у односу на капацитета узорка NZ, за све испитане адсорбенте. Специфична површина узорака као и расподела величине мезопора одређени су применом адсорпионе/десорпционе изотерме за гасовити азот, односно применом BET методе. Закључено је да су природа адсорбата и површинска својства адсорбената главни фактори који одређују капацитет адсорпције.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "An inverse gas chromatography study of the adsorption of organics on zeolite and zeolite/iron oxyhydroxide composite at the infinite and finite surface coverage, Примена инверзне гасне хроматографије при нултој и коначној прекривености за испитивање адсорпције органских мoлекула на зеолиту и композиту зеолита и гвожђе-оксихидроксида",
pages = "397-383",
number = "3",
volume = "89",
doi = "10.2298/JSC230908093L"
}
Lazarević, S. S., Mihajlović-Kostić, M. T., Janković-Častvan, I. M., Janaćković, Đ. T.,& Petrović, R. D.. (2024). An inverse gas chromatography study of the adsorption of organics on zeolite and zeolite/iron oxyhydroxide composite at the infinite and finite surface coverage. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 89(3), 383-397.
https://doi.org/10.2298/JSC230908093L
Lazarević SS, Mihajlović-Kostić MT, Janković-Častvan IM, Janaćković ĐT, Petrović RD. An inverse gas chromatography study of the adsorption of organics on zeolite and zeolite/iron oxyhydroxide composite at the infinite and finite surface coverage. in Journal of the Serbian Chemical Society. 2024;89(3):383-397.
doi:10.2298/JSC230908093L .
Lazarević, Slavica S., Mihajlović-Kostić, Marija T., Janković-Častvan, Ivona M., Janaćković, Đorđe T., Petrović, Rada D., "An inverse gas chromatography study of the adsorption of organics on zeolite and zeolite/iron oxyhydroxide composite at the infinite and finite surface coverage" in Journal of the Serbian Chemical Society, 89, no. 3 (2024):383-397,
https://doi.org/10.2298/JSC230908093L . .

Removal of trivalent chromium from aqueous solutions by natural clays: Valorization of saturated adsorbents as raw materials in ceramic manufacturing

Petrović, Rada; Lazarević, Slavica; Janković-Častvan, Ivona; Matić, Tamara; Milivojević, Marko; Milošević, Dragana; Veljović, Đorđe

(Elsevier, 2023)

TY  - JOUR
AU  - Petrović, Rada
AU  - Lazarević, Slavica
AU  - Janković-Častvan, Ivona
AU  - Matić, Tamara
AU  - Milivojević, Marko
AU  - Milošević, Dragana
AU  - Veljović, Đorđe
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5263
AB  - Kaolinite/illite (KUb) and sepiolite (SEP) clays were used to study Cr(III) adsorption removal from aqueous solutions so that they could be utilized after saturation for ceramic manufacturing. SEP had a larger specific surface area and a higher PZC than KUb. The removal of Cr(III) was evaluated using a batch equilibration procedure at pHi = 4 and pHi = 6. Fast removal kinetics were observed for both clays. Maximum removal capacity was determined by changing the concentration of Cr(III) while keeping the concentration of clay constant and by altering the amount of clay while keeping the concentration of Cr(III) constant. In all situations, SEP had greater capacity than KUb, and capacity was greater for both clays at higher pHi. Not only did the pHi impact the removal capacity and efficiency, but so did the pH during adsorption and the initial concentration of Cr(III). Because of the higher PZC, the pHf for SEP was higher for the same pHi. The higher the pH and Cr(III) concentration, the higher the probability of Cr(OH)3 precipitation and the higher the removal capacity. Dried saturated clays were uniaxially pressed and sintered at 1000 °C for 2 h. The densities of the sintered materials were nearly identical to those of pure clay-based materials, but the compressive strengths were higher, which is significant for the use of saturated clays as raw materials in ceramic manufacturing. Leaching of Cr from SEP-based material was significantly higher than from KUb-based material probably due to the presence of CaCO3 in the SEP.
PB  - Elsevier
T2  - Applied  Clay Sciences
T1  - Removal of trivalent chromium from aqueous solutions by natural clays: Valorization of saturated adsorbents as raw materials in ceramic manufacturing
SP  - 106747
VL  - 231
DO  - 10.1016/j.clay.2022.106747
ER  - 
@article{
author = "Petrović, Rada and Lazarević, Slavica and Janković-Častvan, Ivona and Matić, Tamara and Milivojević, Marko and Milošević, Dragana and Veljović, Đorđe",
year = "2023",
abstract = "Kaolinite/illite (KUb) and sepiolite (SEP) clays were used to study Cr(III) adsorption removal from aqueous solutions so that they could be utilized after saturation for ceramic manufacturing. SEP had a larger specific surface area and a higher PZC than KUb. The removal of Cr(III) was evaluated using a batch equilibration procedure at pHi = 4 and pHi = 6. Fast removal kinetics were observed for both clays. Maximum removal capacity was determined by changing the concentration of Cr(III) while keeping the concentration of clay constant and by altering the amount of clay while keeping the concentration of Cr(III) constant. In all situations, SEP had greater capacity than KUb, and capacity was greater for both clays at higher pHi. Not only did the pHi impact the removal capacity and efficiency, but so did the pH during adsorption and the initial concentration of Cr(III). Because of the higher PZC, the pHf for SEP was higher for the same pHi. The higher the pH and Cr(III) concentration, the higher the probability of Cr(OH)3 precipitation and the higher the removal capacity. Dried saturated clays were uniaxially pressed and sintered at 1000 °C for 2 h. The densities of the sintered materials were nearly identical to those of pure clay-based materials, but the compressive strengths were higher, which is significant for the use of saturated clays as raw materials in ceramic manufacturing. Leaching of Cr from SEP-based material was significantly higher than from KUb-based material probably due to the presence of CaCO3 in the SEP.",
publisher = "Elsevier",
journal = "Applied  Clay Sciences",
title = "Removal of trivalent chromium from aqueous solutions by natural clays: Valorization of saturated adsorbents as raw materials in ceramic manufacturing",
pages = "106747",
volume = "231",
doi = "10.1016/j.clay.2022.106747"
}
Petrović, R., Lazarević, S., Janković-Častvan, I., Matić, T., Milivojević, M., Milošević, D.,& Veljović, Đ.. (2023). Removal of trivalent chromium from aqueous solutions by natural clays: Valorization of saturated adsorbents as raw materials in ceramic manufacturing. in Applied  Clay Sciences
Elsevier., 231, 106747.
https://doi.org/10.1016/j.clay.2022.106747
Petrović R, Lazarević S, Janković-Častvan I, Matić T, Milivojević M, Milošević D, Veljović Đ. Removal of trivalent chromium from aqueous solutions by natural clays: Valorization of saturated adsorbents as raw materials in ceramic manufacturing. in Applied  Clay Sciences. 2023;231:106747.
doi:10.1016/j.clay.2022.106747 .
Petrović, Rada, Lazarević, Slavica, Janković-Častvan, Ivona, Matić, Tamara, Milivojević, Marko, Milošević, Dragana, Veljović, Đorđe, "Removal of trivalent chromium from aqueous solutions by natural clays: Valorization of saturated adsorbents as raw materials in ceramic manufacturing" in Applied  Clay Sciences, 231 (2023):106747,
https://doi.org/10.1016/j.clay.2022.106747 . .
6
4

The Removal of Phosphate from Aqueous Solutions by Sepiolite/ZrO2 Composites: Adsorption Behavior and Mechanism

Milovanović, Željka; Lazarević, Slavica; Janković-Častvan, Ivona; Radovanović, Željko; Cvetković, Slobodan; Janaćković, Đorđe; Petrović, Rada

(MDPI, 2023)

TY  - JOUR
AU  - Milovanović, Željka
AU  - Lazarević, Slavica
AU  - Janković-Častvan, Ivona
AU  - Radovanović, Željko
AU  - Cvetković, Slobodan
AU  - Janaćković, Đorđe
AU  - Petrović, Rada
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6578
AB  - The sepiolite/ZrO2 composites were prepared by sepiolite (Sep) modification with zirconium propoxide in toluene at room temperature for 24 h (Sep–ZrI) or 95 °C for 4 h (sample Sep–ZrII). The efficiency of the obtained composites for the removal of phosphate from aqueous solutions at initial pH = 4 and pH = 8 was investigated. Characterization of the samples shows that synthesis at a higher temperature for a shorter time provides a slightly higher content of amorphous Zr phase, which is deposited on the sepiolite fibers as a thin layer and agglomerated nanoparticles. Compared to Sep, the composites have a lower point of zero charge and higher specific surface area and pore volume. The adsorption kinetics follow the pseudo second-order model. The adsorption capacities of the composites are approximately the same at both initial pH and higher at initial pH = 4 than at pH = 8. The XPS and ATR-FTIR of Sep–ZrI before and after adsorption identifies the formation of inner-sphere complexes as the mechanism of phosphate adsorption. The slow release during desorption with NaOH solution confirms the strong bonds of the phosphates with the surface of the composites.
PB  - MDPI
T2  - Water
T1  - The Removal of Phosphate from Aqueous Solutions by Sepiolite/ZrO2 Composites: Adsorption Behavior and Mechanism
IS  - 13
SP  - 2376
VL  - 15
DO  - 10.3390/w15132376
ER  - 
@article{
author = "Milovanović, Željka and Lazarević, Slavica and Janković-Častvan, Ivona and Radovanović, Željko and Cvetković, Slobodan and Janaćković, Đorđe and Petrović, Rada",
year = "2023",
abstract = "The sepiolite/ZrO2 composites were prepared by sepiolite (Sep) modification with zirconium propoxide in toluene at room temperature for 24 h (Sep–ZrI) or 95 °C for 4 h (sample Sep–ZrII). The efficiency of the obtained composites for the removal of phosphate from aqueous solutions at initial pH = 4 and pH = 8 was investigated. Characterization of the samples shows that synthesis at a higher temperature for a shorter time provides a slightly higher content of amorphous Zr phase, which is deposited on the sepiolite fibers as a thin layer and agglomerated nanoparticles. Compared to Sep, the composites have a lower point of zero charge and higher specific surface area and pore volume. The adsorption kinetics follow the pseudo second-order model. The adsorption capacities of the composites are approximately the same at both initial pH and higher at initial pH = 4 than at pH = 8. The XPS and ATR-FTIR of Sep–ZrI before and after adsorption identifies the formation of inner-sphere complexes as the mechanism of phosphate adsorption. The slow release during desorption with NaOH solution confirms the strong bonds of the phosphates with the surface of the composites.",
publisher = "MDPI",
journal = "Water",
title = "The Removal of Phosphate from Aqueous Solutions by Sepiolite/ZrO2 Composites: Adsorption Behavior and Mechanism",
number = "13",
pages = "2376",
volume = "15",
doi = "10.3390/w15132376"
}
Milovanović, Ž., Lazarević, S., Janković-Častvan, I., Radovanović, Ž., Cvetković, S., Janaćković, Đ.,& Petrović, R.. (2023). The Removal of Phosphate from Aqueous Solutions by Sepiolite/ZrO2 Composites: Adsorption Behavior and Mechanism. in Water
MDPI., 15(13), 2376.
https://doi.org/10.3390/w15132376
Milovanović Ž, Lazarević S, Janković-Častvan I, Radovanović Ž, Cvetković S, Janaćković Đ, Petrović R. The Removal of Phosphate from Aqueous Solutions by Sepiolite/ZrO2 Composites: Adsorption Behavior and Mechanism. in Water. 2023;15(13):2376.
doi:10.3390/w15132376 .
Milovanović, Željka, Lazarević, Slavica, Janković-Častvan, Ivona, Radovanović, Željko, Cvetković, Slobodan, Janaćković, Đorđe, Petrović, Rada, "The Removal of Phosphate from Aqueous Solutions by Sepiolite/ZrO2 Composites: Adsorption Behavior and Mechanism" in Water, 15, no. 13 (2023):2376,
https://doi.org/10.3390/w15132376 . .

Vertically aligned TiO2 nanorod array as an electron transport layer in perovskite photodiode

Stefanović, Milica; Petrović, Rada; Janaćković, Đorđe

(Belgrade : Serbian Ceramic Society, 2023)

TY  - CONF
AU  - Stefanović, Milica
AU  - Petrović, Rada
AU  - Janaćković, Đorđe
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6739
AB  - The development of metal oxide-based electron transport layers in perovskite solar cells (PSCs) is being intensively researched to achieve highly efficient PSCs. They offer the advantage of higher charge carrier mobility and stability compared to typical organic materials. To reduce the recombination of charge carriers, methylammonium lead bromide (MAPbBr3) perovskite was coupled with vertically aligned TiO2 nanorods (NRs) as an electron transport layer in this study. The TiO2 NRs were grown on commercial FTO glass in hydrothermal conditions. Titanium (IV) isopropoxide (TTIP) was added in drops, slowly, in the diluted solution of HCl. The obtained precursor solution was transferred into a Teflon-lined stainless steel autoclave which contained FTO substrates and heated at 150 °C for 2 h. Then, the substrates were cleaned using DI water and ethanol and annealed at 500 °C for 30 min. The solution of MAPbBr3 in dimethylformamide (DMF) was deposited on TiO2 NRs by spin coating technique. FESEM results showed that TiO2 NRs were porous and oriented vertically upwards to the substrate and that the perovskite material filled the space between TiO2 NRs. Diffuse reflectance spectroscopy measurement of the sample proved that the absorption edge of the prepared TiO2 NRs/MAPbBr3 was extended into the visible range. By measuring the I-V characteristics of the sample in the dark and under visible light, a hysteresis curve was obtained. Prepared TiO2 NRs/MAPbBr3 photodiode will be the basis for the construction of solar cells.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023
T1  - Vertically aligned TiO2 nanorod array as an electron transport layer in perovskite photodiode
EP  - 73
SP  - 72
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6739
ER  - 
@conference{
author = "Stefanović, Milica and Petrović, Rada and Janaćković, Đorđe",
year = "2023",
abstract = "The development of metal oxide-based electron transport layers in perovskite solar cells (PSCs) is being intensively researched to achieve highly efficient PSCs. They offer the advantage of higher charge carrier mobility and stability compared to typical organic materials. To reduce the recombination of charge carriers, methylammonium lead bromide (MAPbBr3) perovskite was coupled with vertically aligned TiO2 nanorods (NRs) as an electron transport layer in this study. The TiO2 NRs were grown on commercial FTO glass in hydrothermal conditions. Titanium (IV) isopropoxide (TTIP) was added in drops, slowly, in the diluted solution of HCl. The obtained precursor solution was transferred into a Teflon-lined stainless steel autoclave which contained FTO substrates and heated at 150 °C for 2 h. Then, the substrates were cleaned using DI water and ethanol and annealed at 500 °C for 30 min. The solution of MAPbBr3 in dimethylformamide (DMF) was deposited on TiO2 NRs by spin coating technique. FESEM results showed that TiO2 NRs were porous and oriented vertically upwards to the substrate and that the perovskite material filled the space between TiO2 NRs. Diffuse reflectance spectroscopy measurement of the sample proved that the absorption edge of the prepared TiO2 NRs/MAPbBr3 was extended into the visible range. By measuring the I-V characteristics of the sample in the dark and under visible light, a hysteresis curve was obtained. Prepared TiO2 NRs/MAPbBr3 photodiode will be the basis for the construction of solar cells.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023",
title = "Vertically aligned TiO2 nanorod array as an electron transport layer in perovskite photodiode",
pages = "73-72",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6739"
}
Stefanović, M., Petrović, R.,& Janaćković, Đ.. (2023). Vertically aligned TiO2 nanorod array as an electron transport layer in perovskite photodiode. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023
Belgrade : Serbian Ceramic Society., 72-73.
https://hdl.handle.net/21.15107/rcub_technorep_6739
Stefanović M, Petrović R, Janaćković Đ. Vertically aligned TiO2 nanorod array as an electron transport layer in perovskite photodiode. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023. 2023;:72-73.
https://hdl.handle.net/21.15107/rcub_technorep_6739 .
Stefanović, Milica, Petrović, Rada, Janaćković, Đorđe, "Vertically aligned TiO2 nanorod array as an electron transport layer in perovskite photodiode" in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023 (2023):72-73,
https://hdl.handle.net/21.15107/rcub_technorep_6739 .

Enhanced antimicrobial properties and bioactivity of 3D-printed titanium scaffolds by multilayer bioceramic coating for large bone defects

Milivojević, Marija; Chen, Ke; Radovanović, Željko; Petrović, Rada; Dimitrijević-Branković, Suzana; Kojić, Vesna; Marković, Danica; Janaćković, Đorđe

(IOP Publishing, 2023)

TY  - JOUR
AU  - Milivojević, Marija
AU  - Chen, Ke
AU  - Radovanović, Željko
AU  - Petrović, Rada
AU  - Dimitrijević-Branković, Suzana
AU  - Kojić, Vesna
AU  - Marković, Danica
AU  - Janaćković, Đorđe
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6803
AB  - The restoration of large bone defects caused by trauma, tumor resection, or infection is a major clinical problem in orthopedics and dentistry because postoperative infections, corrosion, and limited osteointegration of metal implants can lead to loosening of the implant. The aim of this study was to improve the surface properties of a 3D-printed (electron beam melting) Ti6Al4V-based macroporous scaffold by multilayer coating with bioactive silicate glasses (BAGs) and hydroxyapatite doped with a silver (AgHAP) or AgHAP additionally sonochemically modified with ZnO (ZnO-AgHAP). The coated scaffolds AgHAP_BAGs_Ti and ZnO-AgHAP_BAGs_Ti enhanced cytocompatibility in L929 and MRC5 cell lines and expressed bioactivity in simulated body fluid. A lower release of vanadium ions in coated samples compared to bare Ti scaffold indicates decreased dissolution of Ti alloy in coated samples. The coated samples reduced growth ofEscherichia coliandStaphylococcus aureusfor 4-6 orders of magnitude. Therefore, the 3D-printed Ti-based scaffolds coated with BAGs and (ZnO-)AgHAP have great potential for application as a multifunctional implant with antibacterial properties for the restoration of defects in load-bearing bones.
PB  - IOP Publishing
T2  - Biomedical Materials
T1  - Enhanced antimicrobial properties and bioactivity of 3D-printed titanium scaffolds by multilayer bioceramic coating for large bone defects
IS  - 6
SP  - 065020
VL  - 18
DO  - 10.1088/1748-605X/ad02d2
ER  - 
@article{
author = "Milivojević, Marija and Chen, Ke and Radovanović, Željko and Petrović, Rada and Dimitrijević-Branković, Suzana and Kojić, Vesna and Marković, Danica and Janaćković, Đorđe",
year = "2023",
abstract = "The restoration of large bone defects caused by trauma, tumor resection, or infection is a major clinical problem in orthopedics and dentistry because postoperative infections, corrosion, and limited osteointegration of metal implants can lead to loosening of the implant. The aim of this study was to improve the surface properties of a 3D-printed (electron beam melting) Ti6Al4V-based macroporous scaffold by multilayer coating with bioactive silicate glasses (BAGs) and hydroxyapatite doped with a silver (AgHAP) or AgHAP additionally sonochemically modified with ZnO (ZnO-AgHAP). The coated scaffolds AgHAP_BAGs_Ti and ZnO-AgHAP_BAGs_Ti enhanced cytocompatibility in L929 and MRC5 cell lines and expressed bioactivity in simulated body fluid. A lower release of vanadium ions in coated samples compared to bare Ti scaffold indicates decreased dissolution of Ti alloy in coated samples. The coated samples reduced growth ofEscherichia coliandStaphylococcus aureusfor 4-6 orders of magnitude. Therefore, the 3D-printed Ti-based scaffolds coated with BAGs and (ZnO-)AgHAP have great potential for application as a multifunctional implant with antibacterial properties for the restoration of defects in load-bearing bones.",
publisher = "IOP Publishing",
journal = "Biomedical Materials",
title = "Enhanced antimicrobial properties and bioactivity of 3D-printed titanium scaffolds by multilayer bioceramic coating for large bone defects",
number = "6",
pages = "065020",
volume = "18",
doi = "10.1088/1748-605X/ad02d2"
}
Milivojević, M., Chen, K., Radovanović, Ž., Petrović, R., Dimitrijević-Branković, S., Kojić, V., Marković, D.,& Janaćković, Đ.. (2023). Enhanced antimicrobial properties and bioactivity of 3D-printed titanium scaffolds by multilayer bioceramic coating for large bone defects. in Biomedical Materials
IOP Publishing., 18(6), 065020.
https://doi.org/10.1088/1748-605X/ad02d2
Milivojević M, Chen K, Radovanović Ž, Petrović R, Dimitrijević-Branković S, Kojić V, Marković D, Janaćković Đ. Enhanced antimicrobial properties and bioactivity of 3D-printed titanium scaffolds by multilayer bioceramic coating for large bone defects. in Biomedical Materials. 2023;18(6):065020.
doi:10.1088/1748-605X/ad02d2 .
Milivojević, Marija, Chen, Ke, Radovanović, Željko, Petrović, Rada, Dimitrijević-Branković, Suzana, Kojić, Vesna, Marković, Danica, Janaćković, Đorđe, "Enhanced antimicrobial properties and bioactivity of 3D-printed titanium scaffolds by multilayer bioceramic coating for large bone defects" in Biomedical Materials, 18, no. 6 (2023):065020,
https://doi.org/10.1088/1748-605X/ad02d2 . .

Effects of selected inorganic chemical activators on properties and hydration mechanism of high volume fly ash (HVFA) binders

Rakić, Jelena M.; Petrović, Rada D.; Radojević, Vesna J.; Baščarević, Zvezdana D.

(Elsevier Ltd., 2023)

TY  - JOUR
AU  - Rakić, Jelena M.
AU  - Petrović, Rada D.
AU  - Radojević, Vesna J.
AU  - Baščarević, Zvezdana D.
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6458
AB  - Effects of Na2SO4, Na2CO3, and Na2SiO3 on setting time, compressive strength (up to 90 days), and hydration mechanism of binders with high volume (70 wt%, HVFA binders) of fly ash (FA) were investigated. Before chemical activation, FA was mechanically activated. Effects of the activators on hydration process were examined by isothermal calorimetry, X-ray diffraction and thermogravimetric analyses, and scanning electron microscopy. Pore solution analyses were also performed. It was found that, with addition of the chemical activators, Portland cement (PC) hydration was accelerated and the pozzolanic reaction started earlier, which resulted in shortening of setting time and increase in early compressive strength of the HVFA binders. Combination of mechanical activation of FA and the chemical activation by sodium silicate proved to be the best choice for synthesis of HVFA binder with good physicomechanical properties.
PB  - Elsevier Ltd.
T2  - Construction and Building Materials
T1  - Effects of selected inorganic chemical activators on properties and hydration mechanism of high volume fly ash (HVFA) binders
SP  - 131833
VL  - 391
DO  - 10.1016/j.conbuildmat.2023.131833
ER  - 
@article{
author = "Rakić, Jelena M. and Petrović, Rada D. and Radojević, Vesna J. and Baščarević, Zvezdana D.",
year = "2023",
abstract = "Effects of Na2SO4, Na2CO3, and Na2SiO3 on setting time, compressive strength (up to 90 days), and hydration mechanism of binders with high volume (70 wt%, HVFA binders) of fly ash (FA) were investigated. Before chemical activation, FA was mechanically activated. Effects of the activators on hydration process were examined by isothermal calorimetry, X-ray diffraction and thermogravimetric analyses, and scanning electron microscopy. Pore solution analyses were also performed. It was found that, with addition of the chemical activators, Portland cement (PC) hydration was accelerated and the pozzolanic reaction started earlier, which resulted in shortening of setting time and increase in early compressive strength of the HVFA binders. Combination of mechanical activation of FA and the chemical activation by sodium silicate proved to be the best choice for synthesis of HVFA binder with good physicomechanical properties.",
publisher = "Elsevier Ltd.",
journal = "Construction and Building Materials",
title = "Effects of selected inorganic chemical activators on properties and hydration mechanism of high volume fly ash (HVFA) binders",
pages = "131833",
volume = "391",
doi = "10.1016/j.conbuildmat.2023.131833"
}
Rakić, J. M., Petrović, R. D., Radojević, V. J.,& Baščarević, Z. D.. (2023). Effects of selected inorganic chemical activators on properties and hydration mechanism of high volume fly ash (HVFA) binders. in Construction and Building Materials
Elsevier Ltd.., 391, 131833.
https://doi.org/10.1016/j.conbuildmat.2023.131833
Rakić JM, Petrović RD, Radojević VJ, Baščarević ZD. Effects of selected inorganic chemical activators on properties and hydration mechanism of high volume fly ash (HVFA) binders. in Construction and Building Materials. 2023;391:131833.
doi:10.1016/j.conbuildmat.2023.131833 .
Rakić, Jelena M., Petrović, Rada D., Radojević, Vesna J., Baščarević, Zvezdana D., "Effects of selected inorganic chemical activators on properties and hydration mechanism of high volume fly ash (HVFA) binders" in Construction and Building Materials, 391 (2023):131833,
https://doi.org/10.1016/j.conbuildmat.2023.131833 . .
3
3

Influence of Post-Synthesis Treatments on the Properties of Brushite/Monetite Powders

Radovanović, Željko; Radovanović, Lidija; Kremenović, Aleksandar; Janaćković, Đorđe; Petrović, Rada

(Belgrade : Serbian Academy of Sciences and Arts, 2022)

TY  - CONF
AU  - Radovanović, Željko
AU  - Radovanović, Lidija
AU  - Kremenović, Aleksandar
AU  - Janaćković, Đorđe
AU  - Petrović, Rada
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6720
AB  - Dicalcium phosphate (DP) materials, of which brushite and monetite were the most known, have
been intensively studied for several decades because of excellent resorptive and osteoconductive
properties that can satisfy the requirements needed for various medical applications, such as bone
cements, coatings of metallic implants and bone grafts [1,2]. Brushite and monetite are the dihydrated (CaHPO4·2H2O) and anhydrous (CaHPO4) forms of DPs, respectively, which showed much
better resorption due to higher solubility in comparison to the hydroxyapatite (HAp) and tricalcium
phosphate (TCP) [2].
In this study, the effect of different post-synthesis treatments on composition and morphology of four
brushite/monetite powders, were analyzed. All the powders have been prepared by modified
precipitation method described previously [3] with molar ratio of starting reagents (NH4)2HPO4 and
Ca(NO3)2·4H2O being 7:10. After filtering, powder I was obtained by drying the precipitate at 105
°C for 4 h, while powder II was obtained by precipitate freezing at ‒10 °C for 72 h, followed by
drying at room temperature for 72 h. By drying the precipitate at 110 °C for 24 h and 105 °C for 3 h,
powders III and IV were obtained, respectively. X-ray powder diffraction (XRPD) revealed that all
the powders are two-phase systems consisting of brushite and monetite: 98.8 mas.% brushite and 1.2
mas.% of monetite in I, 97.7 mas.% brushite and 2.3 mas.% of monetite in II, 66.7 mas.% brushite
and 33.3 mas.% of monetite in III and 45.9 mas.% brushite and 54.1 mas.% of monetite in IV. Field
Emission Scanning Electron Microscopy (FESEM, Figure 1) showed that particles of prepared
materials form the agglomerates in the form of triangular plates. In addition, materials were analyzed
for their spectral, thermal and textural properties.
PB  - Belgrade : Serbian Academy of Sciences and Arts
C3  - Program and Book of Abstracts / Second International Conference ELMINA [Electron Microscopy of Nanostructures] 2022, Belgrade, Serbia, August 22nd-26th
T1  - Influence of Post-Synthesis Treatments on the Properties of Brushite/Monetite  Powders
EP  - 147
SP  - 146
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6720
ER  - 
@conference{
author = "Radovanović, Željko and Radovanović, Lidija and Kremenović, Aleksandar and Janaćković, Đorđe and Petrović, Rada",
year = "2022",
abstract = "Dicalcium phosphate (DP) materials, of which brushite and monetite were the most known, have
been intensively studied for several decades because of excellent resorptive and osteoconductive
properties that can satisfy the requirements needed for various medical applications, such as bone
cements, coatings of metallic implants and bone grafts [1,2]. Brushite and monetite are the dihydrated (CaHPO4·2H2O) and anhydrous (CaHPO4) forms of DPs, respectively, which showed much
better resorption due to higher solubility in comparison to the hydroxyapatite (HAp) and tricalcium
phosphate (TCP) [2].
In this study, the effect of different post-synthesis treatments on composition and morphology of four
brushite/monetite powders, were analyzed. All the powders have been prepared by modified
precipitation method described previously [3] with molar ratio of starting reagents (NH4)2HPO4 and
Ca(NO3)2·4H2O being 7:10. After filtering, powder I was obtained by drying the precipitate at 105
°C for 4 h, while powder II was obtained by precipitate freezing at ‒10 °C for 72 h, followed by
drying at room temperature for 72 h. By drying the precipitate at 110 °C for 24 h and 105 °C for 3 h,
powders III and IV were obtained, respectively. X-ray powder diffraction (XRPD) revealed that all
the powders are two-phase systems consisting of brushite and monetite: 98.8 mas.% brushite and 1.2
mas.% of monetite in I, 97.7 mas.% brushite and 2.3 mas.% of monetite in II, 66.7 mas.% brushite
and 33.3 mas.% of monetite in III and 45.9 mas.% brushite and 54.1 mas.% of monetite in IV. Field
Emission Scanning Electron Microscopy (FESEM, Figure 1) showed that particles of prepared
materials form the agglomerates in the form of triangular plates. In addition, materials were analyzed
for their spectral, thermal and textural properties.",
publisher = "Belgrade : Serbian Academy of Sciences and Arts",
journal = "Program and Book of Abstracts / Second International Conference ELMINA [Electron Microscopy of Nanostructures] 2022, Belgrade, Serbia, August 22nd-26th",
title = "Influence of Post-Synthesis Treatments on the Properties of Brushite/Monetite  Powders",
pages = "147-146",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6720"
}
Radovanović, Ž., Radovanović, L., Kremenović, A., Janaćković, Đ.,& Petrović, R.. (2022). Influence of Post-Synthesis Treatments on the Properties of Brushite/Monetite  Powders. in Program and Book of Abstracts / Second International Conference ELMINA [Electron Microscopy of Nanostructures] 2022, Belgrade, Serbia, August 22nd-26th
Belgrade : Serbian Academy of Sciences and Arts., 146-147.
https://hdl.handle.net/21.15107/rcub_technorep_6720
Radovanović Ž, Radovanović L, Kremenović A, Janaćković Đ, Petrović R. Influence of Post-Synthesis Treatments on the Properties of Brushite/Monetite  Powders. in Program and Book of Abstracts / Second International Conference ELMINA [Electron Microscopy of Nanostructures] 2022, Belgrade, Serbia, August 22nd-26th. 2022;:146-147.
https://hdl.handle.net/21.15107/rcub_technorep_6720 .
Radovanović, Željko, Radovanović, Lidija, Kremenović, Aleksandar, Janaćković, Đorđe, Petrović, Rada, "Influence of Post-Synthesis Treatments on the Properties of Brushite/Monetite  Powders" in Program and Book of Abstracts / Second International Conference ELMINA [Electron Microscopy of Nanostructures] 2022, Belgrade, Serbia, August 22nd-26th (2022):146-147,
https://hdl.handle.net/21.15107/rcub_technorep_6720 .

Characterization and drug release of Zn-Al layered double hydroxyde-nifuroxazide composite

Radovanović, Željko; Radovanović, Lidija; Janaćković, Đorđe; Petrović, Rada

(Belgrade : Materials Research Society of Serbia, 2022)

TY  - CONF
AU  - Radovanović, Željko
AU  - Radovanović, Lidija
AU  - Janaćković, Đorđe
AU  - Petrović, Rada
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7400
AB  - During last decades, layered double hydroxides ([MII1−xMIIIx(OH)2]x+(A−)x/n·yH2O, LDHs) have been used in catalysis, ceramics as well as in removal of anionic pollutants. Due to their excellent anion exchange capacity, good biocompatibility and low toxicity, the nanoparticles of LDHs showed an excellent potential as drug carriers. Nifuroxazide (C12H9N3O5, NFX) is a broad-spectrum antibacterial drug, poorly soluble in water. Towards to increase the solubility of NFX, Zn-Al-LDH/NFX composite has been prepared by precipitation method at room temperture. Zn-Al-LDH, NFX and the obtained composite were analyzed by Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), simultaneous thermogravimetry-differential thermal analysis (TG-DTA) and Brunauer–Emmett–Teller (BET) method. Characterization of the raw materials and the obtained composite confirmed the intercalation of NFX in Zn-Al-LDH. The in vitro study of drug release in simulated stomach acid and intestinal fluid showed constant release of NFX from Zn-Al-LDH during 24 h, confirming Zn-Al-LDH is a promising drug carrier.
PB  - Belgrade : Materials Research Society of Serbia
C3  - Programme and The Book of Abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022
T1  - Characterization and drug release of Zn-Al layered double hydroxyde-nifuroxazide composite
SP  - 150
UR  - https://hdl.handle.net/21.15107/rcub_technorep_7400
ER  - 
@conference{
author = "Radovanović, Željko and Radovanović, Lidija and Janaćković, Đorđe and Petrović, Rada",
year = "2022",
abstract = "During last decades, layered double hydroxides ([MII1−xMIIIx(OH)2]x+(A−)x/n·yH2O, LDHs) have been used in catalysis, ceramics as well as in removal of anionic pollutants. Due to their excellent anion exchange capacity, good biocompatibility and low toxicity, the nanoparticles of LDHs showed an excellent potential as drug carriers. Nifuroxazide (C12H9N3O5, NFX) is a broad-spectrum antibacterial drug, poorly soluble in water. Towards to increase the solubility of NFX, Zn-Al-LDH/NFX composite has been prepared by precipitation method at room temperture. Zn-Al-LDH, NFX and the obtained composite were analyzed by Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), simultaneous thermogravimetry-differential thermal analysis (TG-DTA) and Brunauer–Emmett–Teller (BET) method. Characterization of the raw materials and the obtained composite confirmed the intercalation of NFX in Zn-Al-LDH. The in vitro study of drug release in simulated stomach acid and intestinal fluid showed constant release of NFX from Zn-Al-LDH during 24 h, confirming Zn-Al-LDH is a promising drug carrier.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Programme and The Book of Abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022",
title = "Characterization and drug release of Zn-Al layered double hydroxyde-nifuroxazide composite",
pages = "150",
url = "https://hdl.handle.net/21.15107/rcub_technorep_7400"
}
Radovanović, Ž., Radovanović, L., Janaćković, Đ.,& Petrović, R.. (2022). Characterization and drug release of Zn-Al layered double hydroxyde-nifuroxazide composite. in Programme and The Book of Abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022
Belgrade : Materials Research Society of Serbia., 150.
https://hdl.handle.net/21.15107/rcub_technorep_7400
Radovanović Ž, Radovanović L, Janaćković Đ, Petrović R. Characterization and drug release of Zn-Al layered double hydroxyde-nifuroxazide composite. in Programme and The Book of Abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022. 2022;:150.
https://hdl.handle.net/21.15107/rcub_technorep_7400 .
Radovanović, Željko, Radovanović, Lidija, Janaćković, Đorđe, Petrović, Rada, "Characterization and drug release of Zn-Al layered double hydroxyde-nifuroxazide composite" in Programme and The Book of Abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022 (2022):150,
https://hdl.handle.net/21.15107/rcub_technorep_7400 .

Ciprofloxacin removal using sepiolite-based adsorbents

Marjanović, Vesna; Janković-Častvan, Ivona; Lazarević, Slavica; Radovanović, Željko; Janaćković, Đorđe; Petrović, Rada

(University of Novi Sad, Faculty of Technology Novi Sad, 2022)

TY  - CONF
AU  - Marjanović, Vesna
AU  - Janković-Častvan, Ivona
AU  - Lazarević, Slavica
AU  - Radovanović, Željko
AU  - Janaćković, Đorđe
AU  - Petrović, Rada
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5920
AB  - Ciprofloxacin (CIP) as a broad-spectrum quinolone antibiotic is extensively used in daily life and can be detected in municipal and pharmaceutical wastewaters, as well as natural waters. In this study, natural mineral sepiolite (SEP), SEP modified with hexadecyltrimethylammonium-bromide (HDAB) and SEP composites with graphene oxide (GO) were used as adsorbents for the removal of CIP from aqueous solutions. The composites were prepared at a mass ratio SEP to GO of 2 : 1, using SEP and SEP modified by [3-(2-aminoethylamino)propyl]trimethoxy-silane (APT). Thermogravimetric analysis, X-ray diffraction and nitrogen adsorption-desorption were used to characterize the obtained adsorbents. The adsorption of CIP was investigated at the pH value close to pH of natural waters. The concentration of CIP in aqueous solution was determined by UV-Vis spectroscopy. GO showed the highest adsorption capacity (~ 150 mg/g). The capacity of SEP was about 60 mg/g, while the SEP modification with HDAB has led to a decrease in the adsorption capacity (~ 35 mg/g). The composite SEP/GO showed the higher adsorption capacity (~ 110 mg/g) than the composite SEP-APT/GO (~ 40 mg/g). The capacity of the composite SEP/GO was higher than of mixture of SEP and GO, which indicated a certain degree of GO exfoliation and intecalation of sepiolie particles, as it was shown by X-ray diffraction. Equilibrium data for all adsorbents, except for HDAB modified sepiolite, fitted well to the Langmuir isotherm model.
PB  - University of Novi Sad, Faculty of Technology Novi Sad
C3  - 2nd International Conference on Advanced Production and Processing, Book of abstracts
T1  - Ciprofloxacin removal using sepiolite-based adsorbents
SP  - 218
SP  - 218
UR  - https://hdl.handle.net/21.15107/rcub_technorep_5920
ER  - 
@conference{
author = "Marjanović, Vesna and Janković-Častvan, Ivona and Lazarević, Slavica and Radovanović, Željko and Janaćković, Đorđe and Petrović, Rada",
year = "2022",
abstract = "Ciprofloxacin (CIP) as a broad-spectrum quinolone antibiotic is extensively used in daily life and can be detected in municipal and pharmaceutical wastewaters, as well as natural waters. In this study, natural mineral sepiolite (SEP), SEP modified with hexadecyltrimethylammonium-bromide (HDAB) and SEP composites with graphene oxide (GO) were used as adsorbents for the removal of CIP from aqueous solutions. The composites were prepared at a mass ratio SEP to GO of 2 : 1, using SEP and SEP modified by [3-(2-aminoethylamino)propyl]trimethoxy-silane (APT). Thermogravimetric analysis, X-ray diffraction and nitrogen adsorption-desorption were used to characterize the obtained adsorbents. The adsorption of CIP was investigated at the pH value close to pH of natural waters. The concentration of CIP in aqueous solution was determined by UV-Vis spectroscopy. GO showed the highest adsorption capacity (~ 150 mg/g). The capacity of SEP was about 60 mg/g, while the SEP modification with HDAB has led to a decrease in the adsorption capacity (~ 35 mg/g). The composite SEP/GO showed the higher adsorption capacity (~ 110 mg/g) than the composite SEP-APT/GO (~ 40 mg/g). The capacity of the composite SEP/GO was higher than of mixture of SEP and GO, which indicated a certain degree of GO exfoliation and intecalation of sepiolie particles, as it was shown by X-ray diffraction. Equilibrium data for all adsorbents, except for HDAB modified sepiolite, fitted well to the Langmuir isotherm model.",
publisher = "University of Novi Sad, Faculty of Technology Novi Sad",
journal = "2nd International Conference on Advanced Production and Processing, Book of abstracts",
title = "Ciprofloxacin removal using sepiolite-based adsorbents",
pages = "218-218",
url = "https://hdl.handle.net/21.15107/rcub_technorep_5920"
}
Marjanović, V., Janković-Častvan, I., Lazarević, S., Radovanović, Ž., Janaćković, Đ.,& Petrović, R.. (2022). Ciprofloxacin removal using sepiolite-based adsorbents. in 2nd International Conference on Advanced Production and Processing, Book of abstracts
University of Novi Sad, Faculty of Technology Novi Sad., 218.
https://hdl.handle.net/21.15107/rcub_technorep_5920
Marjanović V, Janković-Častvan I, Lazarević S, Radovanović Ž, Janaćković Đ, Petrović R. Ciprofloxacin removal using sepiolite-based adsorbents. in 2nd International Conference on Advanced Production and Processing, Book of abstracts. 2022;:218.
https://hdl.handle.net/21.15107/rcub_technorep_5920 .
Marjanović, Vesna, Janković-Častvan, Ivona, Lazarević, Slavica, Radovanović, Željko, Janaćković, Đorđe, Petrović, Rada, "Ciprofloxacin removal using sepiolite-based adsorbents" in 2nd International Conference on Advanced Production and Processing, Book of abstracts (2022):218,
https://hdl.handle.net/21.15107/rcub_technorep_5920 .

Composite hydrogels based on gelatin, hydroxypropyl methylcellulose and Mg-doped biphasic calcium phosphate for biomedical applications

Ugrinović, Vukašin; Hristara, Veroniki; Marković, Maja; Petrović, Predrag; Petrović, Rada; Janaćković, Đorđe; Veljović, Đorđe

(Materials Research Society of Serbia, Belgrade, Serbia, 2022)

TY  - CONF
AU  - Ugrinović, Vukašin
AU  - Hristara, Veroniki
AU  - Marković, Maja
AU  - Petrović, Predrag
AU  - Petrović, Rada
AU  - Janaćković, Đorđe
AU  - Veljović, Đorđe
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5240
AB  - Hydrogels are three-dimensional hydrophilic networks of polymers capable of retaining large
amounts of water or biological fluids, which makes them attractive for biomedical and
pharmaceutical applications. Although various types of polymers have been investigated as
hydrogels for biomedical purposes, those obtained from natural polymers have intrinsic
advantages as they are abundant, cheap, biocompatible and biodegradable. Gelatin is a natural
polymer that has been applied in biomedicine due to its low price, biocompatibility, and
biodegradability. HPMC, a derivative of cellulose, is a hydrophilic, biodegradable, and
biocompatible polymer. However, natural polymer-based hydrogels have low mechanical
properties and are relatively soluble in physiological conditions, which requires creative crosslinking strategies to improve the functionality of the hydrogels. The citric acid (CA) is an
inexpensive and non-toxic compound that has been proven to be an effective crosslinker for
natural polymers. In addition, the incorporation of bioactive calcium phosphate particles could
further improve mechanical properties and add new functionalities to the hydrogels.
In this work, we present novel composite hydrogels for biomedical applications, based on CAcrosslinked gelatin/HPMC (HPMC-G) matrix and Mg-doped biphasic calcium phosphate filler
(BCP). Firstly, the HPMC-G hydrogels crosslinking conditions were optimized. Different CA
concentrations, curing temperatures (140-180°C) and times (3-9 min) were applied. During the
second step, the optimaly crosslinked HPMC-G hydrogel was incorporated with different amounts
of BCP. BCP was obtained by calcination of Mg-doped hydroxyapatite (HA) powder synthesized
by the hydrothermal method. XRD analysis confirmed that powder was constituted only of HA
and beta-tricalcium phosphate. The obtained composite hydrogels were characterized by
mechanical testing, FTIR, SEM, swelling behavior and drug deliverability.
PB  - Materials Research Society of Serbia, Belgrade, Serbia
C3  - TWENTY THIRD ANNUAL CONFERENCE - YUCOMAT 2022, Herceg Novi, Montenegro
T1  - Composite hydrogels based on gelatin, hydroxypropyl methylcellulose and Mg-doped biphasic calcium phosphate for biomedical applications
UR  - https://hdl.handle.net/21.15107/rcub_technorep_5240
ER  - 
@conference{
author = "Ugrinović, Vukašin and Hristara, Veroniki and Marković, Maja and Petrović, Predrag and Petrović, Rada and Janaćković, Đorđe and Veljović, Đorđe",
year = "2022",
abstract = "Hydrogels are three-dimensional hydrophilic networks of polymers capable of retaining large
amounts of water or biological fluids, which makes them attractive for biomedical and
pharmaceutical applications. Although various types of polymers have been investigated as
hydrogels for biomedical purposes, those obtained from natural polymers have intrinsic
advantages as they are abundant, cheap, biocompatible and biodegradable. Gelatin is a natural
polymer that has been applied in biomedicine due to its low price, biocompatibility, and
biodegradability. HPMC, a derivative of cellulose, is a hydrophilic, biodegradable, and
biocompatible polymer. However, natural polymer-based hydrogels have low mechanical
properties and are relatively soluble in physiological conditions, which requires creative crosslinking strategies to improve the functionality of the hydrogels. The citric acid (CA) is an
inexpensive and non-toxic compound that has been proven to be an effective crosslinker for
natural polymers. In addition, the incorporation of bioactive calcium phosphate particles could
further improve mechanical properties and add new functionalities to the hydrogels.
In this work, we present novel composite hydrogels for biomedical applications, based on CAcrosslinked gelatin/HPMC (HPMC-G) matrix and Mg-doped biphasic calcium phosphate filler
(BCP). Firstly, the HPMC-G hydrogels crosslinking conditions were optimized. Different CA
concentrations, curing temperatures (140-180°C) and times (3-9 min) were applied. During the
second step, the optimaly crosslinked HPMC-G hydrogel was incorporated with different amounts
of BCP. BCP was obtained by calcination of Mg-doped hydroxyapatite (HA) powder synthesized
by the hydrothermal method. XRD analysis confirmed that powder was constituted only of HA
and beta-tricalcium phosphate. The obtained composite hydrogels were characterized by
mechanical testing, FTIR, SEM, swelling behavior and drug deliverability.",
publisher = "Materials Research Society of Serbia, Belgrade, Serbia",
journal = "TWENTY THIRD ANNUAL CONFERENCE - YUCOMAT 2022, Herceg Novi, Montenegro",
title = "Composite hydrogels based on gelatin, hydroxypropyl methylcellulose and Mg-doped biphasic calcium phosphate for biomedical applications",
url = "https://hdl.handle.net/21.15107/rcub_technorep_5240"
}
Ugrinović, V., Hristara, V., Marković, M., Petrović, P., Petrović, R., Janaćković, Đ.,& Veljović, Đ.. (2022). Composite hydrogels based on gelatin, hydroxypropyl methylcellulose and Mg-doped biphasic calcium phosphate for biomedical applications. in TWENTY THIRD ANNUAL CONFERENCE - YUCOMAT 2022, Herceg Novi, Montenegro
Materials Research Society of Serbia, Belgrade, Serbia..
https://hdl.handle.net/21.15107/rcub_technorep_5240
Ugrinović V, Hristara V, Marković M, Petrović P, Petrović R, Janaćković Đ, Veljović Đ. Composite hydrogels based on gelatin, hydroxypropyl methylcellulose and Mg-doped biphasic calcium phosphate for biomedical applications. in TWENTY THIRD ANNUAL CONFERENCE - YUCOMAT 2022, Herceg Novi, Montenegro. 2022;.
https://hdl.handle.net/21.15107/rcub_technorep_5240 .
Ugrinović, Vukašin, Hristara, Veroniki, Marković, Maja, Petrović, Predrag, Petrović, Rada, Janaćković, Đorđe, Veljović, Đorđe, "Composite hydrogels based on gelatin, hydroxypropyl methylcellulose and Mg-doped biphasic calcium phosphate for biomedical applications" in TWENTY THIRD ANNUAL CONFERENCE - YUCOMAT 2022, Herceg Novi, Montenegro (2022),
https://hdl.handle.net/21.15107/rcub_technorep_5240 .

Sr,Mg co-doping of calcium hydroxyapatite: Hydrothermal synthesis, processing, characterization and possible application as dentin substitutes

Matić, Tamara; Zebić, M. Ležaja; Miletić, Vesna; Cvijović-Alagić, Ivana; Petrović, Rada; Janaćković, Đorđe; Veljović, Đorđe

(2022)

TY  - JOUR
AU  - Matić, Tamara
AU  - Zebić, M. Ležaja
AU  - Miletić, Vesna
AU  - Cvijović-Alagić, Ivana
AU  - Petrović, Rada
AU  - Janaćković, Đorđe
AU  - Veljović, Đorđe
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5362
AB  - The aim of this study was to investigate the influence of binary Sr, Mg ion-doping compared to the single-ion doping effects on the phase composition and morphology of hydrothermally obtained calcium hydroxyapatite (HAP) powders and on the phase composition, microstructure, and mechanical properties of the sintered materials. Additionally, the focus of this study was to investigate the possible utilization of the binary doped Sr,Mg-HAP compacts as dentin substitutes in restorative dentistry by evaluating their bonding ability with commercially available restorative materials using the shear bond strength test (SBS). The hydrothermally obtained mono-doped Mg5 and Sr5 showed the monophasic apatite structure, while in all co-doped samples β-TCP phase was formed, resulting in biphasic calcium phosphate (BCP) powders. It was confirmed that co-doping with Sr and Mg ions led to the thermal stabilization of the β-TCP phase by suppressing the phase transition into α-TCP when sintered at 1200 °C. Moreover, the co-presence of Mg ions significantly improved the hardness of Sr-doped HAP from 3.74 to 5.02 GPa. Sr,Mg-HAP dental inserts were found to achieve sufficient bonding (13.53 MPa) through the micromechanical interlocking with Z250 dental composite and Single Bond Universal dental adhesive applied with a total etch approach. The SBS values obtained for the SrMg-HAP insert were similar to the literature data on bonding ability with human dentin, indicating that binary doped Sr,Mg-HAP ceramics present a promising material for application in restorative dentistry as dentin substitutes.
T2  - Ceramics International
T1  - Sr,Mg co-doping of calcium hydroxyapatite: Hydrothermal synthesis, processing, characterization and possible application as dentin substitutes
EP  - 11165
IS  - 8
SP  - 11155
VL  - 48
DO  - 10.1016/j.ceramint.2021.12.335
ER  - 
@article{
author = "Matić, Tamara and Zebić, M. Ležaja and Miletić, Vesna and Cvijović-Alagić, Ivana and Petrović, Rada and Janaćković, Đorđe and Veljović, Đorđe",
year = "2022",
abstract = "The aim of this study was to investigate the influence of binary Sr, Mg ion-doping compared to the single-ion doping effects on the phase composition and morphology of hydrothermally obtained calcium hydroxyapatite (HAP) powders and on the phase composition, microstructure, and mechanical properties of the sintered materials. Additionally, the focus of this study was to investigate the possible utilization of the binary doped Sr,Mg-HAP compacts as dentin substitutes in restorative dentistry by evaluating their bonding ability with commercially available restorative materials using the shear bond strength test (SBS). The hydrothermally obtained mono-doped Mg5 and Sr5 showed the monophasic apatite structure, while in all co-doped samples β-TCP phase was formed, resulting in biphasic calcium phosphate (BCP) powders. It was confirmed that co-doping with Sr and Mg ions led to the thermal stabilization of the β-TCP phase by suppressing the phase transition into α-TCP when sintered at 1200 °C. Moreover, the co-presence of Mg ions significantly improved the hardness of Sr-doped HAP from 3.74 to 5.02 GPa. Sr,Mg-HAP dental inserts were found to achieve sufficient bonding (13.53 MPa) through the micromechanical interlocking with Z250 dental composite and Single Bond Universal dental adhesive applied with a total etch approach. The SBS values obtained for the SrMg-HAP insert were similar to the literature data on bonding ability with human dentin, indicating that binary doped Sr,Mg-HAP ceramics present a promising material for application in restorative dentistry as dentin substitutes.",
journal = "Ceramics International",
title = "Sr,Mg co-doping of calcium hydroxyapatite: Hydrothermal synthesis, processing, characterization and possible application as dentin substitutes",
pages = "11165-11155",
number = "8",
volume = "48",
doi = "10.1016/j.ceramint.2021.12.335"
}
Matić, T., Zebić, M. L., Miletić, V., Cvijović-Alagić, I., Petrović, R., Janaćković, Đ.,& Veljović, Đ.. (2022). Sr,Mg co-doping of calcium hydroxyapatite: Hydrothermal synthesis, processing, characterization and possible application as dentin substitutes. in Ceramics International, 48(8), 11155-11165.
https://doi.org/10.1016/j.ceramint.2021.12.335
Matić T, Zebić ML, Miletić V, Cvijović-Alagić I, Petrović R, Janaćković Đ, Veljović Đ. Sr,Mg co-doping of calcium hydroxyapatite: Hydrothermal synthesis, processing, characterization and possible application as dentin substitutes. in Ceramics International. 2022;48(8):11155-11165.
doi:10.1016/j.ceramint.2021.12.335 .
Matić, Tamara, Zebić, M. Ležaja, Miletić, Vesna, Cvijović-Alagić, Ivana, Petrović, Rada, Janaćković, Đorđe, Veljović, Đorđe, "Sr,Mg co-doping of calcium hydroxyapatite: Hydrothermal synthesis, processing, characterization and possible application as dentin substitutes" in Ceramics International, 48, no. 8 (2022):11155-11165,
https://doi.org/10.1016/j.ceramint.2021.12.335 . .
8
7

Supercritical CO2 assisted deposition of MAPbBr3 perovskite onto TiO2 nanotubes

Stefanović, Milica; Lukić, Ivana; Vujančević, Jelena; Petrović, Rada; Janaćković, Đorđe

(Materials Research Society of Serbia, 2022)

TY  - CONF
AU  - Stefanović, Milica
AU  - Lukić, Ivana
AU  - Vujančević, Jelena
AU  - Petrović, Rada
AU  - Janaćković, Đorđe
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6170
AB  - Supercritical carbon dioxide (sCO2) is an ideal low-temperature cosolvent for perovskite
deposition due to its relatively low critical point (31.2 °C, 73.8 bar), no surface tension, liquidlike density, gas-like viscosity, and diffusivity. It enables faster mass transfer which allows
penetration of crystals in nanoporous structure. The study investigates the influence of time of
deposition of perovskite assisted with supercritical carbon dioxide on the filling of nanotubes.
Perovskite solar cell technology has been developed so fast due to several factors including a
tunable band gap, high absorption coefficient, and low-cost fabrication. The quality of the
perovskite film is important for the high efficiency of perovskite solar cells. Perovskite precursors
are usually deposited from the solution onto a substrate using spin-coating followed by postdeposition treatments, but often it results in low-quality films that cannot provide good
photovoltaic performances. Deposition of perovskite in the presence of sCO2 is a promising
method for the formation of high-quality perovskite layers. In this work, methylammonium lead
bromide perovskite (MAPbBr3) was deposited on TiO2 nanotubes from the solution in
dimethylformamide (DMF) by application of sCO2 at 35 °C and 200 bar for 1 h, and 3 h. FESEM
results show that TiO2 nanotubes were filled with perovskite material in both cases. The diffuse
reflectance spectroscopy measurement of samples proved that the absorption edge of prepared
TiO2 nanotubes/MAPbBr3 was extended to the visible range. Measurement of I-V characteristics
showed that the sample made for 3 h had a higher value of current than the sample prepared for 1
h. The application of sCO2 during the deposition of perovskite has enabled the preparation of a
photodiode with a better contact between TiO2 nanotubes and perovskite which is important for
the future development of solar cells.
PB  - Materials Research Society of Serbia
C3  - 23th Annual Conference YUCOMAT 2022 and 12th WRTCS
T1  - Supercritical CO2 assisted deposition of MAPbBr3 perovskite onto TiO2 nanotubes
SP  - 73
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6170
ER  - 
@conference{
author = "Stefanović, Milica and Lukić, Ivana and Vujančević, Jelena and Petrović, Rada and Janaćković, Đorđe",
year = "2022",
abstract = "Supercritical carbon dioxide (sCO2) is an ideal low-temperature cosolvent for perovskite
deposition due to its relatively low critical point (31.2 °C, 73.8 bar), no surface tension, liquidlike density, gas-like viscosity, and diffusivity. It enables faster mass transfer which allows
penetration of crystals in nanoporous structure. The study investigates the influence of time of
deposition of perovskite assisted with supercritical carbon dioxide on the filling of nanotubes.
Perovskite solar cell technology has been developed so fast due to several factors including a
tunable band gap, high absorption coefficient, and low-cost fabrication. The quality of the
perovskite film is important for the high efficiency of perovskite solar cells. Perovskite precursors
are usually deposited from the solution onto a substrate using spin-coating followed by postdeposition treatments, but often it results in low-quality films that cannot provide good
photovoltaic performances. Deposition of perovskite in the presence of sCO2 is a promising
method for the formation of high-quality perovskite layers. In this work, methylammonium lead
bromide perovskite (MAPbBr3) was deposited on TiO2 nanotubes from the solution in
dimethylformamide (DMF) by application of sCO2 at 35 °C and 200 bar for 1 h, and 3 h. FESEM
results show that TiO2 nanotubes were filled with perovskite material in both cases. The diffuse
reflectance spectroscopy measurement of samples proved that the absorption edge of prepared
TiO2 nanotubes/MAPbBr3 was extended to the visible range. Measurement of I-V characteristics
showed that the sample made for 3 h had a higher value of current than the sample prepared for 1
h. The application of sCO2 during the deposition of perovskite has enabled the preparation of a
photodiode with a better contact between TiO2 nanotubes and perovskite which is important for
the future development of solar cells.",
publisher = "Materials Research Society of Serbia",
journal = "23th Annual Conference YUCOMAT 2022 and 12th WRTCS",
title = "Supercritical CO2 assisted deposition of MAPbBr3 perovskite onto TiO2 nanotubes",
pages = "73",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6170"
}
Stefanović, M., Lukić, I., Vujančević, J., Petrović, R.,& Janaćković, Đ.. (2022). Supercritical CO2 assisted deposition of MAPbBr3 perovskite onto TiO2 nanotubes. in 23th Annual Conference YUCOMAT 2022 and 12th WRTCS
Materials Research Society of Serbia., 73.
https://hdl.handle.net/21.15107/rcub_technorep_6170
Stefanović M, Lukić I, Vujančević J, Petrović R, Janaćković Đ. Supercritical CO2 assisted deposition of MAPbBr3 perovskite onto TiO2 nanotubes. in 23th Annual Conference YUCOMAT 2022 and 12th WRTCS. 2022;:73.
https://hdl.handle.net/21.15107/rcub_technorep_6170 .
Stefanović, Milica, Lukić, Ivana, Vujančević, Jelena, Petrović, Rada, Janaćković, Đorđe, "Supercritical CO2 assisted deposition of MAPbBr3 perovskite onto TiO2 nanotubes" in 23th Annual Conference YUCOMAT 2022 and 12th WRTCS (2022):73,
https://hdl.handle.net/21.15107/rcub_technorep_6170 .

Improving the contact surface between TiO2 nanotubes and MAPbBr3 to make perovskite solar cells

Stefanović, Milica; Lukić, Ivana; Vujančević, Jelena; Petrović, Rada; Janaćković, Đorđe

(Serbian Academy of Sciences and Arts, 2022)

TY  - CONF
AU  - Stefanović, Milica
AU  - Lukić, Ivana
AU  - Vujančević, Jelena
AU  - Petrović, Rada
AU  - Janaćković, Đorđe
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6172
PB  - Serbian Academy of Sciences and Arts
C3  - Second International conference ELMINA2022 Electron Microscopy of Nanostructures
T1  - Improving the contact surface between TiO2 nanotubes and MAPbBr3 to make perovskite solar cells
EP  - 190
SP  - 189
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6172
ER  - 
@conference{
author = "Stefanović, Milica and Lukić, Ivana and Vujančević, Jelena and Petrović, Rada and Janaćković, Đorđe",
year = "2022",
publisher = "Serbian Academy of Sciences and Arts",
journal = "Second International conference ELMINA2022 Electron Microscopy of Nanostructures",
title = "Improving the contact surface between TiO2 nanotubes and MAPbBr3 to make perovskite solar cells",
pages = "190-189",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6172"
}
Stefanović, M., Lukić, I., Vujančević, J., Petrović, R.,& Janaćković, Đ.. (2022). Improving the contact surface between TiO2 nanotubes and MAPbBr3 to make perovskite solar cells. in Second International conference ELMINA2022 Electron Microscopy of Nanostructures
Serbian Academy of Sciences and Arts., 189-190.
https://hdl.handle.net/21.15107/rcub_technorep_6172
Stefanović M, Lukić I, Vujančević J, Petrović R, Janaćković Đ. Improving the contact surface between TiO2 nanotubes and MAPbBr3 to make perovskite solar cells. in Second International conference ELMINA2022 Electron Microscopy of Nanostructures. 2022;:189-190.
https://hdl.handle.net/21.15107/rcub_technorep_6172 .
Stefanović, Milica, Lukić, Ivana, Vujančević, Jelena, Petrović, Rada, Janaćković, Đorđe, "Improving the contact surface between TiO2 nanotubes and MAPbBr3 to make perovskite solar cells" in Second International conference ELMINA2022 Electron Microscopy of Nanostructures (2022):189-190,
https://hdl.handle.net/21.15107/rcub_technorep_6172 .

Hydroxyapatite-based Bioceramic Dental Inserts as Dentin Substitute

Matić, Tamara; Zebić, Maja L.; Miletić, Vesna; Petrović, Rada; Janaćković, Đorđe; Veljović, Đorđe

(Belgrade : Serbian Academy of Sciences and Arts, 2022)

TY  - CONF
AU  - Matić, Tamara
AU  - Zebić, Maja L.
AU  - Miletić, Vesna
AU  - Petrović, Rada
AU  - Janaćković, Đorđe
AU  - Veljović, Đorđe
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6674
AB  - Tooth caries presents one of the most common diseases worldwide, and its treatment involves
removal of the decayed tooth structure, and the cavity restoration using restorative dental materials. Resin based composites (RBCs) are the most commonly used restorative material in practice owing to their great aesthetic appearance allowing the clinicians to adapt the nuance of the restoration to the patient’s tooth color. However, the RBCs harden by the polymerization of monomers that leads to the polymerization shrinkage of the restoration, leaving the micro-gaps at the teeth-restorations interface which allows the secondary caries formation.
PB  - Belgrade : Serbian Academy of Sciences and Arts
C3  - Program & Book of Abstracts / Second International Conference on Electron Microscopy of Nanostructures ELMINA 2022, August 22nd-26th Belgrade, Serbia
T1  - Hydroxyapatite-based Bioceramic Dental Inserts as Dentin Substitute
EP  - 151
SP  - 150
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6674
ER  - 
@conference{
author = "Matić, Tamara and Zebić, Maja L. and Miletić, Vesna and Petrović, Rada and Janaćković, Đorđe and Veljović, Đorđe",
year = "2022",
abstract = "Tooth caries presents one of the most common diseases worldwide, and its treatment involves
removal of the decayed tooth structure, and the cavity restoration using restorative dental materials. Resin based composites (RBCs) are the most commonly used restorative material in practice owing to their great aesthetic appearance allowing the clinicians to adapt the nuance of the restoration to the patient’s tooth color. However, the RBCs harden by the polymerization of monomers that leads to the polymerization shrinkage of the restoration, leaving the micro-gaps at the teeth-restorations interface which allows the secondary caries formation.",
publisher = "Belgrade : Serbian Academy of Sciences and Arts",
journal = "Program & Book of Abstracts / Second International Conference on Electron Microscopy of Nanostructures ELMINA 2022, August 22nd-26th Belgrade, Serbia",
title = "Hydroxyapatite-based Bioceramic Dental Inserts as Dentin Substitute",
pages = "151-150",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6674"
}
Matić, T., Zebić, M. L., Miletić, V., Petrović, R., Janaćković, Đ.,& Veljović, Đ.. (2022). Hydroxyapatite-based Bioceramic Dental Inserts as Dentin Substitute. in Program & Book of Abstracts / Second International Conference on Electron Microscopy of Nanostructures ELMINA 2022, August 22nd-26th Belgrade, Serbia
Belgrade : Serbian Academy of Sciences and Arts., 150-151.
https://hdl.handle.net/21.15107/rcub_technorep_6674
Matić T, Zebić ML, Miletić V, Petrović R, Janaćković Đ, Veljović Đ. Hydroxyapatite-based Bioceramic Dental Inserts as Dentin Substitute. in Program & Book of Abstracts / Second International Conference on Electron Microscopy of Nanostructures ELMINA 2022, August 22nd-26th Belgrade, Serbia. 2022;:150-151.
https://hdl.handle.net/21.15107/rcub_technorep_6674 .
Matić, Tamara, Zebić, Maja L., Miletić, Vesna, Petrović, Rada, Janaćković, Đorđe, Veljović, Đorđe, "Hydroxyapatite-based Bioceramic Dental Inserts as Dentin Substitute" in Program & Book of Abstracts / Second International Conference on Electron Microscopy of Nanostructures ELMINA 2022, August 22nd-26th Belgrade, Serbia (2022):150-151,
https://hdl.handle.net/21.15107/rcub_technorep_6674 .

THE INFLUENCE OF HYDROTHERMAL SYNTHESIS TEMPERATURE OF MAGNESIUM DOPED HYDROXYAPATITE ON ITS APPLICATION AS DENTIN SUBSTITUTE

Matić, Tamara; Zebić, Maja L.; Miletić, Vesna; Petrović, Rada; Janaćković, Đorđe; Veljović, Đorđe

(Belgrade : Institut za multidisciplinarna istraživanja, 2022)

TY  - CONF
AU  - Matić, Tamara
AU  - Zebić, Maja L.
AU  - Miletić, Vesna
AU  - Petrović, Rada
AU  - Janaćković, Đorđe
AU  - Veljović, Đorđe
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6680
PB  - Belgrade : Institut za multidisciplinarna istraživanja
C3  - Programme and the Book of Abstracts / 6th Conference of The Serbian Society for Ceramic Materials, 6CSCS-2022, June 28-29, 2022, Belgrade, Serbia
T1  - THE INFLUENCE OF HYDROTHERMAL SYNTHESIS TEMPERATURE OF MAGNESIUM DOPED HYDROXYAPATITE ON ITS APPLICATION AS DENTIN SUBSTITUTE
EP  - 37
SP  - 36
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6680
ER  - 
@conference{
author = "Matić, Tamara and Zebić, Maja L. and Miletić, Vesna and Petrović, Rada and Janaćković, Đorđe and Veljović, Đorđe",
year = "2022",
publisher = "Belgrade : Institut za multidisciplinarna istraživanja",
journal = "Programme and the Book of Abstracts / 6th Conference of The Serbian Society for Ceramic Materials, 6CSCS-2022, June 28-29, 2022, Belgrade, Serbia",
title = "THE INFLUENCE OF HYDROTHERMAL SYNTHESIS TEMPERATURE OF MAGNESIUM DOPED HYDROXYAPATITE ON ITS APPLICATION AS DENTIN SUBSTITUTE",
pages = "37-36",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6680"
}
Matić, T., Zebić, M. L., Miletić, V., Petrović, R., Janaćković, Đ.,& Veljović, Đ.. (2022). THE INFLUENCE OF HYDROTHERMAL SYNTHESIS TEMPERATURE OF MAGNESIUM DOPED HYDROXYAPATITE ON ITS APPLICATION AS DENTIN SUBSTITUTE. in Programme and the Book of Abstracts / 6th Conference of The Serbian Society for Ceramic Materials, 6CSCS-2022, June 28-29, 2022, Belgrade, Serbia
Belgrade : Institut za multidisciplinarna istraživanja., 36-37.
https://hdl.handle.net/21.15107/rcub_technorep_6680
Matić T, Zebić ML, Miletić V, Petrović R, Janaćković Đ, Veljović Đ. THE INFLUENCE OF HYDROTHERMAL SYNTHESIS TEMPERATURE OF MAGNESIUM DOPED HYDROXYAPATITE ON ITS APPLICATION AS DENTIN SUBSTITUTE. in Programme and the Book of Abstracts / 6th Conference of The Serbian Society for Ceramic Materials, 6CSCS-2022, June 28-29, 2022, Belgrade, Serbia. 2022;:36-37.
https://hdl.handle.net/21.15107/rcub_technorep_6680 .
Matić, Tamara, Zebić, Maja L., Miletić, Vesna, Petrović, Rada, Janaćković, Đorđe, Veljović, Đorđe, "THE INFLUENCE OF HYDROTHERMAL SYNTHESIS TEMPERATURE OF MAGNESIUM DOPED HYDROXYAPATITE ON ITS APPLICATION AS DENTIN SUBSTITUTE" in Programme and the Book of Abstracts / 6th Conference of The Serbian Society for Ceramic Materials, 6CSCS-2022, June 28-29, 2022, Belgrade, Serbia (2022):36-37,
https://hdl.handle.net/21.15107/rcub_technorep_6680 .

The ExcellMater project for advancement of novel bioceramic and composite biomaterials for medical applications

Obradović, Bojana; Stojkovska, Jasmina; Radovanović, Željko; Matić, Tamara; Petrović, Rada; Janaćković, Đorđe; Veljović, Đorđe

(Consiglio Nazionale delle Ricerche Istituto di Struttura della Materia, 2022)

TY  - CONF
AU  - Obradović, Bojana
AU  - Stojkovska, Jasmina
AU  - Radovanović, Željko
AU  - Matić, Tamara
AU  - Petrović, Rada
AU  - Janaćković, Đorđe
AU  - Veljović, Đorđe
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6682
AB  - Biomaterials engineering is one of the strongest research areas at the Faculty of Technology and Metallurgy (FTM), University of Belgrade including development of novel biomaterials for orthopaedic and dental applications. Especially, synthesis and physico-chemical characterization methods are well established resulting in variety of novel inorganic, polymer and composite biomaterials produced in different forms with controlled compositions and structures. Still, expertise in further advancement of the research results towards utilization in medical devices is lacking. The ExcellMater Horizon 2020 project aims to further advance the scientific and technological capacity of the Faculty in this area by twinning the knowledge from the three European partners, internationally leading institutions, with recognized expertise in biological characterization methods, intellectual property protection and utilization, evaluation of health technologies and regulatory aspects of medical devices. The aim of the project is also to increase visibility of scientific research and enhance collaboration of engineers at FTM with life scientists, medical doctors and pharmacists as well as with industry. Here, we will present some of the novel bioceramic and composite biomaterials developed at FTM aimed for potential applications in orthopaedics, dentistry, bone tissue engineering, and cancer research.
PB  - Consiglio Nazionale delle Ricerche Istituto di Struttura della Materia
C3  - Conference proceedings / 3rd biennial International Conference: Biomaterials and novel technologies for healthcare BIOMAH, October 18-21, 2022 Rome – Italy
T1  - The ExcellMater project for advancement of novel bioceramic and composite biomaterials for medical applications
EP  - 197
SP  - 196
UR  - https://hdl.handle.net/21.15107/rcub_technorep_6682
ER  - 
@conference{
author = "Obradović, Bojana and Stojkovska, Jasmina and Radovanović, Željko and Matić, Tamara and Petrović, Rada and Janaćković, Đorđe and Veljović, Đorđe",
year = "2022",
abstract = "Biomaterials engineering is one of the strongest research areas at the Faculty of Technology and Metallurgy (FTM), University of Belgrade including development of novel biomaterials for orthopaedic and dental applications. Especially, synthesis and physico-chemical characterization methods are well established resulting in variety of novel inorganic, polymer and composite biomaterials produced in different forms with controlled compositions and structures. Still, expertise in further advancement of the research results towards utilization in medical devices is lacking. The ExcellMater Horizon 2020 project aims to further advance the scientific and technological capacity of the Faculty in this area by twinning the knowledge from the three European partners, internationally leading institutions, with recognized expertise in biological characterization methods, intellectual property protection and utilization, evaluation of health technologies and regulatory aspects of medical devices. The aim of the project is also to increase visibility of scientific research and enhance collaboration of engineers at FTM with life scientists, medical doctors and pharmacists as well as with industry. Here, we will present some of the novel bioceramic and composite biomaterials developed at FTM aimed for potential applications in orthopaedics, dentistry, bone tissue engineering, and cancer research.",
publisher = "Consiglio Nazionale delle Ricerche Istituto di Struttura della Materia",
journal = "Conference proceedings / 3rd biennial International Conference: Biomaterials and novel technologies for healthcare BIOMAH, October 18-21, 2022 Rome – Italy",
title = "The ExcellMater project for advancement of novel bioceramic and composite biomaterials for medical applications",
pages = "197-196",
url = "https://hdl.handle.net/21.15107/rcub_technorep_6682"
}
Obradović, B., Stojkovska, J., Radovanović, Ž., Matić, T., Petrović, R., Janaćković, Đ.,& Veljović, Đ.. (2022). The ExcellMater project for advancement of novel bioceramic and composite biomaterials for medical applications. in Conference proceedings / 3rd biennial International Conference: Biomaterials and novel technologies for healthcare BIOMAH, October 18-21, 2022 Rome – Italy
Consiglio Nazionale delle Ricerche Istituto di Struttura della Materia., 196-197.
https://hdl.handle.net/21.15107/rcub_technorep_6682
Obradović B, Stojkovska J, Radovanović Ž, Matić T, Petrović R, Janaćković Đ, Veljović Đ. The ExcellMater project for advancement of novel bioceramic and composite biomaterials for medical applications. in Conference proceedings / 3rd biennial International Conference: Biomaterials and novel technologies for healthcare BIOMAH, October 18-21, 2022 Rome – Italy. 2022;:196-197.
https://hdl.handle.net/21.15107/rcub_technorep_6682 .
Obradović, Bojana, Stojkovska, Jasmina, Radovanović, Željko, Matić, Tamara, Petrović, Rada, Janaćković, Đorđe, Veljović, Đorđe, "The ExcellMater project for advancement of novel bioceramic and composite biomaterials for medical applications" in Conference proceedings / 3rd biennial International Conference: Biomaterials and novel technologies for healthcare BIOMAH, October 18-21, 2022 Rome – Italy (2022):196-197,
https://hdl.handle.net/21.15107/rcub_technorep_6682 .

Strong and tough, pH sensible, interpenetrating network hydrogels based on gelatin and poly(methacrylic acid)

Ugrinović, Vukašin; Panić, Vesna; Spasojević, Pavle; Seslija, Sanja; Bozic, Bojan; Petrović, Rada; Janaćković, Đorđe; Veljović, Đorđe

(2022)

TY  - JOUR
AU  - Ugrinović, Vukašin
AU  - Panić, Vesna
AU  - Spasojević, Pavle
AU  - Seslija, Sanja
AU  - Bozic, Bojan
AU  - Petrović, Rada
AU  - Janaćković, Đorđe
AU  - Veljović, Đorđe
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4984
AB  - Hydrogels are promising materials for biomedical applications due to highly hydrated, porous, permeable structure with possibility to accommodate living cells, drugs, or bioactive factors. In this paper, we reported poly(methacrylic acid) (PMAA)/gelatin IPN hydrogels, synthesized by free-radical polymerization, with adjustable mechanical, structural, physicochemical, and biological characteristics. The influence of methacrylic acid (MAA), gelatin, and cross-linker in the precursor solution on hydrogels properties was investigated. The increasing concentration of MAA, gelatin, and cross-linker led to better mechanical properties, lower porosity, and water content. The compressive mechanical properties of hydrogels were significantly better in comparison to a single-network PMAA hydrogel, while the obtained compressive strength values up to 16 MPa were comparable with tough hydrogels. The increasing concentration of MAA and cross-linker reduced fatigue resistance and degradability, while the increase in gelatin content acted in the opposite way. Swelling tests in different pH conditions demonstrated strong pH-sensibility of the hydrogels, which was more pronounced as MAA concentration was higher, and gelatin and cross-linker concentrations were lower. In addition, the hydrogels strongly promoted the proliferation of human periodontal ligament stem cells and MRC-5 cells as assayed by MTT assay.
T2  - Polymer Engineering and Science
T1  - Strong and tough, pH sensible, interpenetrating network hydrogels based on gelatin and poly(methacrylic acid)
DO  - 10.1002/pen.25870
ER  - 
@article{
author = "Ugrinović, Vukašin and Panić, Vesna and Spasojević, Pavle and Seslija, Sanja and Bozic, Bojan and Petrović, Rada and Janaćković, Đorđe and Veljović, Đorđe",
year = "2022",
abstract = "Hydrogels are promising materials for biomedical applications due to highly hydrated, porous, permeable structure with possibility to accommodate living cells, drugs, or bioactive factors. In this paper, we reported poly(methacrylic acid) (PMAA)/gelatin IPN hydrogels, synthesized by free-radical polymerization, with adjustable mechanical, structural, physicochemical, and biological characteristics. The influence of methacrylic acid (MAA), gelatin, and cross-linker in the precursor solution on hydrogels properties was investigated. The increasing concentration of MAA, gelatin, and cross-linker led to better mechanical properties, lower porosity, and water content. The compressive mechanical properties of hydrogels were significantly better in comparison to a single-network PMAA hydrogel, while the obtained compressive strength values up to 16 MPa were comparable with tough hydrogels. The increasing concentration of MAA and cross-linker reduced fatigue resistance and degradability, while the increase in gelatin content acted in the opposite way. Swelling tests in different pH conditions demonstrated strong pH-sensibility of the hydrogels, which was more pronounced as MAA concentration was higher, and gelatin and cross-linker concentrations were lower. In addition, the hydrogels strongly promoted the proliferation of human periodontal ligament stem cells and MRC-5 cells as assayed by MTT assay.",
journal = "Polymer Engineering and Science",
title = "Strong and tough, pH sensible, interpenetrating network hydrogels based on gelatin and poly(methacrylic acid)",
doi = "10.1002/pen.25870"
}
Ugrinović, V., Panić, V., Spasojević, P., Seslija, S., Bozic, B., Petrović, R., Janaćković, Đ.,& Veljović, Đ.. (2022). Strong and tough, pH sensible, interpenetrating network hydrogels based on gelatin and poly(methacrylic acid). in Polymer Engineering and Science.
https://doi.org/10.1002/pen.25870
Ugrinović V, Panić V, Spasojević P, Seslija S, Bozic B, Petrović R, Janaćković Đ, Veljović Đ. Strong and tough, pH sensible, interpenetrating network hydrogels based on gelatin and poly(methacrylic acid). in Polymer Engineering and Science. 2022;.
doi:10.1002/pen.25870 .
Ugrinović, Vukašin, Panić, Vesna, Spasojević, Pavle, Seslija, Sanja, Bozic, Bojan, Petrović, Rada, Janaćković, Đorđe, Veljović, Đorđe, "Strong and tough, pH sensible, interpenetrating network hydrogels based on gelatin and poly(methacrylic acid)" in Polymer Engineering and Science (2022),
https://doi.org/10.1002/pen.25870 . .
12
11

α-Tricalcium phosphate/fluorapatite-based cement – Promising dental root canal filling material

Kazuz, Abdul; Radovanović, Željko; Veljović, Đorđe; Kojić, Vesna; Jakimov, Dimitar; Vlajić-Tovilović, Tamara; Miletić, Vesna; Petrović, Rada; Janaćković, Đorđe

(University of Novi Sad, Faculty of Technology, 2022)

TY  - JOUR
AU  - Kazuz, Abdul
AU  - Radovanović, Željko
AU  - Veljović, Đorđe
AU  - Kojić, Vesna
AU  - Jakimov, Dimitar
AU  - Vlajić-Tovilović, Tamara
AU  - Miletić, Vesna
AU  - Petrović, Rada
AU  - Janaćković, Đorđe
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5143
AB  - α-Tricalcium phosphate/fluorapatite (α-TCP/FAp) mixed powders were prepared in order to obtain dental root canal filling cements. Different liquids for cement pastes have been investigated and the most suitable one for obtaining rheologically optimal pastes was chosen for further analysis. Morphological changes in the cement materials as a consequence of the formation of hydroxyapatite (HAp) after the immersion in a simulated body fluid (SBF), an influence on the cell viability, and final success of the filling were investigated by field emission scanning electron microscopy. Treatment of the α-TCP/FAp mixtures in SBF at 37 °C resulted in a complete transformation of α-TCP into HAp after 10 days, while the exposure of MRC-5 human and L929 animal fibroblast cells to the cement showed complete absence of cytotoxicity. The root canal of an extracted tooth was filled with the α-TCP/FAp cement containing 5 wt.% of FAp and relatively strong adhesion between the cement and dentine was observed after 48 h. The same cement material was immersed during 10 days in SBF and after that both human and animal fibroblast cells during in vitro MTT tests showed higher cell viability compared to the control sample. These findings lead to a conclusion that the α-TCP/FAp based cement demonstrates potential for further development towards dental cement application.
PB  - University of Novi Sad, Faculty of Technology
T2  - Processing and Application of Ceramics
T1  - α-Tricalcium phosphate/fluorapatite-based cement – Promising dental root canal filling material
EP  - 29
IS  - 1
SP  - 22
VL  - 16
DO  - 10.2298/PAC2201022K
ER  - 
@article{
author = "Kazuz, Abdul and Radovanović, Željko and Veljović, Đorđe and Kojić, Vesna and Jakimov, Dimitar and Vlajić-Tovilović, Tamara and Miletić, Vesna and Petrović, Rada and Janaćković, Đorđe",
year = "2022",
abstract = "α-Tricalcium phosphate/fluorapatite (α-TCP/FAp) mixed powders were prepared in order to obtain dental root canal filling cements. Different liquids for cement pastes have been investigated and the most suitable one for obtaining rheologically optimal pastes was chosen for further analysis. Morphological changes in the cement materials as a consequence of the formation of hydroxyapatite (HAp) after the immersion in a simulated body fluid (SBF), an influence on the cell viability, and final success of the filling were investigated by field emission scanning electron microscopy. Treatment of the α-TCP/FAp mixtures in SBF at 37 °C resulted in a complete transformation of α-TCP into HAp after 10 days, while the exposure of MRC-5 human and L929 animal fibroblast cells to the cement showed complete absence of cytotoxicity. The root canal of an extracted tooth was filled with the α-TCP/FAp cement containing 5 wt.% of FAp and relatively strong adhesion between the cement and dentine was observed after 48 h. The same cement material was immersed during 10 days in SBF and after that both human and animal fibroblast cells during in vitro MTT tests showed higher cell viability compared to the control sample. These findings lead to a conclusion that the α-TCP/FAp based cement demonstrates potential for further development towards dental cement application.",
publisher = "University of Novi Sad, Faculty of Technology",
journal = "Processing and Application of Ceramics",
title = "α-Tricalcium phosphate/fluorapatite-based cement – Promising dental root canal filling material",
pages = "29-22",
number = "1",
volume = "16",
doi = "10.2298/PAC2201022K"
}
Kazuz, A., Radovanović, Ž., Veljović, Đ., Kojić, V., Jakimov, D., Vlajić-Tovilović, T., Miletić, V., Petrović, R.,& Janaćković, Đ.. (2022). α-Tricalcium phosphate/fluorapatite-based cement – Promising dental root canal filling material. in Processing and Application of Ceramics
University of Novi Sad, Faculty of Technology., 16(1), 22-29.
https://doi.org/10.2298/PAC2201022K
Kazuz A, Radovanović Ž, Veljović Đ, Kojić V, Jakimov D, Vlajić-Tovilović T, Miletić V, Petrović R, Janaćković Đ. α-Tricalcium phosphate/fluorapatite-based cement – Promising dental root canal filling material. in Processing and Application of Ceramics. 2022;16(1):22-29.
doi:10.2298/PAC2201022K .
Kazuz, Abdul, Radovanović, Željko, Veljović, Đorđe, Kojić, Vesna, Jakimov, Dimitar, Vlajić-Tovilović, Tamara, Miletić, Vesna, Petrović, Rada, Janaćković, Đorđe, "α-Tricalcium phosphate/fluorapatite-based cement – Promising dental root canal filling material" in Processing and Application of Ceramics, 16, no. 1 (2022):22-29,
https://doi.org/10.2298/PAC2201022K . .

C-doped TiO2 nanotubes with pulsed laser deposited Bi2O3 films for photovoltaic application

Bjelajac, Anđelika; Petrović, Rada; Stan, George E.; Socol, Gabriel; Mihailescu, Andreea; Mihailescu, Ion N.; Veltruska, Katerina; Matolin, Vladimir; Siketic, Zdravko; Provatas, George; Jaksic, Milko; Janaćković, Đorđe

(2022)

TY  - JOUR
AU  - Bjelajac, Anđelika
AU  - Petrović, Rada
AU  - Stan, George E.
AU  - Socol, Gabriel
AU  - Mihailescu, Andreea
AU  - Mihailescu, Ion N.
AU  - Veltruska, Katerina
AU  - Matolin, Vladimir
AU  - Siketic, Zdravko
AU  - Provatas, George
AU  - Jaksic, Milko
AU  - Janaćković, Đorđe
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4996
AB  - Anodization was used to obtain a nanotubular TiO2 photoanode on F-SnO2 glass. Subsequent annealing in the CH4 atmosphere promoted the C-doping and improved the crystallinity of the TiO2 nanotubes. The pulsed laser deposition was applied to cover the nanotubes with Bi2O3, serving as a hole transport material. X-ray photoelectron spectroscopy analyses of the doped samples reveal a shift in the valence band's maximum position towards lower binding energy as compared to those observed for the undoped samples (annealed in the air). The doping positively affects the absorption by shifting the absorption edge to 567 nm. I-V measurements under illumination show that the C-doping of TiO2 increases the current density following the absorbance results. The highest open circuit voltage was reached for the samples with the 300 degrees C-deposited Bi2O3 layer, pointing to better quality of the p-n junction, hence of the contact between Bi2O3 and TiO2. This in situ annealing provided the formation of close contact between Bi2O3 and TiO2, which enabled a faster charge transport as compared to the contact obtained with no annealing or even with post annealing.
T2  - Ceramics International
T1  - C-doped TiO2 nanotubes with pulsed laser deposited Bi2O3 films for photovoltaic application
EP  - 4657
IS  - 4
SP  - 4649
VL  - 48
DO  - 10.1016/j.ceramint.2021.10.251
ER  - 
@article{
author = "Bjelajac, Anđelika and Petrović, Rada and Stan, George E. and Socol, Gabriel and Mihailescu, Andreea and Mihailescu, Ion N. and Veltruska, Katerina and Matolin, Vladimir and Siketic, Zdravko and Provatas, George and Jaksic, Milko and Janaćković, Đorđe",
year = "2022",
abstract = "Anodization was used to obtain a nanotubular TiO2 photoanode on F-SnO2 glass. Subsequent annealing in the CH4 atmosphere promoted the C-doping and improved the crystallinity of the TiO2 nanotubes. The pulsed laser deposition was applied to cover the nanotubes with Bi2O3, serving as a hole transport material. X-ray photoelectron spectroscopy analyses of the doped samples reveal a shift in the valence band's maximum position towards lower binding energy as compared to those observed for the undoped samples (annealed in the air). The doping positively affects the absorption by shifting the absorption edge to 567 nm. I-V measurements under illumination show that the C-doping of TiO2 increases the current density following the absorbance results. The highest open circuit voltage was reached for the samples with the 300 degrees C-deposited Bi2O3 layer, pointing to better quality of the p-n junction, hence of the contact between Bi2O3 and TiO2. This in situ annealing provided the formation of close contact between Bi2O3 and TiO2, which enabled a faster charge transport as compared to the contact obtained with no annealing or even with post annealing.",
journal = "Ceramics International",
title = "C-doped TiO2 nanotubes with pulsed laser deposited Bi2O3 films for photovoltaic application",
pages = "4657-4649",
number = "4",
volume = "48",
doi = "10.1016/j.ceramint.2021.10.251"
}
Bjelajac, A., Petrović, R., Stan, G. E., Socol, G., Mihailescu, A., Mihailescu, I. N., Veltruska, K., Matolin, V., Siketic, Z., Provatas, G., Jaksic, M.,& Janaćković, Đ.. (2022). C-doped TiO2 nanotubes with pulsed laser deposited Bi2O3 films for photovoltaic application. in Ceramics International, 48(4), 4649-4657.
https://doi.org/10.1016/j.ceramint.2021.10.251
Bjelajac A, Petrović R, Stan GE, Socol G, Mihailescu A, Mihailescu IN, Veltruska K, Matolin V, Siketic Z, Provatas G, Jaksic M, Janaćković Đ. C-doped TiO2 nanotubes with pulsed laser deposited Bi2O3 films for photovoltaic application. in Ceramics International. 2022;48(4):4649-4657.
doi:10.1016/j.ceramint.2021.10.251 .
Bjelajac, Anđelika, Petrović, Rada, Stan, George E., Socol, Gabriel, Mihailescu, Andreea, Mihailescu, Ion N., Veltruska, Katerina, Matolin, Vladimir, Siketic, Zdravko, Provatas, George, Jaksic, Milko, Janaćković, Đorđe, "C-doped TiO2 nanotubes with pulsed laser deposited Bi2O3 films for photovoltaic application" in Ceramics International, 48, no. 4 (2022):4649-4657,
https://doi.org/10.1016/j.ceramint.2021.10.251 . .
4
3

The influence of cobalt loading on electrocatalytic performance toward glucose oxidation of pillared montmorillonite-supported cobalt

Milovanović, Biljana; Marinović, Sanja; Vuković, Zorica; Milutinović-Nikolić, Aleksandra; Petrović, Rada; Banković, Predrag; Mudrinić, Tihana

(Elsevier B.V., 2022)

TY  - JOUR
AU  - Milovanović, Biljana
AU  - Marinović, Sanja
AU  - Vuković, Zorica
AU  - Milutinović-Nikolić, Aleksandra
AU  - Petrović, Rada
AU  - Banković, Predrag
AU  - Mudrinić, Tihana
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5127
AB  - In this paper, the influence of cobalt loading in pillared clay-supported cobalt materials on their electrocatalytic performance toward glucose oxidation was investigated. A series of aluminum-pillared montmorillonite clay (AP) materials with different cobalt loadings (x%CoAP, x = 1, 3, 5, and 10 wt%) was synthesized using the incipient wetness impregnation method. The X-ray powder diffraction (XRPD), inductively coupled plasma optical emission spectroscopy (ICP-OES), Fourier transform infrared spectroscopy (FT-IR), field emission scanning electron microscopy coupled with energy dispersive X-ray spectrometry (FE-SEM/EDX), high resolution transmission electron microscopy (HR-TEM) coupled with EDX, X-ray photoelectron spectroscopy (XPS), and low temperature N2 physisorption, were employed for characterization of the materials. The incorporation of cobalt in porous structure of pillared montmorillonite was confirmed. The synthesized materials (x%CoAP) were used for modification of carbon paste (CP) electrode and tested in reaction of glucose electrooxidation. The electrochemical measurements were conducted using cyclic voltammetry and chronoamperometry in a 1 M NaOH solution, with or without glucose. The results showed that the increase of cobalt loading improved the electrode performance toward glucose. The highest current response and sensitivity were obtained for the CP-5%CoAP electrode. A lower electrode performance of CP-10%CoAP was correlated with the presence of higher quantities of Co3O4 (confirmed by XRPD and XPS) in the electrode material. The mechanism and kinetics of glucose electrooxidation was studied in more details for the best performing electrode (CP-5%CoAP). It was found that the process was diffusion-controlled and the diffusion coefficient was determined. The charge transfer coefficient and catalytic rate constant were calculated. The electrode exhibited satisfactory repeatability, reproducibility, stability, and selectivity. The obtained results showed that appropriate amount of cobalt loading in pillared clay led to the obtainment of non-enzymatic electrode materials suitable for sustainable and green glucose sensors.
PB  - Elsevier B.V.
T2  - Journal of Electroanalytical Chemistry
T1  - The influence of cobalt loading on electrocatalytic performance toward glucose oxidation of pillared montmorillonite-supported cobalt
SP  - 116332
VL  - 915
DO  - 10.1016/j.jelechem.2022.116332
ER  - 
@article{
author = "Milovanović, Biljana and Marinović, Sanja and Vuković, Zorica and Milutinović-Nikolić, Aleksandra and Petrović, Rada and Banković, Predrag and Mudrinić, Tihana",
year = "2022",
abstract = "In this paper, the influence of cobalt loading in pillared clay-supported cobalt materials on their electrocatalytic performance toward glucose oxidation was investigated. A series of aluminum-pillared montmorillonite clay (AP) materials with different cobalt loadings (x%CoAP, x = 1, 3, 5, and 10 wt%) was synthesized using the incipient wetness impregnation method. The X-ray powder diffraction (XRPD), inductively coupled plasma optical emission spectroscopy (ICP-OES), Fourier transform infrared spectroscopy (FT-IR), field emission scanning electron microscopy coupled with energy dispersive X-ray spectrometry (FE-SEM/EDX), high resolution transmission electron microscopy (HR-TEM) coupled with EDX, X-ray photoelectron spectroscopy (XPS), and low temperature N2 physisorption, were employed for characterization of the materials. The incorporation of cobalt in porous structure of pillared montmorillonite was confirmed. The synthesized materials (x%CoAP) were used for modification of carbon paste (CP) electrode and tested in reaction of glucose electrooxidation. The electrochemical measurements were conducted using cyclic voltammetry and chronoamperometry in a 1 M NaOH solution, with or without glucose. The results showed that the increase of cobalt loading improved the electrode performance toward glucose. The highest current response and sensitivity were obtained for the CP-5%CoAP electrode. A lower electrode performance of CP-10%CoAP was correlated with the presence of higher quantities of Co3O4 (confirmed by XRPD and XPS) in the electrode material. The mechanism and kinetics of glucose electrooxidation was studied in more details for the best performing electrode (CP-5%CoAP). It was found that the process was diffusion-controlled and the diffusion coefficient was determined. The charge transfer coefficient and catalytic rate constant were calculated. The electrode exhibited satisfactory repeatability, reproducibility, stability, and selectivity. The obtained results showed that appropriate amount of cobalt loading in pillared clay led to the obtainment of non-enzymatic electrode materials suitable for sustainable and green glucose sensors.",
publisher = "Elsevier B.V.",
journal = "Journal of Electroanalytical Chemistry",
title = "The influence of cobalt loading on electrocatalytic performance toward glucose oxidation of pillared montmorillonite-supported cobalt",
pages = "116332",
volume = "915",
doi = "10.1016/j.jelechem.2022.116332"
}
Milovanović, B., Marinović, S., Vuković, Z., Milutinović-Nikolić, A., Petrović, R., Banković, P.,& Mudrinić, T.. (2022). The influence of cobalt loading on electrocatalytic performance toward glucose oxidation of pillared montmorillonite-supported cobalt. in Journal of Electroanalytical Chemistry
Elsevier B.V.., 915, 116332.
https://doi.org/10.1016/j.jelechem.2022.116332
Milovanović B, Marinović S, Vuković Z, Milutinović-Nikolić A, Petrović R, Banković P, Mudrinić T. The influence of cobalt loading on electrocatalytic performance toward glucose oxidation of pillared montmorillonite-supported cobalt. in Journal of Electroanalytical Chemistry. 2022;915:116332.
doi:10.1016/j.jelechem.2022.116332 .
Milovanović, Biljana, Marinović, Sanja, Vuković, Zorica, Milutinović-Nikolić, Aleksandra, Petrović, Rada, Banković, Predrag, Mudrinić, Tihana, "The influence of cobalt loading on electrocatalytic performance toward glucose oxidation of pillared montmorillonite-supported cobalt" in Journal of Electroanalytical Chemistry, 915 (2022):116332,
https://doi.org/10.1016/j.jelechem.2022.116332 . .
1
6
6

Poboljšanje apsorpcionih svojstava TiO2 nanocevi pomoću CH3NH3PbBr3 perovskita kao fotosenzitivizatora

Stefanović, Milica P.; Vujančević, Jelena D.; Petrović, Rada P.; Stevanović, Marija S.; Janaćković, Đorđe T.

(Savez inženjera i tehničara Srbije, 2022)

TY  - JOUR
AU  - Stefanović, Milica P.
AU  - Vujančević, Jelena D.
AU  - Petrović, Rada P.
AU  - Stevanović, Marija S.
AU  - Janaćković, Đorđe T.
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5274
AB  - Organsko-neorganski perovskiti su privukli veliku pažnju istraživača zbog visoke apsorpcije u vidljivom
delu spektra i jeftine proizvodnje. Apsorbovanjem svetlosti dolazi do stvaranja para elektron-šupljina.
U cilju razdvajanja nosilaca naelektrisanja, perovskit se kombinuje sa TiO2 što ima za posledicu
spontani prelazak elektrona sa perovskita na TiO2. Ovo istraživanje je imalo za cilj povećanje dodirne
površine između nanocevi TiO2 i perovskita punjenjem nanocevi perovskitnim materijalom. Rastvor
metilamonijum olovo(II)-bromidnog perovskita (CH3NH3PbBr3) u dimetilformamidu (DMF) je
deponovan na anodizacijom sintetisane TiO2 nanocevi pomoću sistema visokog vakuuma i inertnog
gasa. Postupak je uključivao degazaciju uzorka u visokom vakuumu u trajanju od 3 h na 200 °C, hlađenje
uzorka, a zatim nanošenje rastvora CH3NH3PbBr3 u DMF-u, uz naknadni tretman inertnim gasom (N2)
u cilju ostvarenja natpritiska, što je omogućilo punjenje nanocevi perovskitnim materijalom. Difuznorefleksiona spektroskopija pokazala je da taloženje CH3NH3PbBr3 poboljšava apsorpciona svojstva
TiO2 nanocevi. I-V karakteristike uzorka pokazale su fotodiodno ponašanje i histerezisnu krivu, koja je
karakteristična za perovskitni materijal. Vrednost struje uzorka snimljenim pod vidljivom svetlošću
iznosila je 46 μA bez primene prednapona, dok je nakon primene prednapona iznosila 76 μA. Rezultati
rada ukazuju da je napravljena perovskitna fotodioda sa povećanim kontaktom između TiO2 i perovskita,
koja predstavlja osnovu za buduću konstrukciju solarnih ćelija.
AB  - Organic-inorganic perovskites have attracted much attention from researchers due to their high absorption in the visible part of the spectrum and low-cost fabrication. After absorption of the light, electron-hole pairs are formed. To separate electron-hole pairs and reduce recombination, perovskite is combined with TiO2 which has as a consequence, a spontaneous transition of electrons from perovskite to TiO2. This research aims to increase the contact surface of perovskite and TiO2 nanotubes by filling the nanotubes with perovskite material. The solution of methylammonium lead bromide perovskite (CH3NH3PbBr3) in dimethylformamide (DMF) was deposited on anodically synthesized TiO2 nanotubes by the high vacuum system and inert gas. The procedure involved degassation of the sample under high vacuum for 3 h at 200 °C, cooling of the sample, and putting the solution of CH3NH3PbBr3 in DMF, after which it was treated with inert gas (N2), as an overpressure which enabled the filling of the nanotubes with perovskite material. The diffuse reflectance spectroscopy measurement of the sample proved that deposition of CH3NH3PbBr3 improves the absorption properties of TiO2 nanotubes. The I-V characteristics of the sample showed photodiode behavior and characteristic hysteresis curve for perovskite material. The value of current under visible light for the sample without preconditioning was 46 mA, while after preconditioning value of current was 76 mA. The results indicate that a perovskite photodiode with increased contact between TiO2 and perovskite was made, which is the basis for future solar cell construction.
PB  - Savez inženjera i tehničara Srbije
T2  - Tehnika
T1  - Poboljšanje apsorpcionih svojstava TiO2 nanocevi pomoću CH3NH3PbBr3 perovskita kao fotosenzitivizatora
T1  - Improvement of absorption properties of TiO2 nanotubes by using CH3NH3PbBr3 perovskite as photosensitizer
EP  - 21
IS  - 1
SP  - 15
VL  - 31
DO  - 10.5937/tehnika2201015S
ER  - 
@article{
author = "Stefanović, Milica P. and Vujančević, Jelena D. and Petrović, Rada P. and Stevanović, Marija S. and Janaćković, Đorđe T.",
year = "2022",
abstract = "Organsko-neorganski perovskiti su privukli veliku pažnju istraživača zbog visoke apsorpcije u vidljivom
delu spektra i jeftine proizvodnje. Apsorbovanjem svetlosti dolazi do stvaranja para elektron-šupljina.
U cilju razdvajanja nosilaca naelektrisanja, perovskit se kombinuje sa TiO2 što ima za posledicu
spontani prelazak elektrona sa perovskita na TiO2. Ovo istraživanje je imalo za cilj povećanje dodirne
površine između nanocevi TiO2 i perovskita punjenjem nanocevi perovskitnim materijalom. Rastvor
metilamonijum olovo(II)-bromidnog perovskita (CH3NH3PbBr3) u dimetilformamidu (DMF) je
deponovan na anodizacijom sintetisane TiO2 nanocevi pomoću sistema visokog vakuuma i inertnog
gasa. Postupak je uključivao degazaciju uzorka u visokom vakuumu u trajanju od 3 h na 200 °C, hlađenje
uzorka, a zatim nanošenje rastvora CH3NH3PbBr3 u DMF-u, uz naknadni tretman inertnim gasom (N2)
u cilju ostvarenja natpritiska, što je omogućilo punjenje nanocevi perovskitnim materijalom. Difuznorefleksiona spektroskopija pokazala je da taloženje CH3NH3PbBr3 poboljšava apsorpciona svojstva
TiO2 nanocevi. I-V karakteristike uzorka pokazale su fotodiodno ponašanje i histerezisnu krivu, koja je
karakteristična za perovskitni materijal. Vrednost struje uzorka snimljenim pod vidljivom svetlošću
iznosila je 46 μA bez primene prednapona, dok je nakon primene prednapona iznosila 76 μA. Rezultati
rada ukazuju da je napravljena perovskitna fotodioda sa povećanim kontaktom između TiO2 i perovskita,
koja predstavlja osnovu za buduću konstrukciju solarnih ćelija., Organic-inorganic perovskites have attracted much attention from researchers due to their high absorption in the visible part of the spectrum and low-cost fabrication. After absorption of the light, electron-hole pairs are formed. To separate electron-hole pairs and reduce recombination, perovskite is combined with TiO2 which has as a consequence, a spontaneous transition of electrons from perovskite to TiO2. This research aims to increase the contact surface of perovskite and TiO2 nanotubes by filling the nanotubes with perovskite material. The solution of methylammonium lead bromide perovskite (CH3NH3PbBr3) in dimethylformamide (DMF) was deposited on anodically synthesized TiO2 nanotubes by the high vacuum system and inert gas. The procedure involved degassation of the sample under high vacuum for 3 h at 200 °C, cooling of the sample, and putting the solution of CH3NH3PbBr3 in DMF, after which it was treated with inert gas (N2), as an overpressure which enabled the filling of the nanotubes with perovskite material. The diffuse reflectance spectroscopy measurement of the sample proved that deposition of CH3NH3PbBr3 improves the absorption properties of TiO2 nanotubes. The I-V characteristics of the sample showed photodiode behavior and characteristic hysteresis curve for perovskite material. The value of current under visible light for the sample without preconditioning was 46 mA, while after preconditioning value of current was 76 mA. The results indicate that a perovskite photodiode with increased contact between TiO2 and perovskite was made, which is the basis for future solar cell construction.",
publisher = "Savez inženjera i tehničara Srbije",
journal = "Tehnika",
title = "Poboljšanje apsorpcionih svojstava TiO2 nanocevi pomoću CH3NH3PbBr3 perovskita kao fotosenzitivizatora, Improvement of absorption properties of TiO2 nanotubes by using CH3NH3PbBr3 perovskite as photosensitizer",
pages = "21-15",
number = "1",
volume = "31",
doi = "10.5937/tehnika2201015S"
}
Stefanović, M. P., Vujančević, J. D., Petrović, R. P., Stevanović, M. S.,& Janaćković, Đ. T.. (2022). Poboljšanje apsorpcionih svojstava TiO2 nanocevi pomoću CH3NH3PbBr3 perovskita kao fotosenzitivizatora. in Tehnika
Savez inženjera i tehničara Srbije., 31(1), 15-21.
https://doi.org/10.5937/tehnika2201015S
Stefanović MP, Vujančević JD, Petrović RP, Stevanović MS, Janaćković ĐT. Poboljšanje apsorpcionih svojstava TiO2 nanocevi pomoću CH3NH3PbBr3 perovskita kao fotosenzitivizatora. in Tehnika. 2022;31(1):15-21.
doi:10.5937/tehnika2201015S .
Stefanović, Milica P., Vujančević, Jelena D., Petrović, Rada P., Stevanović, Marija S., Janaćković, Đorđe T., "Poboljšanje apsorpcionih svojstava TiO2 nanocevi pomoću CH3NH3PbBr3 perovskita kao fotosenzitivizatora" in Tehnika, 31, no. 1 (2022):15-21,
https://doi.org/10.5937/tehnika2201015S . .

Promising Hydroxyapatite/Nifuroksazid Conjugate

Radovanović, Željko; Mihajlovski, Katarina; Radovanović, Lidija; Petrović, Rada; Janaćković, Đorđe

(Belgrade : Materials Research Society of Serbia, 2021)

TY  - CONF
AU  - Radovanović, Željko
AU  - Mihajlovski, Katarina
AU  - Radovanović, Lidija
AU  - Petrović, Rada
AU  - Janaćković, Đorđe
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7399
AB  - The synergistic effect of two materials is a desirable phenomenon when designing a conjugate
material. Synthetic Hydroxyapatite (HAp, Ca10(PO4)6(OH)2) is very similar to the inorganic part of
bones and teeth of mammals. It is a well-known biomaterial with good biocompatibility,
osteoconductivity and bioactivity. Nifuroxazide (NFX, C12H9N3O5) is a broad-spectrum antibacterial
drug and poorly soluble in water. Nano HAp and NFX were mixed and homogenized in rotovapor
giving as a result HAp/NFX conjugate. All materials were analyzed by Fourier transform infrared
spectroscopy (FTIR), Field emission scanning electron microscopy (FESEM), X-Ray diffraction
(XRD), Thermogravimetry (TG) and Brunauer–Emmett–Teller (BET) method. The in vitro
antibacterial activities of HAp, NFX and HAp/NFX were examined against Gram-positive bacteria
Staphylococcus aureus, Gram-negative bacteria Escherichia coli and yeast Candida albicans. In vitro
drug release in simulated stomach acid and intestinal fluid showed a much faster release of NFX from
HAp surface than those of raw drug. Afore mentioned analyses showed the unique properties of the
HAp/NFX conjugate and introduced it as particularly prominent drug carrier.
PB  - Belgrade : Materials Research Society of Serbia
C3  - Programme and the Book of abstracts / Twenty-second Annual Conference YUCOMAT 2021 Herceg Novi, Montenegro, August 30 - September 3, 2021
T1  - Promising Hydroxyapatite/Nifuroksazid Conjugate
SP  - 126
UR  - https://hdl.handle.net/21.15107/rcub_technorep_7399
ER  - 
@conference{
author = "Radovanović, Željko and Mihajlovski, Katarina and Radovanović, Lidija and Petrović, Rada and Janaćković, Đorđe",
year = "2021",
abstract = "The synergistic effect of two materials is a desirable phenomenon when designing a conjugate
material. Synthetic Hydroxyapatite (HAp, Ca10(PO4)6(OH)2) is very similar to the inorganic part of
bones and teeth of mammals. It is a well-known biomaterial with good biocompatibility,
osteoconductivity and bioactivity. Nifuroxazide (NFX, C12H9N3O5) is a broad-spectrum antibacterial
drug and poorly soluble in water. Nano HAp and NFX were mixed and homogenized in rotovapor
giving as a result HAp/NFX conjugate. All materials were analyzed by Fourier transform infrared
spectroscopy (FTIR), Field emission scanning electron microscopy (FESEM), X-Ray diffraction
(XRD), Thermogravimetry (TG) and Brunauer–Emmett–Teller (BET) method. The in vitro
antibacterial activities of HAp, NFX and HAp/NFX were examined against Gram-positive bacteria
Staphylococcus aureus, Gram-negative bacteria Escherichia coli and yeast Candida albicans. In vitro
drug release in simulated stomach acid and intestinal fluid showed a much faster release of NFX from
HAp surface than those of raw drug. Afore mentioned analyses showed the unique properties of the
HAp/NFX conjugate and introduced it as particularly prominent drug carrier.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Programme and the Book of abstracts / Twenty-second Annual Conference YUCOMAT 2021 Herceg Novi, Montenegro, August 30 - September 3, 2021",
title = "Promising Hydroxyapatite/Nifuroksazid Conjugate",
pages = "126",
url = "https://hdl.handle.net/21.15107/rcub_technorep_7399"
}
Radovanović, Ž., Mihajlovski, K., Radovanović, L., Petrović, R.,& Janaćković, Đ.. (2021). Promising Hydroxyapatite/Nifuroksazid Conjugate. in Programme and the Book of abstracts / Twenty-second Annual Conference YUCOMAT 2021 Herceg Novi, Montenegro, August 30 - September 3, 2021
Belgrade : Materials Research Society of Serbia., 126.
https://hdl.handle.net/21.15107/rcub_technorep_7399
Radovanović Ž, Mihajlovski K, Radovanović L, Petrović R, Janaćković Đ. Promising Hydroxyapatite/Nifuroksazid Conjugate. in Programme and the Book of abstracts / Twenty-second Annual Conference YUCOMAT 2021 Herceg Novi, Montenegro, August 30 - September 3, 2021. 2021;:126.
https://hdl.handle.net/21.15107/rcub_technorep_7399 .
Radovanović, Željko, Mihajlovski, Katarina, Radovanović, Lidija, Petrović, Rada, Janaćković, Đorđe, "Promising Hydroxyapatite/Nifuroksazid Conjugate" in Programme and the Book of abstracts / Twenty-second Annual Conference YUCOMAT 2021 Herceg Novi, Montenegro, August 30 - September 3, 2021 (2021):126,
https://hdl.handle.net/21.15107/rcub_technorep_7399 .

Hybrid material based on subgleba of mosaic puffball mushroom (Handkea utriformis) as an adsorbent for heavy metal removal from aqueous solutions

Milosevic, Dragana; Levic, Steva; Lazarević, Slavica; Veličković, Zlate; Marinković, Aleksandar; Petrović, Rada; Petrović, Predrag

(2021)

TY  - JOUR
AU  - Milosevic, Dragana
AU  - Levic, Steva
AU  - Lazarević, Slavica
AU  - Veličković, Zlate
AU  - Marinković, Aleksandar
AU  - Petrović, Rada
AU  - Petrović, Predrag
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4788
AB  - The alkali treated subglebal tissue of the mosaic puffball (Handkea utriformis) (Sa) and Sa modified with hydroxyapatite (Sa-HAp), obtained by successive ionic layer adsorption and reaction (SILAR) method, were used for the removal of Pb2+, Cd2+ and Ni2+ from aqueous solution. The materials were characterized by FT-IR, Raman, SEM and EDS analysis and by determination of pH(PZC). The adsorption performances of Sa and SaHAp were assessed in batch experiments at different pH, contact times, temperatures and mass of the adsorbent. Different models of adsorption isotherms were used, and the best fit was obtained with the Langmuir model. Maximum adsorption capacities of Sa towards Pb2+, Cd2+ and Ni2+ were 44.82, 15.54 and 17.21 mg g(-1), while for Sa-HAp were 79.55, 52.59 and 45.01 mg g(-1), respectively. Kinetic data were well fitted by a pseudo second-order model, while thermodynamic studies disclose spontaneous and endothermic adsorption process. The Sa-Hap was successfully regenerated with 1 M NaCl and after the fifth desorption cycle and 10 h achieved 82.9, 69.7 and 60.4 %, while for 0.5 M NaCl + 0.5 M NaOH and 1 h was 78.3, 64.1, 57.5 % of desorbed Pb2+, Cd2+ and Ni2+, respectively. The competitive study and results from a column system confirmed good applicability of Sa-HAp adsorbent.
T2  - Journal of Environmental Management
T1  - Hybrid material based on subgleba of mosaic puffball mushroom (Handkea utriformis) as an adsorbent for heavy metal removal from aqueous solutions
VL  - 297
DO  - 10.1016/j.jenvman.2021.113358
ER  - 
@article{
author = "Milosevic, Dragana and Levic, Steva and Lazarević, Slavica and Veličković, Zlate and Marinković, Aleksandar and Petrović, Rada and Petrović, Predrag",
year = "2021",
abstract = "The alkali treated subglebal tissue of the mosaic puffball (Handkea utriformis) (Sa) and Sa modified with hydroxyapatite (Sa-HAp), obtained by successive ionic layer adsorption and reaction (SILAR) method, were used for the removal of Pb2+, Cd2+ and Ni2+ from aqueous solution. The materials were characterized by FT-IR, Raman, SEM and EDS analysis and by determination of pH(PZC). The adsorption performances of Sa and SaHAp were assessed in batch experiments at different pH, contact times, temperatures and mass of the adsorbent. Different models of adsorption isotherms were used, and the best fit was obtained with the Langmuir model. Maximum adsorption capacities of Sa towards Pb2+, Cd2+ and Ni2+ were 44.82, 15.54 and 17.21 mg g(-1), while for Sa-HAp were 79.55, 52.59 and 45.01 mg g(-1), respectively. Kinetic data were well fitted by a pseudo second-order model, while thermodynamic studies disclose spontaneous and endothermic adsorption process. The Sa-Hap was successfully regenerated with 1 M NaCl and after the fifth desorption cycle and 10 h achieved 82.9, 69.7 and 60.4 %, while for 0.5 M NaCl + 0.5 M NaOH and 1 h was 78.3, 64.1, 57.5 % of desorbed Pb2+, Cd2+ and Ni2+, respectively. The competitive study and results from a column system confirmed good applicability of Sa-HAp adsorbent.",
journal = "Journal of Environmental Management",
title = "Hybrid material based on subgleba of mosaic puffball mushroom (Handkea utriformis) as an adsorbent for heavy metal removal from aqueous solutions",
volume = "297",
doi = "10.1016/j.jenvman.2021.113358"
}
Milosevic, D., Levic, S., Lazarević, S., Veličković, Z., Marinković, A., Petrović, R.,& Petrović, P.. (2021). Hybrid material based on subgleba of mosaic puffball mushroom (Handkea utriformis) as an adsorbent for heavy metal removal from aqueous solutions. in Journal of Environmental Management, 297.
https://doi.org/10.1016/j.jenvman.2021.113358
Milosevic D, Levic S, Lazarević S, Veličković Z, Marinković A, Petrović R, Petrović P. Hybrid material based on subgleba of mosaic puffball mushroom (Handkea utriformis) as an adsorbent for heavy metal removal from aqueous solutions. in Journal of Environmental Management. 2021;297.
doi:10.1016/j.jenvman.2021.113358 .
Milosevic, Dragana, Levic, Steva, Lazarević, Slavica, Veličković, Zlate, Marinković, Aleksandar, Petrović, Rada, Petrović, Predrag, "Hybrid material based on subgleba of mosaic puffball mushroom (Handkea utriformis) as an adsorbent for heavy metal removal from aqueous solutions" in Journal of Environmental Management, 297 (2021),
https://doi.org/10.1016/j.jenvman.2021.113358 . .
6
5

SIMULTANEOUS ADSORPTION OF COPER IONS AND ANTIBIOTICS CIPROFLOXACIN FROM WATER AT SEPIOLITE

Lazarević, Slavica; Janković-Častvan, Ivona; Janaćković, Đorđe; Petrović, Rada

(2021)

TY  - CONF
AU  - Lazarević, Slavica
AU  - Janković-Častvan, Ivona
AU  - Janaćković, Đorđe
AU  - Petrović, Rada
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5922
AB  - The wide use of antibiotics, the increase in chemical industry and traffic, as well as the medical industry resulted in formation of wastewater, which contains complexes of heavy metals and antibiotics. Earlier researches have shown that clay minerals had a significant large adsorption capacity for heavy metal ions, and recently examinations are focused on investigation of the possibility of treatment of water with presence of antibiotics and heavy metal ions. In this paper, the possibility of application of natural mineral sepolite for simultaneous removal of antibiotics of ciprofloxacin and copper ions from aqueous solutions. It was shown that at the initial pH of 6,0±0,1 presence of the copper ions (~ 20 mg/dm3) increased the adsorption capacity of ciprofloxacin onto sepiolite, while the presence of ciprofloxacin, had no significant influence on the removal capacity of Cu2+ ions. The results of adsorption isotherms indicated significant adsorption capacity for both, ciprofloxacin and Cu2+ ions, ie. it was shown that natural mineral sepiolite was very effective adsorbent for the simultaneous removal of ciprofloxacin and Cu2+ ions as a significant water pollutants.
C3  - Zbornik radova 42. Međunarodnog stručno-naučnog skupa Vodovod i kanalizacija
T1  - SIMULTANEOUS ADSORPTION OF COPER IONS AND ANTIBIOTICS CIPROFLOXACIN FROM WATER AT SEPIOLITE
SP  - 232
UR  - https://hdl.handle.net/21.15107/rcub_technorep_5922
ER  - 
@conference{
author = "Lazarević, Slavica and Janković-Častvan, Ivona and Janaćković, Đorđe and Petrović, Rada",
year = "2021",
abstract = "The wide use of antibiotics, the increase in chemical industry and traffic, as well as the medical industry resulted in formation of wastewater, which contains complexes of heavy metals and antibiotics. Earlier researches have shown that clay minerals had a significant large adsorption capacity for heavy metal ions, and recently examinations are focused on investigation of the possibility of treatment of water with presence of antibiotics and heavy metal ions. In this paper, the possibility of application of natural mineral sepolite for simultaneous removal of antibiotics of ciprofloxacin and copper ions from aqueous solutions. It was shown that at the initial pH of 6,0±0,1 presence of the copper ions (~ 20 mg/dm3) increased the adsorption capacity of ciprofloxacin onto sepiolite, while the presence of ciprofloxacin, had no significant influence on the removal capacity of Cu2+ ions. The results of adsorption isotherms indicated significant adsorption capacity for both, ciprofloxacin and Cu2+ ions, ie. it was shown that natural mineral sepiolite was very effective adsorbent for the simultaneous removal of ciprofloxacin and Cu2+ ions as a significant water pollutants.",
journal = "Zbornik radova 42. Međunarodnog stručno-naučnog skupa Vodovod i kanalizacija",
title = "SIMULTANEOUS ADSORPTION OF COPER IONS AND ANTIBIOTICS CIPROFLOXACIN FROM WATER AT SEPIOLITE",
pages = "232",
url = "https://hdl.handle.net/21.15107/rcub_technorep_5922"
}
Lazarević, S., Janković-Častvan, I., Janaćković, Đ.,& Petrović, R.. (2021). SIMULTANEOUS ADSORPTION OF COPER IONS AND ANTIBIOTICS CIPROFLOXACIN FROM WATER AT SEPIOLITE. in Zbornik radova 42. Međunarodnog stručno-naučnog skupa Vodovod i kanalizacija, 232.
https://hdl.handle.net/21.15107/rcub_technorep_5922
Lazarević S, Janković-Častvan I, Janaćković Đ, Petrović R. SIMULTANEOUS ADSORPTION OF COPER IONS AND ANTIBIOTICS CIPROFLOXACIN FROM WATER AT SEPIOLITE. in Zbornik radova 42. Međunarodnog stručno-naučnog skupa Vodovod i kanalizacija. 2021;:232.
https://hdl.handle.net/21.15107/rcub_technorep_5922 .
Lazarević, Slavica, Janković-Častvan, Ivona, Janaćković, Đorđe, Petrović, Rada, "SIMULTANEOUS ADSORPTION OF COPER IONS AND ANTIBIOTICS CIPROFLOXACIN FROM WATER AT SEPIOLITE" in Zbornik radova 42. Međunarodnog stručno-naučnog skupa Vodovod i kanalizacija (2021):232,
https://hdl.handle.net/21.15107/rcub_technorep_5922 .